@ARTICLE{Kierzkowska-Pawlak_Hanna_Reaction_2012, author={Kierzkowska-Pawlak, Hanna and Siemieniec, Marta and Chacuk, Andrzej}, number={No 1 March}, journal={Chemical and Process Engineering}, pages={7-18}, howpublished={online}, year={2012}, publisher={Polish Academy of Sciences Committee of Chemical and Process Engineering}, abstract={The kinetics of the reaction between CO2 and methyldiethanolamine in aqueous solutions have been studied using the stopped-flow technique at 288, 293, 298 and 303 K. The amine concentration ranged from 250 to 875 mol·m-3. The overall reaction rate constant was found to increase with amine concentration and temperature. The acid base catalysis mechanism was applied to correlate the experimentally determined kinetic data. A good agreement between the second order rate constants for the CO2 reaction with MDEA computed from the stopped-flow data and the values reported in the literature was obtained.}, type={Artykuły / Articles}, title={Reaction kinetics of CO2 in aqueous methyldiethanolamine solutions using the stopped-flow technique}, URL={http://journals.pan.pl/Content/84667/PDF/01-ZS-paper-Kierzkowska-Pawlak.pdf}, doi={10.2478/v10176-012-0001-6}, keywords={CO2capture, reaction kinetics, methyldiethanolamine, stopped-flow technique}, }