Antimony speciation in soils in areas subjected to industrial anthropopressure

Journal title

Archives of Environmental Protection








Jabłońska-Czapla, Magdalena : Institute of Environmental Engineering, Polish Academy of Sciences, Poland ; Grygoyć, Katarzyna : Institute of Environmental Engineering, Polish Academy of Sciences, Poland ; Rachwał, Marzena : Institute of Environmental Engineering, Polish Academy of Sciences, Poland



soil, ; Sb(III), ; antimony speciation, ; Sb(V), ; SbMe3, ; industrial anthropopressure

Divisions of PAS

Nauki Techniczne




Polish Academy of Sciences


  1. Bagherifam, S., Brown, T.C., Wijayawardena, A. & Naidu, R. (2021). The influence of different antimony (Sb) compounds and ageing on bioavailability and fractionation of antimony in two dissimilar soils, Environmental Pollution, 270, 1, pp. 116270.
  2. Barker, A.J., Mayhew L.E., Douglas, T.A., Ilgen, A.G. & Trainor T.P. (2020). Lead and antimony speciation associated with the weathering of bullets in a historic shooting range in Alaska, Chemical Geology, 553, pp. 119797.
  3. Barragan, J.A., Ponce de León, C., Alemán Castro, J. R., Peregrina-Lucano A., Gómez-Zamudio F. & Larios-Durán, E.R. (2020), Copper and Antimony Recovery from Electronic Waste by Hydrometallurgical and Electrochemical Techniques, ACS Omega, 5(21), pp. 12355–12363. doi: 10.1021/acsomega.0c01100
  4. Bi, X., Li, Z., Zhuang, X., Han, Z. & Yang, W. (2011). High levels of antimony in dust from e-waste recycling in southeastern China, Science of the Total Environment, 409, pp. 5126–5128. DOI:10.1016/j.scitotenv.2011.08.009
  5. De Gregori, I., Quiroz, W., Pinochet, H., Pannier, F. & Potin-Gautier, M. (2007). Speciation analysis of antimony in marine biota by HPLC-(UV)-HG-AFS: Extraction procedures and stability of antimony species, Talanta, 73, pp. 458-465. DOI: 10.1016/j.talanta.2007.04.015
  6. Directive (EU) 2020/2184 of the European Parliament and of the council of 16 December 2020 on the quality of water intended for human consumption
  7. Diquattro, S., Castidi, P., Ritch, S., Juhasz, L.J., Brunetti, G., Scheckel, K.G., Garau, G. & Lombi, E. (2021). Insights into the fate of antimony (Sb) in contaminated soils: Ageing influence on Sb mobility, bioavailability, bioaccessibility and speciation, Science of The Total Environment, 770, pp. 145354.
  8. Filella, M., Belzile, N. & Chen, Y. (2002). Antimony in the environment: a review focused on natural waters II. Relevant solution chemistry, Earth-Science Reviews, 59, pp. 265–285. DOI: 10.1002/chin.200323280
  9. Ge, Z. & Wei, C. (2013). Simultanous Analysis of SbIII, SbV and TMSb by High Performance Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry Detection: Application to Antimony Speciation in Soil Samples, Journal of Chromatographic Science, 51, pp. 391-399.
  10. Hammel, W., Debus, R. & Steubing, L. (2000). Mobility of antimony in soil and its availability to plants, Chemosphere, 41, pp. 1791-1798. DOI: 10.1016/s0045-6535(00)00037-0
  11. He, M., Wang, N., Long, X., Zhang, C., Ma, C., Zhong, Q., Wang, A., Wang, Y., Pervaiz, A. & Shan, J. (2019). Antimony speciation in the environment: recent advances in understanding the biogeochemical processes and ecological effects, Journal of Environmental Sciences, 75, pp. 14–39. DOI: 10.1016/j.jes.2018.05.023
  12. Herath, I., Vithanage, M. & Bundschuh, J. (2017). Antimony as a global dilemma: geochemistry, mobility, fate and transport, Environmental Pollution, 223, pp. 545–559. DOI: 10.1016/j.envpol.2017.01.057
  13. Jabłońska-Czapla, M., Rachwał M., Grygoyć K. & Wawer M. (2022). Identification of the antimony sources in soils in areas subject to industrial anthropopressure using geophysical-geochemical methods, Chemosphere (under review).
  14. Jabłońska-Czapla, M., Szopa, S. & Rosik-Dulewska, Cz. (2014a). Impact of mining dump on the accumulation and mobility of metals in the Bytomka River sediments, Archives of Environmental Protection, 40, 2, pp. 3-19. DOI: 10.2478/aep-2014-0013
  15. Jabłońska-Czapla, M., Szopa, S., Grygoyć, K., Łyko, A. & Michalski, R. (2014b). Development and validation of HPLC–ICP-MS method for the determination inorganic Cr, As and Sb speciation forms and its application for Pławniowice reservoir (Poland) water and bottom sediments variability study, Talanta, 120, pp. 475-483.
  16. Ji, Y., Mestrot, A., Schulin, R. & Tandy, S. (2018). Uptake and transformations of methylated and inorganic antimony in plants, Frontiers in Plant Science, 9, 140, pp. 1-10.
  17. Jia, X., Ma L., Liu, J., Liu, P., Yu, L., Zhou, J., Li, W., Zhou W. & Dong., Z. (2022). Reduction of antimony mobility from Sb-rich smelting slag by Shewanella oneidensis: Integrated biosorption and precipitation, Journal of Hazardous Materials, 426, pp.127385.
  18. Kozak, L. & Niedzielski, P. (2008). Determination of inorganic antimony species by hyphenated technique high performance liquid chromatography with hydride generation atomic absorption spectrometry detection, Archives of Environmental Protection, 34, 4, pp. 71-79.
  19. Kulka, E. & Gzyl, J. (2008). Assessment of lead and cadmium soil contamination in the vicinity of a non-ferrous metal smelter, Archives of Environmental Protection, 34, pp. 105-115.
  20. Loska, K., Wierchuła, D. & Korus, I. (2004). Antimony concentration in farming soil of southern Poland, Bulletin of Environmental Contamination and Toxicology, 72, pp. 858-865. DOI:10.1007/S00128-004-0323-2
  21. Martinez, A.M. & Escheberria, J. (2016).Towards a better understanding of the reaction between metal powders and the solid lubricant Sb2S3 in a low-metallic brake pad at high temperature, Wear, 348-349, pp. 27-42. DOI: 10.1016/j.wear.2015.11.014
  22. Muhammad Shahid, N., Khalid, S., Dumat, C., Pierart, A. & Niazi N.K. (2019). Biogeochemistry of antimony in soil-plant system: Ecotoxicology and human health, Applied Geochemistry, 106, pp. 45-59.
  23. Nishad, P.A. & Bhaskarapillai, A. (2021) Antimony, a pollutant of emerging concern: A review on industrial sources and remediation technologies, Chemosphere, 277, pp. 130252.
  24. Pasieczna, A. (2012). The content of antimony and bismuth in the soils of agricultural lands in Poland, Polish Journal of Agronomy, 10, pp. 21-29. (in Polish)
  25. Qi, C., Liu, G., Kang, Y., Lam, P.K.S. & Chou, C. (2011). Assessment and distribution of antimony in soils around three coal mines, Anhui China, Journal of the Air & Waste Management Association, 61, pp. 850-857. DOI: 10.3155/1047-3289.61.8.850
  26. Quan, S.X., Yan, B., Yang, F., Li, N., Xiao, X.M. & Fu, J.M. (2015). Spatial distribution of heavy metal contamination in soils near a primitive e-waste recycling site, Environmental Science and Pollution Research, 22, pp. 1290-1298. DOI: 10.1007/s11356-014-3420-8
  27. Quiroz, W., Cortes, M., Astudillo, F., Bravo, M., Cereceda, F., Vidal, V. & Lobos, M.G. (2013). Antimony speciation in road dust and urban particulate matter in Valparaiso, Chile: Analytical and environmental considerations, Microchemical Journal, 10, pp. 266-272. DOI: 10.1016/j.microc.2013.04.006
  28. Rachwał, M., Wawer, M., Magiera T. & Steinnes, E. (2017). Integration of soil magnetometry and geochemistry for assessment of human health risk from metallurgical slag dumps. Environmental Science and Pollution Research, 24, pp. 26410–26423. DOI: 10.1007/s11356-017-0218-5
  29. Regulation of the Minister of the Environment of September 1, 2016 on the method of assessing pollution of the earth's surface, Journal of Laws No. 1395 (in Polish)
  30. Warchulski, R., Gawęda, A., Kądziołka-Gaweł, M. & Szopa, K. (2015). Composition and element mobilization in pyrometallurgical slags from the Orzeł Biały smelting plant in the Bytom Piekary Śląskie area, Poland. Mineralogical Magazine, 79, 2, pp. 459–483.
  31. Wei, C., Ge, Z., Chu, W. & Feng, R. (2015). Speciation of antimony and arsenic in the soils and plants in an old antimony mine, Environmental and Experimental Botany, 109, pp. 31-39.
  32. Wu, T., Cui, X., Ata-Ul-Karim, S.T., Cui, P., Liu, C., Fan, T., Sun, Q., Gong, H., Zhou, D. & Wang Y. (2022). The impact of alternate wetting and drying and continuous flooding on antimony speciation and uptake in a soil-rice system. Chemosphere, 297, pp. 134147.
  33. Zhang, Z., Lu, Y., Li, H., Zhang, N., Cao, J., Qui, B. & Yang, Z. (2021). Simultaneous Separation of Sb(III) and Sb(V) by High Performance Liquid Chromatography (HPLC) – Inductively Coupled Plasma – Mass Spectrometry (ICP-MS) with Application to Plants, Soils and Sediments, Analytical Letters, 54, 6, pp. 919-934. DOI:10.1080/00032719.2020.1788049






DOI: 10.24425/aep.2022.140765



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