The paper presents the results of investigation into the technological possibility of making light-section castings of GX2CrNiMoN25-6-3
cast steel. For making castings with a wall thickness in the thinnest place as small as below 1 mm, the centrifugal casting technology was
employed. The technology under consideration enables items with high surface quality to be obtained, while providing a reduced
consumption of the charge materials and, as a result, a reduction in the costs of unit casting production.
The paper, which is a summary and supplement of previous works and research, presents the results of numerical and physical modeling of the GX2CrNiMoCuN25-6-3 duplex cast steel thin-walled castings production. To obtain thin-walled castings with wall in the thinnest place even below 1 mm was used the centrifugal casting technology and gravity casting. The analyzed technology (centrifugal casting) enables making elements with high surface quality with reduced consumption of batch materials and, as a result, reducing the costs of making a unitary casting. The idea behind the production of cast steel with the use of centrifugal technology was to find a remedy for the problems associated with unsatisfactory castability of the tested alloy.
The technological evaluation of the cast construction was carried out using the Nova Flow & Solid CV 4.3r8 software. Numerical simulations of crystallization and cooling were carried out for a casting without a gating system and sinkhead located in a mold in accordance with the pouring position. It was assumed that the analyzed cast will be made in the sand form with dimensions 250×250×120 mm.
The paper presents the research results concerning the chromium-nickel-molybdenum duplex cast steel GX2CrNiMoCuN 25-6-3-3 grade. The aim of studies was the description of the influence of hyperquenching temperature Tp i.e. 1100, 1125 and 1150℃ on microstructure and mainly mechanical properties i.e. tensile strength UTS, yield strength YS, hardness HB, elongation EL and impact energy KV of duplex cast steel GX2CrNiMoCuN 25-6-3-3 grade. The range of studies included ten melts which were conducted in foundry GZUT S.A. Based on the obtained results was confirmed that application of hyperquenching process guarantees the elimination of brittle s phase in the microstructure of studied duplex cast steel. Moreover on the basis of conducted statistical analysis of the researches results is concluded that with the decrease in hyperquenching temperature increases ductility and amount of austenite, while decreases strength and amount of ferrite in studied duplex cast steel GX2CrNiMoCuN 25-6-3-3 grade.
The paper presents the results of research on the microstructure of GX2CrNiMoCuN25-6-3-3 and GX2CrNiMoCuN25-6-3 cast steels with
a varying carbon content. The cause for undertaking the research were technological problems with hot cracking in bulk castings of duplex
cast steel with a carbon content of approx. 0.06% and with 23% Cr, 8.5% Ni, 3% Mo and 2.4% Cu. The research has shown
a significant effect of increased carbon content on the ferrite and austenite microstructure morphology, while exceeding the carbon content
of 0.06% results in a change of the shape of primary grains from equiaxial to columnar.
The paper is concerned with comparing the methods for determining the ferrite content in castings from duplex stainless steels. It uses Schaeffler diagram, empirical formula based calculation, image analysis of metallographic sample, X-ray diffraction and measurement with a feritscope. The influence of wall thickness of the casting on the ferrite content was tested too. The results of the experiments show that the casting thickness of 25 or 60 mm does not have a significant effect on the measured amount of ferrite. The image analysis of metallographic sample and the measurement with the feritscope appear to be the most suitable methods. On the contrary, predictive methods, such as Schaeffler diagram or empirical formula based calculation are only indicative and cannot replace the real measurements. X-ray diffraction seems to be the least suitable measuring method. Values of ferrite content measured in such a way often deviated from the values measured by image analysis and with feritscope.
In the high-alloy, ferritic - austenitic (duplex) stainless steels high tendency to cracking, mainly hot-is induced by micro segregation
processes and change of crystallization mechanism in its final stage. The article is a continuation of the problems presented in earlier
papers [1 - 4]. In the range of high temperature cracking appear one mechanism a decohesion - intergranular however, depending on the
chemical composition of the steel, various structural factors decide of the occurrence of hot cracking. The low-carbon and low-alloy cast
steel casting hot cracking cause are type II sulphide, in high carbon tool cast steel secondary cementite mesh and / or ledeburite segregated
at the grain solidified grains boundaries, in the case of Hadfield steel phosphorus - carbide eutectic, which carrier is iron-manganese and
low solubility of phosphorus in high manganese matrix. In duplex cast steel the additional factor increasing the risk of cracking it is very
"rich" chemical composition and related with it processes of precipitation of many secondary phases.
This paper presents a baseband model and an enhanced implementation of the wireless full duplex analog method introduced by [1].Unlike usual methods based on hardware and software self- interference cancelation, the proposed design relies on FSK modulation. The principle is when the transmitter of a local end is sending data by modulating the carrier with the appropriate frequency deviation, its own receiver is checking if the remote transmitter is using the opposite deviation. Instead of architectures often used by both non-coherent and coherent receivers that require one filter (matched filter for coherent detection) for each frequency deviation, our design uses one mixer and one single integrator-decimator filter. We test our design using Universal Software Radio Peripheral as radio frequency front end and computer that implements the signal processing methods under free and open source software. We validate our solution experimentally and we show that in-band full duplex is feasible and synthesizable for wireless communications.
The sintered stainless steels of different microstructures (austenitic, ferritic and duplex) were laser surface alloyed with hard powders (SiC, Si3N4) and elemental alloying powders (Cr, FeCr, FeNi) to obtain a complex steel microstructure of improved properties. Laser surface alloying (LSA) involved different strategies of powder placing: the direct powder feeding to the molten metal pool and filling grooves machined on the sample surface by powder, and then laser surface melting. Obtained microstructures were characterised and summarised, basing on LOM, SEM and XRD analysis. The links between base material properties, like superficial hardness and microhardness, derived microstructures and erosion resistance was described. The LSA conditions and alloying powder placement strategies on erosion resistance was evaluated. The erosion wear is lower for Cr, FeCr, FeNi laser alloying, where powders were dissolved in the steel microstructure, and hard phases were not precipitated. Precipitations of hard phases (carbides, silicides, martensite formation) reduce erosion resistance of SiC alloyed stainless steel. The LSA with Si3N4 works better due to lack of precipitates and formation of a soft and ductile austenitic microstructure. The erosion wear at the impingement angle of 90° is high for hard and therefore brittle surface layers obtained as a result of alloying by hard particles (SiC, Si3N4). The softer and ductile austenitic stainless steel resist better than harder ferritic and duplex stainless steel material at studied erodent im pingement angle.
This paper presents an investigation into effect of nitrogen content of shielding gas mixture on weld geometry, microstructure and hardness of pulsed laser welded 2205 duplex stainless steel. Full penetration autogenous welding was performed on 2 mm thick plates using a low power pulsed Nd: YAG laser. light and scanning electron microscopy were used to study the resulting microstructures. It is observed that 2 mm full penetrated joint decreases to 1.8 mm by dominating nitrogen in argon-nitrogen mixture. Different morphologies of austenite phase as well as an increase of 8% of its content can be observed in pure nitrogen shielded welds. Average weld grain size in sample which is welded in nitrogen atmosphere stands at approximately 41 μm which is smaller than that of argon atmosphere which is about 51 μm. Micro-hardness test reveals that hardness values increase from 280 HV in base metal to 307 HV in weld center line and the shielding gas mixture does not significantly influence the weld hardness.
The examined material comprised two grades of corrosion-resistant cast steel, namely GX2CrNiMoN25-6-3 and GX2CrNiMoCuN25-6-3-
3, used for example in elements of systems of wet flue gas desulphurisation in power industry. The operating conditions in media heated
up to 70°C and containing Cl- and SO4 ions and solid particles produce high erosive and corrosive wear.The work proposes an application
of the σ phase as a component of precipitation strengthening mechanism in order to increase the functional properties of the material.
The paper presents the results of examination of the kinetics of σ phase precipitation at a temperature of 800°C and at times ranging from
30 to 180 minutes. Changes in the morphology of precipitates of the σ phase were determined using the value of shape factor R.
Resistance to erosion-corrosion wear of duplex cast steel was correlated with the kinetics of sigma phase precipitating.
High-alloy corrosion-resistant ferritic-austenitic steels and cast steels are a group of high potential construction materials. This is
evidenced by the development of new alloys both low alloys grades such as the ASTM 2101 series or high alloy like super or hyper duplex
series 2507 or 2707 [1-5]. The potential of these materials is also presented by the increasing frequency of sintered components made both
from duplex steel powders as well as mixtures of austenitic and ferritic steels [6, 7]. This article is a continuation of the problems presented
in earlier works [5, 8, 9] and its inspiration were technological observed problems related to the production of duplex cast steel.
The analyzed AISI A3 type cast steel is widely used in both wet exhaust gas desulphurisation systems in coal fired power plants as well as
in aggressive working environments. Technological problems such as hot cracking presented in works [5, 8], with are effects of the rich
chemical composition and phenomena occurring during crystallization, must be known to the technologists.
The presented in this work phenomena which occur during the crystallization and cooling of ferritic-austenitic cast steel were investigated
using numerical methods with use of the ThermoCalc and FactSage® software, as well with use of experimental thermal-derivative
analysis.
The dry sliding wear behavior of heat-treated super duplex stainless steel AISI 2507 was examined by taking pin-on-disc type of wear-test
rig. Independent parameters, namely applied load, sliding distance, and sliding speed, influence mainly the wear rate of super duplex
stainless steel. The said material was heat treated to a temperature of 850°C for 1 hour followed by water quenching. The heat treatment
was carried out to precipitate the secondary sigma phase formation. Experiments were conducted to study the influence of independent
parameters set at three factor levels using the L27 orthogonal array of the Taguchi experimental design on the wear rate. Statistical
significance of both individual and combined factor effects was determined for specific wear rate. Surface plots were drawn to explain the
behavior of independent variables on the measured wear rate. Statistically, the models were validated using the analysis of variance test.
Multiple non-linear regression equations were derived for wear rate expressed as non-linear functions of independent variables. Further,
the prediction accuracy of the developed regression equation was tested with the actual experiments. The independent parameters
responsible for the desired minimum wear rate were determined by using the desirability function approach. The worn-out surface
characteristics obtained for the minimum wear rate was examined using the scanning electron microscope. The desired smooth surface was
obtained for the determined optimal condition by desirability function approach.
The paper discusses possible applications of the percolation theory in analysis of the microstructure images of polycrystalline materials.
Until now, practical use of this theory in metallographic studies has been an almost unprecedented practice. Observation of structures so
intricate with the help of this tool is far from the current field of its application. Due to the complexity of the problem itself, modern
computer programmes related with the image processing and analysis have been used. To enable practical implementation of the task
previously established, an original software has been created. Based on cluster analysis, it is used for the determination of percolation
phenomena in the examined materials. For comparative testing, two two-phase materials composed of phases of the same type (ADI
matrix and duplex stainless steel) were chosen. Both materials have an austenitic - ferritic structure. The result of metallographic image
analysis using a proprietary PERKOLACJA.EXE computer programme was the determination of the content of individual phases within
the examined area and of the number of clusters formed by these phases. The outcome of the study is statistical information, which
explains and helps in better understanding of the planar images and real spatial arrangement of the examined material structure. The results
obtained are expected to assist future determination of the effect that the internal structure of two-phase materials may have on a
relationship between the spatial structure and mechanical properties.
The paper presents the results of examination concerning optimization of the σ phase precipitates with respect to the functional properties of ferritic-austenitic cast steel. The examined material comprised two grades of corrosion-resistant cast steel, namely GX2CrNiMoN25-6-3 and GX2CrNiMoCuN25-6-3-3, used for example in elements of systems of wet flue gas desulphurisation in power industry. The operating conditions in media heated up to 70°C and containing Cl- and SO4 ions and solid particles produce high erosive and corrosive wear. The work proposes an application of the σ phase as a component of precipitation strengthening mechanism in order to increase the functional properties of the material. Morphology and quantities of σ phase precipitates were determined, as well as its influence on the erosion and corrosion wear resistance. It was shown that annealing at 800°C or 900°C significantly improves tribological properties as compared with the supersaturated state, and the best erosion and corrosion wear resistance achieved due to the ferrite decomposition δ → γ’ + σ was exhibited in the case of annealing at the temperature of 800°C for 3 hours.
The current work presents the research results of abrasion wear and adhesive wear at rubbing and liquid friction of new austenitic, austenitic-ferritic (“duplex”) cast steel and gray cast iron EN-GJL-250, spheroidal graphite iron EN-GJS-600-3, pearlitic with ledeburitic carbides and spheroidal graphite iron with ledeburitic carbides with a microstructure of the metal matrix: pearlitic, upper bainite, mixture of upper and lower bainite, martensitic with austenite, pearlitic-martensitic-bainitic-ausferritic obtained in the raw state. The wearing quality test was carried out on a specially designed and made bench. Resistance to abrasion wear was tested using sand paper P40. Resistance to adhesive wear was tested in interaction with steel C55 normalized, hardened and sulfonitrided. The liquid friction was obtained using CASTROL oil. It was stated that austenitic cast steel and “duplex” are characterized by a similar value of abrasion wear and adhesive wear at rubbing friction. The smallest decrease in mass was shown by the cast steel in interaction with the sulfonitrided steel C55. Austenitic cast steel and “duplex” in different combinations of friction pairs have a higher wear quality than gray cast iron EN-GJL250 and spheroidal graphite iron EN-GJS-600-3. Austenitic cast steel and “duplex” are characterized by a lower wearing quality than the spheroidal graphite iron with bainitic-martensitic microstructure. In the adhesive wear test using CASTROL oil the tested cast steels and cast irons showed a small mass decrease within the range of 1÷2 mg.