@ARTICLE{Wilczek_A._SEM/TEM_2022,
 author={Wilczek, A. and Morgiel, J. and Sypień, A. and Pomorska, M. and Rogal, Ł.},
 volume={vol. 67},
 number={No 4},
 journal={Archives of Metallurgy and Materials},
 pages={1341-1348},
 howpublished={online},
 year={2022},
 publisher={Institute of Metallurgy and Materials Science of Polish Academy of Sciences},
 publisher={Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences},
 abstract={High pressure die casting (HDPC) allows to produce aluminum parts for car industry of complicated shapes in long series. Dies used in this process must be robust enough to withstand long term injection cycling with liquid aluminum alloys, as otherwise their defects are imprinted on the product making them unacceptable. It is expected that nitriding followed by coating deposition (duplex treatment) should protect them in best way and increase intervals between the cleaning/repairing operations. The present experiment covered investigations of the microstructure of the as nitride and deposited with CrAlN coating as well as its shape after foundry tests. The observations were performed with the scanning and transmission electron microscopy (SEM/TEM) method. They showed that the bottom part of this bi-layer is formed by roughly equi-axed Cr2N crystallites, while the upper one with the fine columnar (CrAl)N crystallites. This bi-layers were matched with a set of 7x nano-layers of CrN/(CrAl)N, while at the coating bottom a CrN buffer layer was placed. The foundry run for up to 19 500 cycles denuded most of coated area exposed to fast liquid flow (40 m/s) but left most of bottom part of the coating in the areas exposed to slower flow (7 m/s). The acquired data indicated that the main weakness of this coating was in its porosity present both at the columnar grain boundaries (upper layer) as well as at the bottom of droplets imbedded in it (both layers). They nucleate cracks propagating perpendicularly and the latter at an angle or even parallel to the substrate. The most crack resistant part of the coating turned-out the bottom layer built of roughly equiaxed fine Cr2N crystallites. Even application of this relatively simple duplex protection in the form of CrAlN coating deposited on the nitride substrate helped to extend the die run in the foundry by more than three times.},
 type={Article},
 title={SEM/TEM Investigation of Degradation of Bi-Layer (Cr,Al)N/Cr2N3 Duplex Coatings Exposed to AlSi Alloy High Pressure Die Casting Cycles},
 URL={http://journals.pan.pl/Content/125069/PDF/AMM-2022-4-18-Morgiel.pdf},
 doi={10.24425/amm.2022.141060},
 keywords={duplex coatings, CrN/Cr2N/(CrN/CrAlN)/CrAlN, SEM, TEM, HPDC},
}