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Abstract

The paper presents the results of research related to the possibility of inoculation of the AZ91 magnesium alloy casted into ceramic moulds by gadolinium. Effects of gadolinium content (0.1–0.6 wt%) on microstructure of the AZ91 alloy under as-cast state were investigated. The influence of the inoculator on the formation of the microstructure investigated by means of the thermal and derivative analysis by analysing the thermal effects arising during the alloy crystallization resulting from the phases formed. The degree of fragmentation of the microstructure of the tested alloys was assessed by means of the light microscopy studies and an image analysis with statistical analysis was performed. Conducted analyses have aimed at examining on the effect of inoculation of the gadolinium on the differences between the grain diameters and average size of each type of grain by way of measuring their perimeters of all phases, preliminary αMg and eutectics αMg+γ(Mg17Al12) in the prepared examined material.
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[2] Yu, Zhang et. al (2017). Effects of samarium addition on as-cast microstructure, grain fragmentation and mechanical properties of Mg-6Zn-0.4Zr magnesium alloy. Journal of Rare Earths. 167(1), 31-33. DOI: 10.1016/S1002-0721(17)60939-6.
[3] Cao, F.Y, Song, G.L. & Atrens, A. (2016). Corrosion and passivation of magnesium alloys. Corrosion Science, 111(10), 835-845. DOI: 10.1016/j.corsci.2016.05.041.
[4] Mao, X., Yi, Y., Huang, S. & He, H. (2019). Bulging limit of AZ31B magnesium alloy tubes in hydroforming with internal and external pressure. The International Journal of Advanced Manufacturing Technology. 101, 2509-2517. DOI: https://doi.org/10.1007/s00170-018-3076-5.
[5] Władysiak, R. & Kozuń, A. (2015). Structure of AlSi20 alloy in heat treated die casting. Archives of Foundry Engineering.15(1), 113-118. DOI: 10.1515/afe-2015-0021.
[6] Rapiejko, C., Pisarek, B. & Pacyniak, T. (2017). Effect of intensive cooling of alloy AZ91 with a chromium addition on the microstructure and mechanical properties of the casting. Archives of Metallurgy and Materials. 62(4), 2199-2204. DOI: 10.1515/amm-2017-0324.
[7] Zhao, H.L., Guan, S.K. & Zheng, F.Y. (2007). Effects of Sr and B addition on microstructure and mechanical properties of AZ91 magnesium alloy. Journal of Materials Research. 22, 2423-2428. DOI: 10.1557/jmr.2007.0331.
[8] Bonnah, R.C., Fu, Y. & Hao, H. (2019). Microstructure and mechanical properties ofAZ91 magnesium alloy with minor additions of Sm, Si and Ca elements. China Foundry. 16(5), 319-325. DOI: 10.1007/s41230-019-9067-9.
[9] Jafari, H. & Amiryavari, P. (2016). The effects of zirconium and beryllium on microstructure evolution, mechanical properties and corrosion behaviour of as-cast AZ63 alloy. Materials Science & Engineering A. 654, 161-168 DOI: 10.1016/j.msea.2015.12.034.
[10] Boby, A., Ravikumar, K.K., Pillai, U.T.S. & Pai, B.C. (2013). Effect of antimony and yttrium addition on the high temperature properties of AZ91 magnesium alloy. Procedia Engineering 55. 355(5), 98-102. DOI: 10.1016/j.proeng. 2013.03.226.
[11] Huang, W., Yang, X., Mukai, T. & Sakai, T. (2019). Effect of yttrium addition on the hot deformation behaviors and microstructure development of magnesium alloy. Journal of Alloys and Compounds. 786, 118-125. DOI: 10.1016/ j.jallcom.2019.01.269.
[12] Pourbahari, B., Mirzadeh, H., Emamy, M. & Roumina, R. (2018). Enhanced ductility of afine-grained Mg-Gd-Al-Zn magnesium alloy by hot extrusion. Advanced Engineering Materials. 20, 1701171. DOI: 10.1002/adem.201701171.
[13] Tardif, S., Tremblay, R. & Dubé, D. (2010). Influence of cerium on the microstructure and mechanical properties of ZA104 and ZA104 + 0.3Ca magnesium alloys. Material Science and Engineering A. 527, 7519-7529. DOI: 10.1016/j.msea.2010.08.082.
[14] Wang, X.J. et al. (2018). What is going on in magnesium alloys? Journal of Materials Science & Technology. 34(2), 245-247. DOI: 10.1016/j.jmst.2017.07.019.
[15] Nan, J. et. al (2016) Effect of neodymium, gadolinium addition on microstructure and mechanical properties of AZ80 magnesium alloy. Journal of Rare Earths. 34(6), 632-637. DOI: 10.1016/S1002-0721(16)60072-8.
[16] Miao, Y., Yaohui, L., Jiaan, L. & Yulai, S. (2014). Corrosion and mechanical properties of AM50 magnesium alloy after being modified by 1 wt.% rare earth element gadolinium. Journal of Rare Earth. 723, 558-563. DOI: 10.1016/S1002-0721(14)60108-3.
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[20] PN-EN 1753:2001. Magnesium and magnesium alloys. Magnesium alloy ingots and castings.
[21] Rapiejko, C., Pisarek, B, Czekaj, E. & Pacyniak, T. (2014). Analysis of AM60 and AZ91 Alloy Crystallisation in ceramic moulds by thermal derivative analisys (TDA). Archive of Metallurgy and Materials. 59(4) DOI: 10.2478/amm-2014-0246.
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Authors and Affiliations

C. Rapiejko
1
ORCID: ORCID
D. Mikusek
1
P. Just
1
T. Pacyniak
1
ORCID: ORCID

  1. Lodz University of Technology, Department of Materials Engineering and Production Systems, ul. Stefanowskiego 1, 90-924 Łódź, Poland
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Abstract

The mathematical model and numerical simulations of the solidification of a cylindrical casting, which take into account the process of the mould cavity filling by liquid metal and the feeding of the casting through the conical riser during its solidification, are proposed in the paper. The interdependence of thermal and flow phenomena were taken into account because they have an essential influence on solidification process. The effect of the pouring temperature and pouring velocity of the metal on the solidification kinetics of the casting was determined. In order to obtain the casting without shrinkage defects, an appropriate selection of these parameters was tried, which is important for foundry practice. The velocity fields have been obtained from the solution of Navier-Stokes equations and continuity equation, while temperature fields from solving the equation of heat conductivity containing the convection term. In the solidification modelling the changes in thermo-physical parameters as a function of temperature were considered. The finite element method (FEM) was used to solve the problem.

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Authors and Affiliations

L. Sowa
ORCID: ORCID
T. Skrzypczak
ORCID: ORCID
P. Kwiatoń
ORCID: ORCID
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Abstract

The present work studies the tribological properties of new hybrid material composed from high porosity open cell aluminum alloy (AlSi10Mg) skeleton and B83 babbitt infiltrated into it. The porous skeleton is obtained by replication method applying salt (NaCl) as space holder. The reinforcing phase of the skeleton consists of Al2O3 particles. The skeleton contains Al2O3 particles as reinforcement. The microstructure of the obtained materials is observed and the tribological properties are determined. A comparison between tribological properties of nominally nonporous aluminum alloy, high porosity open cell skeleton, babbitt alloy and the hybrid material is presented. It is concluded that new hybrid material has high wear resistivity and is a promising material for sliding bearings and other machine elements with high wear resistivity.

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Authors and Affiliations

M. Kolev
L. Drenchev
L. Stanev
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Abstract

The application of hardfacing is one of the ways to restore the functional properties of worn elements. The possibility of using filler materials rich in chrome allows for better wear resistance than base materials used so far. The paper presents the results of research on the use of 3 different grades of covered electrodes for the regeneration of worn track staves. The content of the carbon in the covered electrodes was from 0,5% to 7% and the chromium from 5% to 33%. The microscopic and hardness tests revealed large differences in the structure and properties of the welds. The differences in the hardness of the welds between the materials used were up to 150 HV units. The difference in wear resistance, in the ASTM G65 test, between the best and worst materials was almost 12 times big.

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Authors and Affiliations

M. Gucwa
J. Winczek
P. Wieczorek
M. Mičian
ORCID: ORCID
R. Koňár
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Abstract

This study aimed to prepare Zr55Cu30Al10Ni5 bulk amorphous alloys by spark plasma sintering of raw amorphous alloy powders and investigate their microstructure and micromechanical behaviors. When the sintering temperature ( Ts) was 675K, which was lower than the glass transition temperature ( Tg) of the material, the sintered sample was almost fully amorphous but the density was lower. However, when Ts was 705K, which was higher than Tg, partial crystallization occurred, but the density was higher. The hardness of the bonding zone of the sintered sample at 675K was 5.291 GPa due to the lower density, which was lower than that at 705K, and the hardness at 705K was 8.836 GPa. The generation of thermodynamically stable intermetallic phases, the hardness, and the elastic modulus of the samples sintered above Tg were higher due to the higher density.
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Authors and Affiliations

Yaqiong Ge
1
Zexin Chang
1
Wenxian Wang
1
Qingling Hou
1

  1. Taiyuan University of Science and Technology, College of Materials Science and Engineering, Taiyuan 030024, China
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Abstract

Mount Flora at Hope Bay, in northernmost part of Antarctic Peninsula, is a famous Jurassic flora locality. It has already been studied for a hundred years, but however, it is still possible to find there new taxa. Based on two species of liverworts found at Mount Flora (Schizolepidella gracilis and Schizolepidella birkenmajeri sp. nov.), the present study discusses affiliation of the genus Schizolepidella to liverworts. The new species Schizolepidella birkenmajeri is erected.

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Authors and Affiliations

Anna Maria Ociepa
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Abstract

A. B. Dobrowolski, a member of the Belgian expedition in Belgica to West Antarctica (1897-1899), after his return home became a strong supporter of Polish scientific activity in the Polar countries. His patronage - called by him the "Polar Action", was especially well marked during organization of three Polish expeditions to the Svalbard archipelago: to Bear Island during the 2nd Polar Year, 1932-33 and to Spitsbergen in 1934 and 1938. Apart from his scientific achievements in Antarctica, Dobrowolski was also widely known as an author of popular-scientific books on history of discovery and exploration in the Arctic and the Antarctic.

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Authors and Affiliations

Joanna Popiołek
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Abstract

The objective of this study was to determine the suitability of the nanofi ltration (NF) process to recover the regenerating agent (NaOH) from spent solutions contaminated with organic compounds. NaOH recovery from 2 spent regenerant solutions after cleaning ultrafiltration (UF) membranes (polymeric 30 kDa, ceramic 300 kDa) fouled with natural humic water was carried out using 2 types of NF membranes: NP010P (Na2SO4 rejection: 35–75%) and NP030P (Na2SO4 rejection: 80–95%). It has been shown that the use of the NP030P membrane allows for very high separation effi ciency of organic compounds (up to 97% of color intensity reduction) from the tested solutions. It was also observed that the effectiveness of the process, in addition to the type of membrane used, also depends on the time of NF process – along with the elapsed time of the process, the hydraulic and separation properties of the tested membranes deteriorated. The obtained results showed that the use of both tested NF membranes allows for the recovery of NaOH to a degree that allows its re-use.

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Authors and Affiliations

Agnieszka Urbanowska
Małgorzata Kabsch-Korbutowicz
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Abstract

The paper discusses the use of multiclustering statistical analysis in the assessment of domestic wastewater filtration effectiveness. Calculations included data collected over four months of experiments with using waste as filling material of vertical flow filters for domestic sewage treatment. The effectiveness of pollutants removal was analysed in case of me-chanically shredded waste in the form of PET flakes, PUR foam trims, shredded rubber tires and wadding. The organic compounds (CODcr, BOD5) removal, suspend solids, biogens (as NH4+, PO43– ions) and oxygen saturation changing com-pared with sand filling was analysed. Multiclustering statistical analysis allowed to divide pollutants removal efficiency of analysed materials into 3 clusters, depending on the hydraulic loading. The first group consisted in quality parameters of treated sewage: the highest reduction of BOD5 and NH4-N. It included the values of quality parameters and indicators for the filtrates obtained at the lowest hydraulic load from columns filled with 60 cm of rubber tires or sand. The second group comprised the results for fillings containing foam, PET and rubber tires (the other hydraulic loads).It featured the highest reduction of total suspended solids and PO43–. Removal of easily biodegradable organic compounds was at a similar level in both cluster groups. The filter filled with polyester waste (wadding), which was as effective as 30 cm layer of sand, and the filters filled with 60 cm of sand working at the highest hydraulic load. Third group showed the lowest values of parameters and indicators for analysed filtrates.

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Authors and Affiliations

Dawid Bedla
Ewa Dacewicz
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Abstract

The problem of harmful casting resins has been present in foundries for many years. Manufacturers are introducing new products that contain in their composition environmentally and eco-friendly ingredients. Unfortunately, not all types of technology can be used, sometimes environmental benefits are disproportionate to the quality of castings and their price. In the foundry industry, the most popular binders are based on organic compounds (often carcinogenic) and other harmful substances. Due to strict legal regulations regarding environmental protection, as well as care for the foundry's workers' comfort - their occurrence should be reduce to a minimum. These compounds often behave also depending on the conditions of use (temperature, atmosphere). The application of various methods of thermal analysis and spectroscopic methods allows to verify the mechanism of resin decomposition process in relation to conditions in the form in both inert and oxidizing atmosphere. For analysis the resins from cold-box technology, were used TG–DTG–DSC, Py-GC/MS methods and specified the course of changes occurring in combination of different atmosphere.

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Authors and Affiliations

S. Żymankowska-Kumon
K. Kaczmarska
B. Grabowska
A. Bobrowski
S. Cukrowicz
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Abstract

The paper describes the studies of ternary SnZn9Al1.5 lead-free alloy from the viewpoint of its mechanical behavior as well as microstructure examined by the light and scanning electron microscopy. The authors focused their attention specifically on the fatigue parameters determined by the original modified low-cycle fatigue method (MLCF), which in a quick and economically justified way allows determination of a number of mechanical parameters based on the measurement data coming from one test sample only. The effect of the addition of 1.5% Al to the binary eutectic SnZn9 alloy on its microstructure and the obtained level of mechanical parameters was analyzed. The phases and intermetallic compounds occurring in the alloy were identified based on the chemical analysis carried out in micro-areas by the SEM/EDS technique. It was shown that the addition of 1.5% Al to the binary eutectic SnZn9 alloy resulted in a more favorable microstructure and consequently had a positive effect on the mechanical parameters of the alloy. Based on the conducted research, it was recommended to use a combinatorial method based on the phase quanta theory to quickly evaluate the microstructure and the original MLCF method to determine a number of mechanical parameters.
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Authors and Affiliations

M. Maj
K. Pietrzak
A. Klasik
N. Sobczak
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Abstract

The goal of this paper is to explore and to provide tools for the investigation of the problems of unit-length scheduling of incompatible jobs on uniform machines. We present two new algorithms that are a significant improvement over the known algorithms. The first one is Algorithm 2 which is 2-approximate for the problem Qm|pj  = 1, G = bisubquartic|Cmax. The second one is Algorithm 3 which is 4-approximate for the problem Qm|pj  = 1, G = bisubquarticCj, where m ∈ {2, 3, 4}. The theory behind the proposed algorithms is based on the properties of 2-coloring with maximal coloring width, and on the properties of ideal machine, an abstract machine that we introduce in this paper.

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Authors and Affiliations

T. Pikies
M. Kubale

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