Synthesis of Natural Phenolic Compound Contained Alkaline Phenolic Foundry Resin and Its Performance Evaluation on Casting

Journal title

Archives of Foundry Engineering




vo. 21


No 2


Güvendik, A.E. : Çukurova Kimya Endüstrisi A.Ş., Turkey ; Ay, K. : Manisa Celal Bayar University, Turkey



Phenolic resins ; Lignin ; Sustainability ; Foundry ; No-Bake

Divisions of PAS

Nauki Techniczne




The Katowice Branch of the Polish Academy of Sciences


[1] Pilato, L. (2010). Phenolic Resins: A century of progress (pp. 451-502). Germany Berlin: Springer Verlag. [2] Bindernagel, E. (1983). Molding sands and molding processes in foundry engineering (in German). Germany Dusseldorf: Giesserei-Verlag.
[3] Dressler, H. (1994). Resorcinol/formaldehyde resins-adhesives for wood, and other nonrubber applications. In: Resorcinol. (pp.85-124). Topics in Applied Chemistry. Springer, Boston, MA.
[4] Danielson, B. & Simonson, R. (1998). Kraft lignin in phenol formaldehyde resin. Part 1-2. Evaluation of an industrial trial. Journal of Adhesion Science and Technology. 12(9), 941-946.
[5] Ramires, E.C. & Frollini, E. (2012). Tannin-phenolic resins: Synthesis, characterization, and application as matrix in biobased composites reinforced with sisal fibers. Composites: Part B. 43, 2851-2860. DOI: 10.1016/j.compositesb.2012.04.049.
[6] Sellers Jr., T. & Miller Jr., G.D. (2004). Laboratory manufacture of high moisture southern pine strandboard bonded with three tannin adhesive types. Forest Products Journal. 54(12), 296-301.
[7] Pizzi, A., Horak, R.M., Ferreiraand, D., Roux, R.D. (1979). Condensates of phenol, resorcinol, phloroglucinol and pyrogallol, as flavonoids A-and B-rings model compounds with formaldehyde, Part 2. Cell. Chem. Technol. 13, 753-762.
[8] Fross, K.G. & Fuhrmann, A. (1979). Finnish plywood, partially cleboard, and fiberboard made with a lignin-base adhesive. Forest Products Journal. 29(7), 39-43.
[9] Falkehag, S.I. (1975). Lignin in materials, Applied Pol. Symp. 28, 247-257.
[10] Kuo, M., Hse, C.Y. & Huang, D.H. (1991). Alkali treated kraft lignin as a component in flakeboard resins. Holzforschung. 45(1), 47-54. DOI: 10.1515/hfsg.1991.45.1.47.
[11] Rubio, A., Virginia, M. (2004). Formulation and curing of "resol" type phenol-formaldehyde resins with partial substitution of phenol by modified lignosulfonates.(in Spanish) Universidad Complutense de Madrid, Servicio de Publicaciones.
[12] Ungureanu, E., Ungureanu, O., Capraru, A.M. & Popa, V.I. (2009). Chemical modification and characterization of straw lignin. Cellulose Chemistry & Technology. 43(7-8), 263-269.
[13] Kerns, W.D., Pavkov, K.L., Donofrio, D.J., Gralla, E.J. & Swenberg, J.A. (1983). Carcinogenicity of formaldehyde in rats and mice after long-term inhalation exposure. Cancer Research. 43, 4382-4392.
[14] Mäkinen, M., Kalliokoski, P. & Kangas, J. (1999). Assessment of total exposure to phenol-formaldehyde resin glue in plywood manufacturing. International Archives of Occupational and Environmental Health. 72, 309-314.
[15] Nordman, H., Keskinen, H. & Tuppurainen, M. (1985). Formaldehyde asthma-rare or overlooked? Journal of Allergy and Clinical Immunology. 75, 91-99.
[16] Khan, S. (2012). Fossil Fuel and the Environment, chapter 8: Singh, B.R. and O. Singh, O. Global trends of fossil fuel reserves and climate change in the 21st century, InTech, India.
[17] Hock, H. & Lang, S. (1944). Auto-oxidation of hydrocarbons, IX. Notice: About peroxides of benzene derivatives. Berichte der Deutschen Chemischen Gesellschaft (A and B Series), 77, 257-264. (in German).
[18] Monni, J., Rainio, J. & Pakkanen, T.T. (2007). Novel two-stage phenol formaldehyde resol resin synthesis. Journal of Applied Polymer Science. 103, 371-379.
[19] Knop, A. & Pilato, L.A. (1985). Phenolic Resins-Chemistry, Applications and Performance. (pp. 25-35), XV, Springer-Verlag, Berlin, 3-540-15039-0.
[20] Kuhn, H. (2000).Vol 8 Mechanical Testing and Evalution. ASM Handbook, 9th ed., US: ASM International.
[21] Moulding sands, moulding and core sand mixtures. Methods for determination of compressive, tensile, bending and shearing strength,(in Russian) Russian Standards, GOST 23409.7-78.
[22] Bouajila, J., Raffin, G., Alamercery, S., Waton, H., Sanglar, C. & Grenier-Loustalot, M.F. (2003). Phenolic resins (IV). Thermal degradation of crosslinked resins in controlled atmospheres. Polymers & Polymer Composites. 11(5), 345-357.
[23] Stephanou, A. & Pizzi, A. (1993). Rapid-curing lignin-based exterior wood adhesives; Part II: Esters acceleration mechanism and application to panel products. Holzforschung-International Journal of the Biology, Chemistry, Physics and Technology of Wood. 47(6), 501-506. DOI: 10.1515/hfsg.1993.47.6.501.
[24] Lei, H., Pizzi, A., Despres, A., Pasch, H. & Guanben Du. (2005). Ester Acceleration Mechanisms in Phenol-Formaldehyde Resin Adhesives. Journal of Applied Polymer Science. 100, 3075-3093.
[25] Mocek, J. (2019). Multiparameter Assessment of the Gas Forming Tendency of Foundry Sands with Alkyd Resins. Archives of Foundry Engineering. 19(2), 41-48. DOI: 10.24425/afe.2019.127114.
[26] Wrona, R. (2015). The Sources of Surface Defects in Castings Produced in Automated Process Lines. Archives of Foundry Engineering. 15(4), 91-94. DOI: 10.1515/afe-2015-0086.






DOI: 10.24425/afe.2021.136097


Archives of Foundry Engineering; 2021; vo. 21; Ahead of print