Chemical heat pumps (CHP) use reversible exothermal and endothermal chemical reactions to increase the temperature of working fluids. In comparison to the “classical” vapour compression chemical heat pumps, CHP enables us to achieve significantly higher temperatures of a heated medium which is crucial for the potential application, e.g. for production of superheated steam. Despite the advantages presented, currently, there are no installations using CHP for lowgrade waste heat recovery available on the market. The scaling up of industrial processes is still one of the greatest challenges of process engineering. The aim of the theoretical and experimental concept study presented here was to evaluate a method of reclaiming energy from low temperature waste streams and converting it into a saturated steam of temperature from 120 to 150 ◦C, which can be useful in industry. A chemical heat pump concept, based on the dilution and concentration of phosphoric acid, was used to test the method in the laboratory scale. The heat of dilution and energy needed for water evaporation from the acid solutionwere experimentally measured. The cycle of successive processes of dilution and concentration has been experimentally confirmed. A theoretical model of the chemical heat pump was tested and coefficient of performance measured.
This paper presents the results of thermodynamic analyses of a system using a horizontal ground heat exchanger to cool a residential building in summer and heat it in the autumn-winter period. The main heating device is a vapour compression heat pump with the ground as the lower heat source. The aim of the analyses is to examine the impact of heat supply to the ground in the summer period, when the building is cooled, on the operation of the heating system equipped with a heat pump in the next heating season, including electricity consumption. The processes occurring in cooling and heating systems have an unsteady nature. The main results of the calculations are among others the time-dependent values of heat fluxes extracted from or transferred to the ground heat exchanger, the fluxes of heat generated by the heat pump and supplied to the heated building by an additional heat source, the parameters in characteristic points of the systems, the temperature distributions in the ground and the driving electricity consumption in the period under analysis. The paper presents results of analysis of cumulative primary energy consumption of the analyzed systems and cumulative emissions of harmful substances.
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In the paper a heating system with a vapour compressor heat pump and vertical U-tube ground heat exchanger for small residential house is considered. A mathematical model of the system: heated object - vapour compressor heat pump - ground heat exchanger is presented shortly. The system investigated is equipped, apart from the heat pump, with the additional conventional source of heat. The processes taking place in the analyzed system are of unsteady character. The model consists of three elements; the first containing the calculation model of the space to be heated, the second - the vertical U-tube ground heat exchanger with the adjoining area of the ground. The equations for the elements of vapour compressor heat pump form the third element of the general model. The period of one heating season is taken into consideration. The results of calculations for two variants of the ground heat exchanger are presented and compared. These results concern variable in time parameters at particular points of the system and energy consumption during the heating season. This paper presents the mutual influence of the ground heat exchanger subsystem, elements of vapour compressor heat pump and heated space.
The dynamic performance of cylindrical double-tube adsorption heat pump is numerically analysed using a non-equilibrium model, which takes into account both heat and mass transfer processes. The model includes conservation equations for: heat transfer in heating/cooling fluids, heat transfer in the metal tube, and heat and mass transfer in the adsorbent. The mathematical model is numerically solved using the method of lines. Numerical simulations are performed for the system water-zeolite 13X, chosen as the working pair. The effect of the evaporator and condenser temperatures on the adsorption and desorption kinetics is examined. The results of the numerical investigation show that both of these parameters have a significant effect on the adsorption heat pump performance. Based on computer simulation results, the values of the coefficients of performance for heating and cooling are calculated. The results show that adsorption heat pumps have relatively low efficiency compared to other heat pumps. The value of the coefficient of performance for heating is higher than for cooling
The conditions of efficient use of heat pumps in air conditioning systems are considered in order to ensure the established temperature and relative humidity of air in premises with the removal of excess moisture in the warm or hot periods of the year. For this purpose, a thermodynamic analysis of heat pump air conditioning schemes with exhaust air recirculation through a condenser and through a heat pump evaporator has been carried out. To determine the potential capabilities of such schemes to maintain comfortable conditions in the production room, a numerical analysis of their operating parameters, depending on the temperature and relative humidity of external atmospheric air, was performed. It has been shown that recirculation of exhaust air through the heat pump evaporator allows to maintain the given conditions in the room in a wider range of parameters of external atmospheric air. In addition, it has been shown that such a scheme requires less specific energy consumption for the operation of heat pump, which means that it is more efficient.
Two-dimensional numerical investigations of the fluid flow and heat transfer have been carried out for the laminar flow of the louvered fin-plate heat exchanger, designed to work as an air-source heat pump evaporator. The transferred heat and the pressure drop predicted by simulation have been compared with the corresponding experimental data taken from the literature. Two dimensional analyses of the louvered fins with varying geometry have been conducted. Simulations have been performed for different geometries with varying louver pitch, louver angle and different louver blade number. Constant inlet air temperature and varying velocity ranging from 2 to 8 m/s was assumed in the numerical experiments. The air-side performance is evaluated by calculating the temperature and the pressure drop ratio. Efficiency curves are obtained that can be used to select optimum louver geometry for the selected inlet parameters. A total of 363 different cases of various fin geometry for 7 different air velocities were investigated. The maximum heat transfer improvement interpreted in terms of the maximum efficiency has been obtained for the louver angle of 16° and the louver pitch of 1.35 mm. The presented results indicate that varying louver geometry might be a convenient way of enhancing performance of heat exchangers.