In the present work, different Cu-alloyed model ductile irons with ferritic (0%Cu-0.09%Mn), mixed ferritic-pearlitic (0.38%Cu-0.40%Mn) and pearlitic (0.69%Cu-0.63%Mn) microstructure were produced and analyzed in terms of their electrochemical corrosion behavior in a 3.5wt.%NaCl aqueous solution containing naturally dissolved oxygen at room temperature (25°C). The remaining elements such as Si and Mg were kept at balanced levels in an attempt to minimize variations in graphite size and distribution among different samples. The corrosion resistance was evaluated by electrochemical impedance spectroscopy and potentiodynamic polarization. Microstructure analysis of the cast alloys confirmed similarity in the graphite morphology among the different cast samples and the expected variations in the metallic matrix. In the absence of passivation, it was found that the addition of copper led to an increase in corrosion resistance, which could be attested by higher values polarization resistance and corrosion potential.
This paper presents a voltammetric segmented voltage sweep mode that can be used to identify and measure heavy metals' concentrations. The proposed sweep mode covers a set of voltage ranges that are centered around the redox potentials of the metals that are under analysis. The heavy metal measurement system can take advantage of the historical database of measurements to identify the metals with higher concentrations in a given geographical area, and perform a segmented sweep around predefined voltage ranges or, alternatively, the system can perform a fast linear voltage sweep to identify the voltammetric current peaks and then perform a segmented voltage sweep around the set of voltages that are associated with the voltammetric current peaks. The paper also includes the presentation of two auto-calibration modes that can be used to improve system's reliability and proposes the usage of a Gaussian curve fitting of voltammetric data to identify heavy metals and to evaluate their concentrations. Several simulation and experimental results, that validate the theoretical expectations, are also presented in the paper.
This paper presents a low-cost and smart measurement system to acquire and analyze mechanical motion parameters. The measurement system integrates several measuring nodes that include one or more triaxial accelerometers, a temperature sensor, a data acquisition unit and a wireless communication unit. Particular attention was dedicated to measurement system accuracy and compensation of measurement errors caused by power supply voltage variations, by temperature variations and by accelerometers’ misalignments. Mathematical relationships for error compensation were derived and software routines for measurement system configuration, data acquisition, data processing, and self-testing purposes were developed. The paper includes several simulation and experimental results obtained from an assembled prototype based on a crank-piston mechanism
This paper presents a methodology for contact detection between convex quadric surfaces using its implicit equations. With some small modifications in the equations, one can model superellipsoids, superhyperboloids of one or two sheets and supertoroids. This methodology is to be implemented on a multibody dynamics code, in order to simulate the interpenetration between mechanical systems, particularly, the simulation of collisions with motor vehicles and other road users, such as cars, motorcycles and pedestrians.
The contact detection of two bodies is formulated as a convex nonlinear constrained optimization problem that is solved using two methods, an Interior Point method (IP) and a Sequential Quadratic Programming method (SQP), coded in MATLAB and FORTRAN environment, respectively. The objective function to be minimized is the distance between both surfaces. The design constraints are the implicit superquadrics surfaces equations and operations between its normal vectors and the distance itself. The contact points or the points that minimize the distance between the surfaces are the design variables. Computational efficiency can be improved by using Bounding Volumes in contact detection pre-steps. First one approximate the geometry using spheres, and then Oriented Bounding Boxes (OBB).
Results show that the optimization technique suits for the accurate contact detection between objects modelled by implicit superquadric equations.
The combination of the austempered ductile iron mechanical properties strongly depend on the parameters used on the austempering cycle. On this study, the influence of austempering time and austenitizing temperature on the properties of a ductile iron were evaluated. A metallic bath of Zamak at 380°C was used as an austempering mean. A set of ductile iron blocks were austenitized at 900°C for 90 minutes and submitted to different austempering times in order to determine the best combination of microstructural and mechanical properties. After the definition of the time of austempering, the reduction of the austenitizing temperature was evaluated. The best combination of properties was obtained with austenitizing at 860°C and austempering during 60 minutes.