Nauki Techniczne

Gospodarka Surowcami Mineralnymi - Mineral Resources Management

Zawartość

Gospodarka Surowcami Mineralnymi - Mineral Resources Management | 2023 | vol. 39 | No 2

Abstrakt

The main source of information on the abundance of polymetallic nodules (APN) is the results of direct seafloor sampling, mainly using box corers. Due to the vast spread of nodule occurrence in the Pacific, the distances between successive sampling sites are significant. This makes it difficult to reliably estimate the nodule resources, especially in parts of the deposit with small areas corresponding to the areas scheduled for extraction in the short term (e.g. within one year). It seems justified to try to increase the accuracy of nodule resource estimates through the use of information provided by numerous photos of the ocean floor taken between sampling stations. In particular, the percentage of nodule coverage of the ocean floor (NC), the data on fraction distribution of nodules (FD) and the coverage of nodules with sediments (SC) are important here. In the presented study, three regression models were used to predict the nodule abundance from images: simple linear regression (SLR), multiple regression (MR), and general linear model (GLM). The GLM provides the most accurate prediction of nodule abundance (APN) due to the ability of this model to simultaneously take into account both quantitative variable (NC) and qualitative variables (FD, SC). The mean absolute errors of APN prediction are in the range of 1.0–1.7 kg/m2, which is 7–13% of the average nodule abundance determined for training or testing data sets. This result can be considered satisfactory for predicting the abundance in ocean floor areas covered only by photographic survey.
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Autorzy i Afiliacje

Monika Wasilewska-Błaszczyk
1
ORCID: ORCID
Jacek Mucha
1
ORCID: ORCID

  1. AGH University of Science and Techology, Kraków, Poland

Abstrakt

In the Mardin-Mazıdağı region, which corresponds to the northern Arabian Plate, layers containing marine phosphorite rocks are found within the Karababa Formation (Upper Cretaceous). The Karataş member contains phosphorites and carbonate rocks with nodular chert geodes and fossils.
The phosphorite and micritic limestones contain invertebrate fossil fragments and materials such as optical isotropic pelletic apatite minerals, angular/subangular and plated fish bone fragments, and brachiopod shells. SEM (scanning electron microscopy) results show that the apatite minerals are either spherical or ellipsoidal in shape and their size varies between 100–200 μm. According to X-ray diffraction (XRD) examinations, the rocks contain apatite (carbonate rich fluorapatite; CFA), carbonate (calcite, dolomite), silica (quartz and opal-CT), little feldspar, and clay (smectite, palygorskite/ sepiolite, kaolinite, illite, chlorite, mixed layered chlorite-vermiculite (C-V) and illite-vermiculite (I-V).
The average major and trace elements found in the phosphorite include P2O5 (35.41 wt.%), REE s (44.57 ppm), Y (52.85 ppm), and U (5.45 ppm). The Mazıdağı phosphorite analysis indicates that the conditions are slightly oxic, which is supported by their slightly negative Ce anom average values (–0.30), low Ce/La ratios (0.32), and a V/(V + Ni) mean of 0.93 ppm. All the recoded values of the average REE for the study area are considerably lower than those in Iraq (84.30 ppm), Tunisia (400.3 ppm), Morocco (571.75 ppm) and Jordan (187 ppm). It is inferred that mineral formation processes are affected by the biogenic and biogeochemical activities that occurred in conjunction with the changes in sea level driven by the tectonic conditions associated with the evolution of the Neotethys Ocean.
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Autorzy i Afiliacje

Sema Tetiker
1
ORCID: ORCID

  1. Batman University, Turkey

Abstrakt

The growing increase in the use of cars and transportation in general is causing an increase the emission of pollutants into the atmosphere. The current European Union regulations impose the minimization of pollution through the use of automotive catalytic converters on all member countries, which stops toxic compounds from being emitted into the atmosphere thanks to their contents of platinum group metals (PGMs). However, the growing demand for cars and the simultaneous demand for catalytic converters is contributing to the depletion of the primary sources of PGMs. This is why there is now increasing interest in recycling PGMs from catalytic converters through constantly developing technologies. There are newer and more sustainable solutions for the recovery of PGMs from catalytic converters, making the process part of a circular economy (CE) model. The purpose of this article is to present two innovative methods of PGM recovery in the framework of ongoing research and development projects.
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Autorzy i Afiliacje

Natalia Generowicz
1
ORCID: ORCID
Agnieszka Nowaczek
1
ORCID: ORCID
Leszek Jurkowski
2
Iakovos Yakoumis
3

  1. Mineral and Energy Economy Research Institute Polish Academy of Sciences, Kraków, Poland
  2. Unimetal Recycling sp. z o.o., Trzebinia, Poland
  3. MONOLITHOS Catalysts and Recycling Ltd, Athens, Greece

Abstrakt

This study presents the results of concentrations of rare earth elements and yttrium (REY ), uranium (U), and thorium (Th) in ashes from combustion/co-combustion of biomass (20%, 40%, and 60% share) from the agri-food industry (pomace from apples, walnut shells, and sunflower husks) and hard coal. The study primarily focuses on ashes from the co-combustion of biomass and hard coal, in terms of their potential use for the recovery of rare earth elements (REE ), and the identification of the sources of these elements in the ashes. Research methods such as ICP-MS (inductively coupled plasma mass spectrometry), XRD (X-ray diffraction), and SEM -EDS (scanning electron microscopy with quantitative X-ray microanalysis) were used. The total average content of REY in ash from biomass combustion is 3.55–120.5 mg/kg, and in ash from co-combustion, it is from 187.3 to 73.5 mg/kg. The concentration of critical REE in biomass combustion ash is in the range 1.0–38.7 mg/kg, and in cocombustion ash it is 23.3–60.7 mg/kg. In hard-coal ash, the average concentration of REY and critical REY was determined at the level of 175 and 45.3 mg/kg, respectively. In all samples of the tested ashes, a higher concentration of Th (0.2–14.8 mg/kg) was found in comparison to U (0.1–6 mg/kg). In ashes from biomass and hard-coal combustion/co-combustion, the range of the prospective coefficient (Coutl) is 0.66–0.82 and 0.8–0.85, respectively, which may suggest a potential source for REE recovery. On the basis of SEM -EDS studies, yttrium was found in particles of ashes from biomass combustion, which is mainly bound to carbonates. The carriers of REY , U, and Th in ashes from biomass and hard-coal co-combustion are phosphates (monazite and xenotime), and probably the vitreous aluminosilicate substance.
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Autorzy i Afiliacje

Joanna Adamczyk
1
Danuta Smołka-Danielowska
1
ORCID: ORCID
Arkadiusz Krzątała
1
Tomasz Krzykawski
1

  1. University of Silesia, Katowice, Poland

Abstrakt

This article investigates the possibilities of the recovery of raw materials at the Kraków–Płaszów municipal wastewater treatment plant (WWTP). The materials include sand coming with raw sewage and delivered by septic tankers, after cleaning sewage systems. Following the Regulation of the Minister of Climate (January 2020), sand from grit chambers is classified in the waste catalog as waste, with the code of 19 08 02. (Journal of Laws of 2020, item 10). The purchase of very efficient units has optimized the grit chamber operation and minimized the amount of waste generated as well as being an odor nuisance. The paper presents a mass balance for sand collected at the WWTP. Due to the use of new sand separators, the amount of this waste has been reduced by 28%. The paper presents the sieve curves of sand collected at the wastewater treatment plant and during the cleaning of sewage wells, as well as for sand mixtures. The sand mixture was prepared to allow some variations in the grain size characteristics of the sand. The graining differentiation indexes and curvature indexes were calculated. In addition, in laboratory tests, the leachability of heavy metals and the content of dry matter (DM) and dry mineral matter (DMM) were determined. The laboratory tests confirmed the reduction of organic solids to a level below 3% of dry weight; the content of heavy metals remained below the level of detection. The experiments confirmed that sand from the WWTP can be used as fine-grained aggregate in the production of concrete.
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Autorzy i Afiliacje

Justyna Górka
1
ORCID: ORCID
Dominika Poproch
2 3
ORCID: ORCID
Małgorzata Cimochowicz-Rybicka
1
ORCID: ORCID
Bartosz Łuszczek
4
ORCID: ORCID

  1. Faculty of Environmental Engineering and Energy, Cracow University of Technology, Kraków, Poland
  2. Doctoral School, Cracow University of Technology, Kraków, Poland
  3. Krakow Water, Kraków, Poland
  4. Kraków Water, Kraków, Poland

Abstrakt

In this article, gold is analyzed from an investment perspective as an asset that allows you to increase your wealth. The analysis is twofold. First, it is about examining to what extent changes in gold prices in the world markets translate into changes in the prices of shares of companies that extract gold. Second, it was checked whether there is a financial leverage effect, which in this case means that changes in the price of shares of gold mining companies are greater than changes in the price of gold itself. Methodically, the Sharpe model was used and two basic parameters of the model were estimated, i.e. the intercept (alpha), and the beta coefficient as a measure of systematic risk, for the gold market and the equity market of gold mining companies and ET Fs based on these companies.
The research carried out in accordance with the logic of the Sharpe model shows that the obtained value of the alpha parameter for the stock market was positive, while for the gold market it was negative. At the same time, higher levels of this parameter are beneficial to the investor, which means that an advantage of the stock market over the gold market exists. In turn, the estimated beta for the stock market is much lower than for the gold market. The systematic risk level for stocks is 0.45, and for the gold market it is 1.98, which is a significant difference. The stocks of gold mining companies can be classified as defensive against the stock market (the rate of return of the gold mine stock is insensitive to market movements) and aggressive against the gold market (the rate of return of the gold mine shares reacts more strongly than the movement in the price of gold).
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Autorzy i Afiliacje

Mikołaj Baranowski
1
Krystian Pera
1
ORCID: ORCID

  1. University of Economics, Katowice, Poland

Abstrakt

Road construction has been an ongoing engineering practice throughout human history. Although road construction technologies have changed over time, the raw material used has not changed for centuries, and it seems that it will not change in the upcoming centuries. Although some standards are used to determine the aggregate quality in road construction works, it is often complex and laborious to identify the aggregates that best meet the standards. Long-lasting and high-quality roads can be built and the most suitable aggregate is selected for the road. This study aims to select the most suitable aggregates used in hot-mix asphalt pavement production for road construction. In this study, multi-criteria decision-making methods were used for the selection of the aggregate that provides the best conditions. Aggregates used in constructing roads within the provincial borders of Ankara are produced from six stone quarries. To rank these aggregates and determine the ideal quarry for hot-mix asphalt production, the analytical hierarchy process (AHP) and the technique for order preference by similarity to an ideal solution (TOPSIS) method, which are multi-criteria decision making (MCDM) methods, were used. The results obtained from the tests on aggregates and hot-mix asphalts (HMA) were compared with the the best results based on the maximum and minimum limits determined in the standards. By comparing the the best results of the standards with the test results of the aggregates, weight scores were made for each test. Weight scores were scored and classified using the AHP and TOPSIS multi-criteria decision-making methods. As a result, the aggregate with the highest score and the quarry area represented by the aggregate were determined as the most suitable for hot-mix asphalt construction.
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Autorzy i Afiliacje

Niyazi Bilim
1
ORCID: ORCID
Hamza Güneş
2

  1. Konya Technical University, Turkey
  2. Ankara Metropolitan Municipality, Turkey

Abstrakt

The capacity market is a response to potential capacity scarcity in the system. The missing money problem may occur as a result of the dynamic development of renewable energy sources because their capacity factors are significantly lower in comparison to those of conventional generating units. The capacity market is a response to capacity scarcity in dynamic growth in renewable energy sources with lower capacity factors than thermal power plants. It is a support mechanism that provides additional funds in order for generation companies to be ready to produce electricity in system stress events. So far, seven capacity auctions have been held for 2021–2027 delivery periods. Since the vast majority of capacity market units are coal-fired public thermal power plants and combined heat and power plants, the analysis of capacity auction results provides valuable findings on coal consumption in the years to come. With this in mind, the objective of the study is to investigate the potential of coal consumption resulting from the long-term capacity contracts signed thus far. For this purpose, a comprehensive analysis of the capacity auctions’ results is conducted, including the analysis of the duration of the contracts, the structure of ownership, and fuels used in power units. The results show that the figures relating to the consumption of steam coal in units that have won capacity auctions are around 21,306 thousand Mg for 2023 and decreasing to 9,603 thousand Mg for 2035. Although European restrictions were introduced to limit remuneration for high-emission units, the long-term contracts ensure that these will remain in the system and will have an impact on the total consumption of steam coal in the medium- and long-term in the Polish power system.
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Autorzy i Afiliacje

Aleksandra Komorowska
1
ORCID: ORCID

  1. Mineral and Energy Economy Research Institute, Polish Academy of Sciences, Kraków, Poland

Abstrakt

A significant problem with the effective functioning of the hard-coal mining industry, especially in relation to mining enterprises and mines located in the Upper Silesian Coal Basin, are the high costs of mining. This is due to many reasons, among which, an important aspect is the ineffective use of the working time of mining faces. The unsatisfactory use of working time caused by unplanned shutdowns of mining faces is a significant reason for the fact that the use of the production potential of the expensive, modern mechanized systems built in them, with the production capacity of around 1,000–1,500 tons per hour, is relatively small – the average daily volume of mining from a longwall working is most often around 3,000 tonnes or even slightly less. A significant reason for this is the occurrence of a large number of interruptions in the continuity of their work, which is mainly caused by equipment failures, the impact of unfavorable geological and mining conditions or technological shutdowns.
The article deals with the problem of the unsatisfactory level of the effective use of working time in mining faces (longwalls) in Polish hard-coal mines. The main reason for this is the occurrence of a large number of unplanned stops and interruptions, sometimes lasting several days. Their elimination or at least reduction would significantly contribute to the improvement of the existing situation. The condition for this, however, is reliable analyses aimed at detailed the identification of their causes. It was proposed to use three methods – the analytic hierarchy process (AHP), the development of the Pareto-Lorenz diagram and the 5 Whys method. Examples of their practical application are also presented.
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Autorzy i Afiliacje

Patrycja Bąk
1
ORCID: ORCID
Marian Turek
2
ORCID: ORCID

  1. AGH University of Science and Technology, Kraków, Poland
  2. Central Mining Institute, Katowice, Poland

Abstrakt

The article presents the principles of sozology formulated by Walery Goetel and examples of their development in the scientific and research works as well as implementation and teaching work performed at the Faculty of Civil Engineering and Resource Management at AGH University of Science and Technology. These works are aimed at the rational management of mineral deposits and its extraction, as well as at the creation of utility values of the post-mining areas. It has also been shown that the work carried out at the faculty has gone far beyond mining activities using the experience gained from them. This has included, for example, the preservation and accessibility of the subsoil of medieval towns and the revitalization of towns with a predominantly industrial character. Work has also been conducted to rehabilitate sites and facilities for additional public use.
The most important directions of solutions in the field of the reclamation and revitalization of post-mining areas developed with the participation of the faculty staff as well as in cooperation with national and international researchers are in this article. The continuous development of the Faculty is also reflected in its name changes: from the Faculty of Mining, through the Faculty of Mining and Geoengineering, to the Faculty of Civil Engineering and Resource Management. The current name reflects the actual scope of the subject matter undertaken in research and teaching, specifically the management of natural mineral deposits and also of secondary resources that should be reused in a closed cycle.
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Autorzy i Afiliacje

Ryszard Uberman
1
ORCID: ORCID
Marek Cała
2
ORCID: ORCID
Anna Maria Ostręga
2
ORCID: ORCID

  1. Mineral and Energy Economy Research Institute, Polish Academy of Sciences, Kraków, Poland
  2. AGH University of Science and Technology, Kraków, Poland

Abstrakt

Contamination of the natural environment with petroleum pollution is still a frequent and particularly dangerous phenomenon, thus there is a need to remove these pollutants. Various types of mineral sorbents (silicate minerals, zeolites, perlite, diatomite, clay rocks) are highly valued in remediation processes due to their affordable, big selectivity and high efficiency. However, many sorbents are not resistant to moisture, which limits their use. The hydrophobization process improves the effectiveness of sorbents used in a humid environment. The DAMSORB produced by IM-POL was hydrophobized with a methanolic stearic acid solution. The use of cheap stearic acid as a modifier is economically advantageous. The evaluation of the hydrophobic properties of the modified material was performed on the basis of the results obtained from the tests: water absorption, floating on the water surface and the contact angles were determined. Tests of the sorption of petroleum-derived compounds were performed on the basis of three procedures: in accordance with the technical sheet of the leading producer of hydrophobic sorption materials in Poland, the Westighouse’s method in the oil layer and the Westighouse’s method on a flat surface. The modified sorbent floats on the surface of the water very well. The average value of the contact angle for the modified sample is 104 degrees. Material is super hydrophobic. In the water environment, the hydrophobized samples have a higher absorption capacity in relation to oil contaminations compared to the raw material. Features of the modified sorbent, such as good buoyancy on the water surface, low affinity to water and better absorption of oil from the solution, make it possible to use the material to remove petroleum contamination from water and highly moist surfaces.
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Autorzy i Afiliacje

Elżbieta Vogt
1
ORCID: ORCID
Karolina Topolska
1

  1. AGH University of Science and Technology, Kraków, Poland

Dodatkowe informacje

The subject matter of the articles published in Mineral Resources Management covers issues related to minerals and raw materials, as well as mineral deposits, with particular emphasis on:

  • The scientific basis for mineral resources management,
  • The strategy and methodology of prospecting and exploration of mineral deposits,
  • Methods of rational management and use of deposits,
  • The rational exploitation of deposits and the reduction in the loss of raw materials,
  • Mineral resources management in processing technologies,
  • Environmental protection in the mining industry,
  • Optimization of mineral deposits and mineral resources management,
  • The rational use of mineral resources,
  • The economics of mineral resources,
  • The raw materials market,
  • Raw materials policy,
  • The use of accompanying minerals,
  • The use of secondary raw materials and waste,
  • Raw material recycling,
  • The management of waste from the mining industry.

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