Heat transport when two surfaces of solids come into contact is an important phenomenon in many metallurgical processes. Determining the boundary conditions of heat transfer allows to obtain the correct solutions of the heat conduction equation. The paper presents models for determining the heat transfer coefficient between steel materials in contact. Experimental tests were carried out to measure the temperature changes of the contacting samples made of steel S235 (1.0038) and steel 15HM (1.7335) under the pressure of 10, 15 and 20 MPa. There was a large temperature difference between the samples. The results of the experiment were compared with numerically calculated temperatures and the value of the heat transfer coefficient was determined at different pressure values depending on the time.
The tundish prevents unsteady flow affecting on the steel cleanness and temperature. The presented article offers a new design of a ladle shroud (LS) with three holes placed in a special dome (separating the steel flow) steeped in a metal bath. Various options of the LS construction were analysed, as well as its positioning in the tundish in relation to its longitudinal axis. The conducted numerical simulations enabled to assess the impact of the designed ladle shroud on the flow of liquid steel through the tundish. The results showed that the best option is to use the LS with two larger holes and one smaller which activates the flow structure and reduces the rate of the liquid steel velocity in the tundish, limiting the flow turbulence.
Czestochowa University of Technology, Faculty of Production Engineering and Materials Technology, Department of Metallurgy and Metals Technology, 19 Armii Krajowej Av., 42-200 Czestochowa, Poland
The article presents the results of tests of plastic shaping of magnesium alloy Mg-Li. Magnesium alloy for an extrusion process was obtained with the method of vacuum smelting and casting into graphite moulds. The materials for tests were slabs cast from magnesium alloys with symbols: Mg-4%Li-1%Ca (LX41). Before the process of deformation the castings were subject to homogenization. Conventional extrusion tests were conducted in a complex state of deformation (KoBo method). An assessment was performed of the influence of the deformation process parameters on the structure and properties of the tested alloy. Results of mechanical tests were presented both for static compression test in room temperature. On the basis of the achieved tests results, the susceptibility to plastic working for the Mg-4%Li-1%Ca alloy was determined. An analysis of the microstructure was conducted both in the initial condition and after plastic deformation with the use of light and scanning microscopy techniques. The applied deformation methods allowed the determination of the influence of process parameters on changes in the microstructure and properties of the Mg-4%Li-1%Ca alloy.
The inverse solution to the heat flux identification during the vertical plate cooling in air has been presented. The developed solution allowed to separate the energy absorbed by the chamber due to radiation from the convection heat losses to air. The uncertainty tests were carried out and the accuracy of the solution has been estimated at a level of 1%-5% depending on the boundary condition model. The inverse solution was obtained for the temperature measurements in the vertical plate. The stainless-steel plate was heated to 950°C and then cooled in the chamber in air only to about 30°C. The identified heat transfer coefficient was compared with the Churchill and Chu model. The solution has allowed to separate the radiation heat losses and to determine the Nusselt number values that stay in good agreement with the Churchill and Chu model for a nearly steady-state air flow for the plate temperature below 100°C.
AGH University of Science and Technology, Faculty of Metals Engineering and Industrial Computer Science, Department of Heat Engineering and Environment Protection, al. Mickiewicza 30, 30-059 Kraków, Poland
AGH University of Science and Technology, Faculty of Energy and Fuels, al. Mickiewicza 30, 30-059 Kraków, Poland
This paper reports on the flexural properties of thin fly ash geopolymers exposed to elevated temperature. The thin fly ash geopolymers (dimension = 160 mm × 40 mm × 10 mm) were synthesised using12M NaOH solution mixed with designed solids-to-liquids ratio of 1:2.5 and Na2SiO3/NaOH ratio of 1:4 and underwent heat treatment at different elevated temperature (300°C, 600°C, 900°C and 1150°C) after 28 days of curing. Flexural strength test was accessed to compare the flexural properties while X-Ray Diffraction (XRD) analysis was performed to determine the phase transformation of thin geopolymers at elevated temperature. Results showed that application of heat treatment boosted the flexural properties of thin fly ash geopolymers as the flexural strength increased from 6.5 MPa (room temperature) to 16.2 MPa (1150°C). XRD results showed that the presence of crystalline phases of albite and nepheline contributed to the increment in flexural strength.
A fading mechanism during casting of treated Al-B-Sr master alloys in an aluminium-silicon cast alloy was investigated. Two different master alloys, the Al-3%B-3%Sr and Al-4%B-1%Sr were demonstrated for the efficiency test both grain refinement and modification microstructure. From experimental result, the addition of Al-3%B-3%Sr master alloy led to a refined grain size and fully modified eutectic Si. However, smaller grain sizes were found with Al-4%B-1%Sr master alloy addition while eutectic Si had coarser acicular morphology. The formation of high amounts of SrB6 compound in the Al-3%B-3%Sr master alloy resulted to increase of grain size and eutectic Si. In fading mechanism test when holding the melt for prolong time, the agglomeration of the SrB6 and AlSiSr compounds at the bottom of the casting specimen was important factors that decreased both grain refinement and modification efficiency. The stirring of the melt before pouring was found that the grain size and Si morphology were improved.
University of Technology North Bangkok, Faculty of Engineering, Department of Materials and Production Technology Engineering, King Mongkut’s Bangkok, Thailand
This paper presents a comparative study on the effects of the in-situ surface modifications performed on “H” type microfluidic systems obtained via additive manufacturing. The microsystem was printed using a polylactic acid filament on an Ender-5 Pro printer. The surface modification of the main channel was done using chloroform by two different methods: vapor smoothing and flushing. The obtained surface roughness was studied using an optical microscope and the ImageJ software, as well as scanning electron microscopy. The effect of the channel surface treatment upon the characteristics of the fluid flow was assessed. The microfluidic systems were used for the dynamic study of biofilm growth of Candida albicans (ATCC 10231). The influence of the surface roughness of the main channel on the formation and growth of the biofilm was studied using quantitative methods, scanning electron microscopy imaging as well as optical coherence tomography.
The composition and structural modification of aluminium alloys influence their strength, tribological properties and structural stability. The phase composition of the structure as well as the characteristics of the elementary cell of each identified phase was established by X-ray diffraction, and the main objective was to determine the compositional phases, microstructure and microcomposition of the alloy. Based on the cyclic voltammograms it can be said that on the OCP interval (+1.5 V… –1.1 V), after the breakthrough potential is an intensification of the anodic process by the pronounced increase of the current density, in these conditions the Al-Si alloy has low values which means that it has a better corrosion resistance.
The article presents the developed IT solutions supporting the material and technological conversion process in terms of the possibility of using the casting technology of selected alloys to produce products previously manufactured with the use of other methods and materials. The solutions are based on artificial intelligence, machine learning and statistical methods. The prototype module of the information and decision-making system allows for a preliminary assessment of the feasibility of this type of procedure. Currently, the selection of the method of manufacturing a product is based on the knowledge and experience of the technologist and constructor. In the described approach, this process is supported by the proprietary module of the information and decision-making system, which, based on the accumulated knowledge, allows for an initial assessment of the feasibility of a selected element in a given technology. It allows taking into account a large number of intuitive factors, as well as recording expert knowledge with the use of formal languages. Additionally, the possibility of searching for and collecting data on innovative solutions, supplying the knowledge base, should be taken into account. The developed and applied models should allow for the effective use and representation of knowledge expressed in linguistic form. In this solution, it is important to use methods that support the selection of parameters for the production of casting. The type, number and characteristics of data have an impact on the effectiveness of solutions in terms of classification and prediction of data and the relationships detected.
The research focused on TiO2 nanostructures environmental applications due to the special characteristics that displayed degradation of the organic compounds into environmentally friendly products through exposure to UV light. The protocol behind obtaining the nanostructures involved the use of a Ti material exposed to alkaline treatment and advanced oxidation using NaOH solution and acetone. These studied nanostructures were analyzed extensively by using methods such as scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD) for characterizing the elements, compounds and morphological properties of the material. These differences in morphology is attributed to different NaOH solution concentrations. The Ti sheets were immersed into NaOH and acetone mixed solutions for 72 hours. The best results were recorded by using 30% NaOH solution. After obtaining the 3D structures, which improve specific surface and contact area with the environment, the samples were tested under UV light in order to degrade methylene blue in order to determine their photocatalytic performance.
University Politehnica of Bucharest, Faculty of Materials Science and Engineering, Department of Materials Processing and Ecometallurgy, 313 Splaiul Independentei, 060042, Bucharest, Romania
This study evaluated the effect of milling speed and compaction pressure on the densification and morphology of the CuZn-Gr composite. The composite was prepared by using the powder metallurgy technique. The effect on the microstructural and compaction was determined based on different milling speeds. The different milling speeds involved were 175, 200, 225, and 250 rpm. Meanwhile, the different compaction pressures used in this study were 127, 250, 374, and 500 MPa. The properties of the milled powder gave the result to green density and densification parameters. The XRD pattern of Cu and Zn broadened as milling time increased.
Universiti Malaysia Kelantan, Faculty of Bioengineering and Technology, 17600 Jeli Kelantan, Malaysia
Urich Technology (KC0023880-A), No. 457, Lorong 7/1, Taman Semarak, 08000 Sungai Petani, Kedah, Malaysia
Universiti Malaysia Perlis, Faculty of Mechanical Engineering Technology, Perlis, Malaysia
Universiti Malaysia Perlis, Center of Excellence Geopolymer and Green Technology (CEGeoGTech), Perlis, Malaysia
Sharda University, School of Basic Sciences and Research, Department of Physics, Center of Excellence on Solar Cells & Renewable Energy, Greater Noida, Uttar Pradesh 201308, India
The parameters of the injection moulding process have a significant influence on the properties of the moulded parts. Selection of appropriate injection conditions (e. g. the injection temperature, mould temperature, injection and holding pressure, injection speed) contributes to the productivity and energy consumption of the injection moulding process as well as to the quality of the moulded parts. The aim of this study was to evaluate the influence of injection moulding parameters on properties of poly(ethylene) mouldings. Regranulate obtained from recycled film, which is a mixture of low-density poly(ethylene) and linear low-density poly(ethylene), was used for testing. Samples in the form of standardised tensile bars of type A1 were produced by injection moulding. A Krauss-Maffei KM65-160C4 injection moulding machine was used for this purpose. Variable parameters of the this process used in the study were: injection speed, mould temperature and holding pressure. The results of tensile strength tests of the obtained samples are presented. The weight and dimensions of mouldings from four different regranulates were also investigated. The effect of injection moulding conditions on the properties of poly(ethylene) mouldings was shown in the investigations. The mass of poly(ethylene) mouldings is dependent on the holding pressure.
Czestochowa University of Technology, Faculty of Mechanical Engineering and Computer Science, Department of Technology and Automation, 21 Armii Krajowej Av., 42- 201 Czestochowa, Poland
Tannic acid or tannin, type of phenolic compound contains in kenaf bast fibre. Conventional extraction has certain limitations in terms of time, energy, and solvent consumption. Ultrasound assisted extraction (UAE) can extract bioactive components in shorter time, low temperature, with lesser energy and solvent requirement. UAE as alternative extraction technique is better equipped to retain the functionality of the bioactive compounds. In this study, the conditions for ultrasound assisted extraction (UAE) of tannic acid from kenaf bast fibre by assessing the effect of sonication time and different duty cycles were optimized. The use of ultrasound to extract tannic acid from kenaf bast fiber was evaluated. Ultrasound-assisted extraction (UAE) was carried out using ethanol as solvent to intensify the extraction efficacy. Phytochemical screening was conducted to identify the presence of tannic acid in extracts. The extracts then were analyzed using High-Performance Liquid Chromatography (HPLC) and Scanning Electron Microscopy (SEM). It was found that 0.2429 mg/mL of tannic acid was obtained under the extraction conditions of extraction temperature of 40℃, sonication time of 20 minutes and duty cycle of 50%. From SEM analysis, it was found that the raw sample demonstrated rough surface and no porous but kenaf bast fibre display smoother surface with less impurities and few pores appeared after the extraction process using UAE. These results indicate that ultrasound-assisted extraction is an efficient method for extracting tannic acid from kenaf bast fibre with the advantages of lower extraction time and higher extraction yield.
In this work, zinc oxide (ZnO) thin films are deposited on glass substrate using the sol-gel spin coating technique. The effect of annealing temperature on structural properties was investigated. The ZnO sol-gel was produced from zinc acetate dehydrate as the starting material with iso-propanol alcohol as the stabilizer. The ratio was controlled, distilled water and diethanolamine as the solvent mixing on a magnetic stirrer for an hour under constant heat of 60°C. The ZnO thin film was deposited using the spin coating technique with the speed of 3000 rpm for 30 minutes before the sample undergoes pre-heat in the oven at the temperature of 100°C for 10 minutes. The sample was annealing in the furnace for an hour at 200°C, 350°C, and 500°C. The X-ray diffraction (XRD) analysis confirms that hexagonal wurtzite structure with zincite and zinc acetate hydroxide hydrate composition. The thin films surface roughness was analyzed using an atomic force microscope (AFM) and scanning electron microscope (SEM) for surface morphology observation.
Universiti Tun Hussein Onn Malaysia, Faculty of Engineering Technology, Department of Mechanical Engineering Technology, Jalan Edu Hub Gunasama1, Pagoh Edu Hub, KM1, Jln Panchor, 84600 Pagoh Johor, Malaysia
Universiti Tun Hussein Onn Malaysia, Faculty of Mechanical and Manufacturing Engineering, Parit Raja, 86400 Batu Pahat, Johor, Malaysia
Universiti Malaysia Perlis, Center of Excellence Geopolymer and Green Technology (CEGeoGTech), Perlis, Malaysia
Universiti Tun Hussein Onn Malaysia, Faculty of Mechanical and Manufacturing Engineering, Integrated Material and Process, Advanced Manufacturing & Materials Centre, Parit Raja, 86400 Batu Pahat, Johor, Malaysia
Universiti Malaysia Perlis, Faculty of Mechanical Engineering Technology, Perlis, Malaysia
Microalloying elements such as Ti, Nb, V, entered into steel they influence their microstructure and mechanical properties, because formation of carbonitrides, M(C,N). Influence of carbonitrides to the microstructure and mechanical properties depends on their basic stereological parameters: volume fraction, Vv, and their size, r. In this work the Cellular Automata model of the kinetics of the carbonitrides precipitation which enable to predict the image of the microstructure and calculate the size of carbonitrides formed during isothermal annealing of supersaturated steel is presented. In the high temperature the microalloying elements inhibit the austenite grains growth. Chemical composition of steel has influence to volume fraction and size of precipitations. The work is supplemented with examples of experimental comparison.
An investigation of the failure process of maraging steel grade X3NiCoTi18-9-5 produced by the SLM method that is subjected to various three-dimensional stress-states has been carried out. In this paper, deformations and damage evolution are analysed experimentally and numerically. Three microstructures of the SLM steel were obtained after the appropriate heat treatment. Tensile tests of smooth specimens and axisymmetric notched specimens have been performed. Numerical models of the samples with ring notches were made in order to determine the stress state and displacement field in the notch area at the moment of the sample’s breakage as well as to compare the experimentally determined effective strain in the notch after the sample’s breakage with the deformation being calculated on the basis of the numerical solution. As a result of the research, it was found that the type of fracture of samples obtained from X3NiCoTi18-9-5 steel powder by the SLM method depends on the size of the ring notch’s radius. Based on the performed numerical calculations and experimental tests, it was found that, for each of the analysed variants of heat treatment, it was possible to indicate the approximate limit value of triaxiality factor Tf, above which there is a scrap of brittle X3NiCoTi18-9-5 steel produced by the SLM method. This value is determined by the characteristic bending of the function that determines the relationship between triaxiality factor Tfand effective strain eeff.
One of the most interesting categories of artifacts for archaeometallurgical research includes deposits of bronze items, so-called “metallurgists hoards”. They contain, aside of final products, many fragments of raw material and, moreover, metallurgical tools. An important source for the studies on the history of metallurgical technology is hoard from Przybysław, Greater Poland district. Thus, the aim of the work is the identification and interpretation of bronze-working practices and strategies adopted by prehistoric communities of the Late Bronze Age and the Early Iron Age (ca. 600 BC). The examined objects are characterized in terms of their design, structure, and chemical composition. The methods chosen for the studies of artifacts include: metallographic macro- and microscopic observations using optical microscopy (OM) and scanning electron microscopy (SEM), the analysis of chemical composition with the methods of energy dispersive X-ray spectroscopy (EDS), and X-ray fluorescence (ED-XRF). The thermodynamic analysis of the alloys was performed on the basis of the CALPHAD method. The experimental melts allowed to verify the theoretical considerations and to determine the characteristic temperatures of changes. The old casting technology can be analyzed basing on computer modeling and computer simulation methods. Simulations in the MAGMASOFT® software are a good example to illustrate how to fill a mould cavity with a molten bronze for a hoop ornament. It is also an appropriate tool to determine temperature distribution in a mould. The simulations also show the possible disadvantages with this old technology.
This paper presents an innovative solution in the form of a virtual reality (VR) and high performance computing (HPC) system dedicated to aid designing rotary forming processes with laser beam reheating the material formed. The invented method allowing a virtual machine copy to be coupled with its actual counterpart and a computing engine utilizing GPU processors of graphic NVidia cards to accelerate computing are discussed. The completed experiments and simulations of the 316L stainless steel semi-product spinning process showed that the developed VR-HPC system solution allows the manufacturing process to be effectively engineered and controlled in industrial conditions.
The article discusses benefits associated with the use of silicon carbide in the process of melting gray cast iron and ductile cast iron in induction electric furnaces. It presents the analysis of the impact of various charge materials and the addition of a variable amount of SiC and FeSi to the fixed charge when melting cast iron of grades GJS 400-15 and GJS 500-7 on mechanical properties and microstructure. Moreover, the article includes an analysis of the efficiency of carburization and the increase in the content of silicon during the application of SiC. The article also presents the results of the study of primary modification using silicon carbide at the minimum temperature of Temin eutectic and Tsol solidus. Based on analysis of the literature, conducted research, and calculations, it was found that the addition of silicon carbide has a beneficial impact on the properties of melted cast iron. The addition of SiC in the charge increases the content of C and Si without increasing the amount of contaminations. The addition of SiC at reduced pig iron presence in the charge decreases production costs, while the use of SiC as an inoculant increases both Temin and Tsol, which is beneficial from the point of view of cast iron nucleation.
Numerical simulations of the KOBO extrusion process are presented in this paper. The coupled thermomechanical Eulerian-Lagrangian approach was applied for the three-dimensional finite element model. The dynamic explicit Euler forward method was used in numerical calculations. The elastic-plastic Chaboche model assuming isotropic and kinematic hardening under variable temperature conditions was applied to describe the behaviour of the material under cyclic loading. In numerical computations Chaboche material model implemented in commercial software, as well as the proprietary one written as FORTRAN procedure were tested. The numerical results present the stress and strain distributions in the extruded material, as well as an increase of temperature due to the plastic work and friction. The shape of plastic strain zones was verified experimentally. The approach presented in the paper is a promising numerical tool to simulate the KOBO process.
Rzeszow University of Technology, Faculty of Mechanical Engineering and Aeronautics, Department of Materials Forming and Processing, 8 Powstańców Warszawy Ave., 35-959 Rzeszów, Poland
FeMnSiCrNi alloys represent a promising class of FeMnSi-based shape memory alloys (SMAs) characterized by excellent characteristics of formability and corrosion resistance. The present paper is focused on a 68Fe-18Mn-3Si-7Cr-4Ni (mass. %) SMA, produced by powder metallurgy routine, which was tested to creep, using a dual cantilever specimen holder, and analyzed by means of the dedicated software of a dynamic mechanical analyzer. The specimens were tested at five temperatures by applying, at each of them, four bending force values, during 2000 s. The variation of bending creep deflection with time, temperature and force was discussed both from the point of instant value and 1000 s-value. These results enabled plotting a space diagram of stabilized creep rate variation with both applied force and test temperature. In such context, a theoretical model in a multifractal paradigm of motion was built, considering that FeMnSiCrNi shape memory alloy can be assimilated, both structurally and functionally, with a multifractal object. Finally, this model was validated by means of experimental data.
In this study, microstructure, mechanical, corrosion and corrosive wear properties of Mg-xAg the as-cast and extruded alloys (x: 1, 3 and 5 wt. % Ag) were investigated. According to the experimental results, as the amount of Ag added in the casting alloys increases, the secondary phases (Mg4Ag, Mg54Ag17) emerging in the structure have become more clarified. Furthermore, it was observed that as the amount of Ag increased, the grain size decreased and thus the mechanical properties of the alloys increased. Similarly, the extrusion process enabled the grains to be refined and the mechanical properties to be increased. As a result of the in vitro tests performed, the Mg-1Ag exhibited very bad corrosion properties compared to other alloys. On the other hand, according to corrosive wear tests results, a high wear rate and friction coefficient were found for Mg-5Ag alloys.
The Ti-Zr and Ti-Zr/sol-gel were used as pretreatment layers before the electroless nickel coating on AM60B magnesium alloy. Scanning Electron Microscopy was employed to investigate the surface morphology of the pretreated layers and applied electroless coatings. Chemical analysis of the Ti-Zr layer, and nickel coatings was done using the Energy-Dispersive X-ray Spectroscopy. Moreover, the X-ray Diffraction and Atomic Force Microscopy methods were utilized to evaluate the microstructure and surface roughness of the electroless coatings, respectively. Electrochemical Impedance Spectroscopy was employed to study the corrosion behavior of Ni-P coatings. The results show that Ti-Zr layer has structural cracks, and the sol-gel film was covered all cracks entirely. The cauliflower-like electroless nickel coating was applied on both mentioned pretreated layers. The cross-sectional images revealed the higher thickness for the electroless coating on Ti-Zr/sol-gel layer, probably due to a large number of Ni nucleation centers. The EIS results demonstrate that the electroless coating on Ti-Zr/sol-gel has high corrosion protection and microhardness value.
The thermal expansion of a ZrO2-20 mol% Gd2O3 pellet has been systematically investigated using a thermo-mechanical analyzer in the temperature range of 293-1773 K. Variations in the thermal expansion coefficient and density upon temperature change were calculated using the thermal expansion data. The average linear thermal expansion coefficient of the ZrO2-20 mol% Gd2O3 pellet was found to be 9.522 × 10–6 K–1 in the range of 298-1073 K. This value is smaller than that of ZrO2 and larger than that of Gd2O3. Further, with an increase in temperature to 1773 K, the density of ZrO2-20 mol% Gd2O3 pellet was found to decrease to 94.98 % of the initial density at 293 K.
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