TitleReaction kinetics of CO2 in aqueous methyldiethanolamine solutions using the stopped-flow technique
Journal titleChemical and Process Engineering
NumerNo 1 March
KeywordsCO2capture ; reaction kinetics ; methyldiethanolamine ; stopped-flow technique
Divisions of PASNauki Techniczne
PublisherPolish Academy of Sciences Committee of Chemical and Process Engineering
TypeArtykuły / Articles
IdentifierDOI: 10.2478/v10176-012-0001-6 ; ISSN 0208-6425
SourceChemical and Process Engineering; 2012; No 1 March; 7-18
ReferencesDonaldson T. (1980), Carbon dioxide reaction kinetics and transport in aqueous amine membranes, Ind. Eng. Chem. Fundam, 19, 260, doi.org/10.1021/i160075a005 ; Figueroa J. (2008), Advances in CO<sub>2</sub> capture technology - The U. S. Department of Energy's Carbon Sequestration Program, Int. J Greenhouse Gas Control, 2, 9, doi.org/10.1016/S1750-5836(07)00094-1 ; Haimour N. (1987), Kinetics of the reaction between carbon dioxide and methyldiethanolamine, Chem. Eng. Sci, 42, 1393, doi.org/10.1016/0009-2509(87)85011-X ; Jamal A. (2006), Kinetics of carbon dioxide absorption and desorption in aqueous alkanolamine solutions using a novel hemispherical contactor - I. Experimental apparatus and mathematical modeling, Chem. Eng. Sci, 61, 6571, doi.org/10.1016/j.ces.2006.04.046 ; Kierzkowska-Pawlak H. (2010), Kinetics of carbon dioxide absorption into aqueous MDEA solutions, Ecol. Chem. Eng. S, 17, 463. ; H Kierzkowska-Pawlak (2011), Numerical simulation of CO<sub>2</sub> absorption into aqueous MDEA solutions, Korean J. Chem. Eng, 29, 6. ; Knipe A. (1974), A fast response conductivity amplifier for chemical kinetics, J. Phys. E, 7, 586, doi.org/10.1088/0022-3735/7/7/025 ; Li J. (2007), Reaction kinetics of CO<sub>2</sub> in aqueous ethylenediamine, ethylethanolamine, and diethylmonoethanolamine solutions in the temperature range of 298-313 K, using the stopped-flow technique, Ind. Eng. Chem. Res, 46, 4426, doi.org/10.1021/ie0614982 ; Khorassani S. (2011), Establishing a new conductance stopped-flow apparatus to investigate the initial fast step of reaction between 1,1,1-trichloro-3-methyl-3-phospholene and methanol under a dry inert atmosphere, Analyst, 136, 1713, doi.org/10.1039/c0an00817f ; Ko J.-J. (2000), Kinetics of absorption of carbon dioxide into solutions of N-methyldiethanolamine + water, Chem. Eng. Sci, 55, 4139, doi.org/10.1016/S0009-2509(00)00079-8 ; Kohl A. (1997), Gas Purification. ; Littel R. (1991), Kinetics of carbon dioxide with tertiary amines in aqueous solution, AIChE J, 36, 1633, doi.org/10.1002/aic.690361103 ; Moniuk W. (2000), Absorption of CO<sub>2</sub> in aqueous solutions of N-methyldiethanolamine, Inż. Chem. i Proces, 21, 183. ; Notz R. (2011), CO<sub>2</sub> capture for fossil fuel-fired power plants, Chem. Eng. Technol, 34, 163, doi.org/10.1002/ceat.201000491 ; Pani F. (1997), Kinetics of absorption of CO<sub>2</sub> in concentrated aqueous methyldiethanolamine solutions in the range 296 K to 343 K, J. Chem. Eng. Data, 42, 353, doi.org/10.1021/je960251g ; Pinsent B. (1956), The kinetics of combination of carbon dioxide with hydroxide ions, Trans. Faraday Soc, 52, 1512, doi.org/10.1039/TF9565201512 ; Pohorecki R. (1988), Kinetics of reaction between carbon dioxide and hydroxyl ions in aqueous electrolyte solutions, Chem. Eng. Sci, 43, 1677, doi.org/10.1016/0009-2509(88)85159-5 ; Ramachandran N. (2006), Kinetics of the absorption of CO<sub>2</sub> into mixed aqueous loaded solutions of monoethanolamine and methyldiethanolamine, Ind. Eng. Chem. Res, 45, 2608, doi.org/10.1021/ie0505716 ; Rinker E. (1995), Kinetics and modeling of carbon dioxide absorption into aqueous solutions of N-methylodiethanolamine, Chem. Eng. Sci, 50, 5, 755, doi.org/10.1016/0009-2509(94)00444-V ; Siemieniec M. (2012), Reaction kinetics of CO<sub>2</sub> in aqueous diethanolamine solutions in the temperature range of 293÷313 K using the stopped-flow technique, Ecological Chem. Eng. S, 19, 55, doi.org/10.2478/v10216-011-0006-y ; Steeneveldt R. (2006), CO<sub>2</sub> capture and storage. Closing the knowing-doing gap, Chem. Eng. Res. Des, 84, 739, doi.org/10.1205/cherd05049 ; Vaidya P. (2007), CO<sub>2</sub>-alkanolamine reaction kinetics: A review of recent studies, Chem. Eng. Technol, 30, 1467, doi.org/10.1002/ceat.200700268 ; S. van Loo (2007), The removal of carbon dioxide with activated solutions of methyldiethanol-amine, J. Pet. Sci. Eng, 55, 135, doi.org/10.1016/j.petrol.2006.04.017 ; Zhang X. (2002), Kinetics of absorption of CO<sub>2</sub> into aqueous solution of MDEA blended with DEA, Ind. Eng. Chem. Res, 41, 1135, doi.org/10.1021/ie010605j
Dorota Antos, Rzeszów University of Technology, Poland
Katarzyna Bizon, Cracow University of Technology, Poland
Tomasz Ciach, Warsaw University of Technology, Poland
Magdalena Cudak, West Pomeranian University of Technology, Szczecin, Poland
Grzegorz Dzido, Silesian University of Technology, Poland
Marek Dziubiński, Lodz University of Technology, Poland
Leon Gradoń, Warsaw University of Technology, Poland
Andrzej Górak, TU Dortmund, Germany
Andrzej Heim, Lodz University of Technology, Poland
Marek Henczka, Warsaw University of Technology, Poland
Andrzej Jarzębski, Silesian University of Technology, Poland
Zdzisław Jaworski, West Pomeranian University of Technology, Szczecin, Poland
Władysław Kamiński, Poland
Bożenna Kawalec-Pietrenko, Poland
Stanisław Ledakowicz, Lodz University of Technology, Poland
Łukasz Makowski, Warsaw University of Technology, Poland
Eugeniusz Molga, Warsaw University of Technology, Poland
Andrzej Noworyta, Wrocław University of Science and Technology, Poland
Roman Petrus, Rzeszów University of Technology, Poland
Ryszard Pohorecki, Warsaw University of Technology, Poland
Rafał Rakoczy, West Pomeranian University of Technology, Szczecin, Poland
Andrzej Sobkowiak, Rzeszów University of Technology, Poland
Tomasz Sosnowski, Warsaw University of Technology, Poland
Anna Trusek, Wrocław University of Science and Technology, Poland
Kazimiera Wilk, Wrocław University of Science and Technology, Poland
Ireneusz Zbiciński, Lodz University of Technology, Poland
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