There are a huge number of objects constituting a storage place of coal mining waste in the coal basins in Poland and around the world. The article is a continuation of the study on the possibilities of using raw materials deposited on the coal mining waste dumping grounds on the example of the Przezchlebie dumping ground. The possibility of coal recovery from mining waste located on the dumping ground was analyzed. Tests on the quality parameters of waste were carried out, i.e. moisture and ash content, as well as the calorific value of raw waste. The relatively high calorific value and low ash content in the waste served as the basis for further tests related to the separation of coal. Tests on the mining waste enrichment using the complex based on the K-102 Komag pulse separator were carried out. As a result of coal separation, 7.66% of concentrate was obtained (in relation to feed) with the calorific value of 26.16 MJ/kg and ash content of 19.96%. Apart from mining waste, power plant waste (fly ash) can also be found on the dumping ground. They were subjected to tests for the possibility of using them in the production of construction materials, especially concrete and cement. Fly ash from the Przezchlebie dumping ground was classified as silica ash and it was found that it meets the requirements of Polish standard, except for the fineness of 42%. The separation of coal will eliminate the fire hazard on the dumping ground. A possible scenario of managing waste material on a dumping ground, which can be implemented in similar facilities, has been presented.
As of the spring of 2017, the HAŁDY Database is available on the Polish Geological Institute – NRI website. The geodatabase contains information and data on waste mineral raw materials collected on old heaps, industrial waste stock-piles and in post-mining settlers, from the Polish part of the Sudety Mountains. The article presents the types of data and information contained in the geodatabase and the methodology for their collection. As a result of four-year research works, field reconnaissance, archives and geological basic research, 445 objects of former mining and mineral processing were inventoried. There are 403 mine heaps, 16 industrial settlers, 23 stock-piles and 3 external dumps. These are mainly objects after coal mining and metal ores, including post-uranium. The greatest opportunities for the economic use of waste are associated with coal sludge accumulated in settlers of the liquidated Lower Silesian Coal Basin. The material from stone heaps after polymetallic, iron and fluorite ore mining is also easy to use. The issue of the economic use of post-flotation copper ore waste or the recovery of metals (including gold) from dumps of arsenic mining remains open. The limitation here is the efficiency of metal recovery technologies and environmental restrictions. Some of the objects are located in protected areas, which excludes the possibility of waste management. Some stock-piles and heaps should be carefully reclaimed and covered by environmental monitoring, due to their harmful impact on environmental components.
Hydrogen is the fuel of the future, therefore many hydrogen production methods are developed. At present, fuel cells are of great interest due to their energy efficiency and environmental benefits. A brief review of effective formation methods of hydrogen was conducted. It seems that hydrogen from steam reforming of methanol process is the best fuel source to be applied in fuel cells. In this process Cu-based complex catalysts proved to be the best. In presented work kinetic equations from available literature and catalysts are reported. However, hydrogen produced even in the presence of the most selective catalysts in this process is not pure enough for fuel cells and should be purified from CO. Currently, catalysts for hydrogen production are not sufficiently active in oxidation of carbon monoxide. A simple and effective method to lower CO level and obtain clean H2 is the preferential oxidation of monoxide carbon (CO-PROX). Over new CO-PROX catalysts the level of carbon monoxide can be lowered to a sufficient level of 10 ppm.