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Abstract

The paper presents the results of investigation into the technological possibility of making light-section castings of GX2CrNiMoN25-6-3

cast steel. For making castings with a wall thickness in the thinnest place as small as below 1 mm, the centrifugal casting technology was

employed. The technology under consideration enables items with high surface quality to be obtained, while providing a reduced

consumption of the charge materials and, as a result, a reduction in the costs of unit casting production.

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Authors and Affiliations

G. Stradomski
M. Nadolski
Z. Stradomski
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Abstract

Duplex cast steel it is a material with great potential. The properties of this material have contributed to its wide application in many industrial sectors, for example: oil extraction, printing, petrochemical industry, energy - flue gas desulphurization systems, seawater desalination plants, shipbuilding industry. The article presents the results of tribological tests following the static pressure roller burnishing (SPRB) process of GX2CrNiMoN22-5-3 duplex cast steel. The tests provided a basis for assessing the effect of the burnishing parameters on tribological properties of that material. The issue is important because the authors focused their research on duplex cast steels grade that are not containing copper. The article presents part of the research concerning the influence of the burnishing process on the properties of the duplex steel surface layer. Copper in duplex steels affects many areas one of them is the plastic properties. Its absence also reduces castability. Because of that it is reasonable to determine to what extent the properties of the surface layer of copper-free duplex cast steel grades can be shaped in burnishing process.
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Authors and Affiliations

G.E. Stradomski
1
ORCID: ORCID
J. Fik
2
ORCID: ORCID
D. Rydz
1
ORCID: ORCID

  1. Czestochowa University of Technology, Faculty of Production Engineering and Materials Technology, Poland
  2. Department of Advanced Computational Methods, Jan Dlugosz University in Czestochowa
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Abstract

This work deals with the problem of intermetallic phases in cast standard duplex steel ASTM A890 Gr 4A (generally known as 2205). The investigated steel was subjected to isothermal heat treatment in the range from 595 °C to 900 °C and in the duration from 15 minutes to 245 hours, and was also investigated in terms of anisothermal (natural) cooling after casting into the mould. The precipitation starts at grain boundaries with a consistent ferrite transformation. The work is focused on the precipitation of the sigma phase (σ) and the chi phase (χ). Examination of the microstructure was conducted using light and scanning electron microscopy. Their statistical analysis was carried out using the results of the investigations of precipitation processes in the microstructure, both within the grains and at the grain boundaries. To illustrate this impact, the surface area of precipitates was evaluated. The percentage of these intermetallic phases was calculated by measuring their area using a computer image analysis system. Based on their observations, a combined time-temperature transformation (TTT) diagram with continuous cooling transformation (CCT) curves was created.
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Authors and Affiliations

M. Myška
1
ORCID: ORCID
P. Bořil
1
ORCID: ORCID
V. Krutiš
1
ORCID: ORCID
V. Kaňa
1
ORCID: ORCID
A. Zádĕra
1
ORCID: ORCID

  1. Brno University of Technology, Czech Republic
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Abstract

The paper presents the results of research conducted in the field of crystallization and microstructure of duplex alloy cast steel GX2CrNiMoCuN 25-6-3-3 grade. The material for research was the above-mentioned cast steel with a chemical composition compliant with the relevant PN-EN 10283 standard, but melted at the lowest standard allowable concentration of alloying additives (some in short supply and expensive), i.e. Cr, Ni, Mn, Mo, Cu and N. The analysis of the crystallization process was performed based on the DTA (Derivative Thermal Analysis) method for a stepped casting with a thickness of individual steps of 10, 20, 40 and 60 mm. The influence of wall thickness was also taken into account in the cast steel microstructure testing, both in the as-cast state and after solution heat treatment. The phase composition of the cast steel microstructure was determined by using an optical microscope and X-ray phase analysis. The analysis of test results shows that the crystallization of tested cast steel uses the ferritic mechanism, while austenite is formed as a result of solid state transformation. The cast steel under analysis in the as-cast state tends to precipitate the undesirable σ-type Fe-Cr intermetallic phase in the microstructure, regardless of its wall thickness. However, the casting wall thickness in the as-cast state affects the austenite grain size, i.e. the thicker the casting wall, the wider the γ phase grains. The above-mentioned defects of the tested duplex alloy cast steel microstructure can be effectively eliminated by subjecting it to heat treatment of type hyperquenching.
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Bibliography

[1] Chojecki, A., Telejko, I. (2003). The foundry engineering of cast steel. Kraków: Akapit. (in Polish).
[2] Perzyk, M., Waszkiewicz, S., Kaczorowski, M., Jopkiewicz, A. (2004). Foundry engineering. Warszawa: WNT. (in Polish).
[3] Gunn, R. (1997). Duplex stainless steels - microstructure, properties and applications. Cambridge: Woodhead Publishing.
[4] Stradomski, G. (2016). Influence of the sigma phase morphology on shaping the properties of steel and duplex cast steel. Częstochowa: Publishers of Czestochowa University of Technology. (in Polish).
[5] Voronenko, B. (1997). Austenitic-ferritic stainless steels: A state-of-the-art review. Metal Science and Heat Treatment. 39(10), 428-437. https://doi.org/10.1007/BF02484228.
[6] Kalandyk, B. (2011). Characteristics of microstructure and properties of castings made from ferritic-austenitic steel. Katowice – Gliwice: AFE. (in Polish).
[7] Stradomski, G. (2017). The analysis of AISI A3 type ferritic-austenitic cast steel crystallization mechanism. Archives of Foundry Engineering. 17(3), 229-233. https://doi.org/10.1515/afe-2017-0120.
[8] Šenberger, J., Pernica, V., Kaňa, V. & Záděra, A. (2018). Prediction of ferrite content in austenitic Cr-Ni steel castings during production. Archives of Foundry Engineering. 18(3), 91-94. https://doi.org/10.24425/123608.
[9] Kaňa, V., Pernica, V., Záděra, A. & Krutiš, V. (2019). Comparison of methods for determining the ferrite content in duplex cast steels. Archives of Foundry Engineering. 19(2), 85-90. https://doi.org/10.24425/afe.2019.127121.
[10] Yamamoto, R., Yakuwa, H., Miyasaka, M. & Hara, N. (2019). Effects of the α/γ-phase ratio on the corrosion behavior of cast duplex stainless steel. Corrosion. 76(9), 815-825. https://doi.org/10.5006/3464.
[11] Jurczyk, P., Wróbel, T. & Baron, C. (2021). The influence of hyperquenching temperature on microstructure and mechanical properties of alloy cast steel GX2CrNiMoCuN 25-6-3-3. Archives of Metallurgy and Materials. 66(1), 73-80. https://doi.org/10.24425/amm.2021.134761.
[12] Kalandyk, B., Zapała, R. & Pałka, P. (2022). Effect of isothermal holding at 750 °C and 900 °C on microstructure and properties of cast duplex stainless steel containing 24% Cr-5% Ni-2.5% Mo-2.5% Cu. Materials. 15(23), 1-17. https://doi.org/10.3390/ma15238569.
[13] Wróbel, T., Jurczyk, P., Baron, C. & Jezierski, J. (2023). Search for the optimal soaking temperature for hyperquenching of the GX2CrNiMoCuN 25-6-3-3 duplex cast steel. International Journal of Metalcasting. https://doi.org/10.1007/s40962-023-01020-x. (in print).
[14] Głownia, J. & Banaś, J. (1997). Effect of modification and segregation on the delta-ferrite morphology and corrosion resistance of cast duplex steel. Metallurgy and Foundry Engineering. 23(2), 261-267.

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Authors and Affiliations

T. Wróbel
1
ORCID: ORCID
P. Jurczyk
1
ORCID: ORCID
C. Baron
1
ORCID: ORCID
P. Nuckowski
2
ORCID: ORCID

  1. Silesian University of Technology, Department of Foundry Engineering, Towarowa 7, 44-100 Gliwice, Poland
  2. Silesian University of Technology, Materials Research Laboratory, Konarskiego 18a, 44-100 Gliwice, Poland
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Abstract

The effect of aging time at 850°C for 300 s, 600 s, 1800 s, and 84600 s on the microstructural evolution and corrosion resistance of 2205 duplex stainless steel (DSS) was studied after cold rolling up to 60% of reduction. X-ray diffraction, scanning electron and transmission electron microscopy were used for microstructural characterization. The corrosion behavior was studied by cyclic potentiodynamic polarization (CPP) and electrochemical impedance technique (EIS) in 3.5% NaCl solution and the susceptibility to sensitization was investigated through the double loop electrochemical potentiodynamic reactivation (DL-EPR) test in 0.5 M H2SO4 + 0.1 M NaCl + 0.002 M KSCN solution. After cold working, increasing aging time led to an increase in sigma phase precipitation and a decrease in pitting corrosion resistance. However, the ultrafine microstructure had a beneficial influence on the self-healing effect in Cr and Mo depleted areas with the increasing of aging time, resulting in higher passivation ability. The DSS 2205 type was not susceptible to intergranular corrosion for the aged conditions applied.
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Authors and Affiliations

R.F. Assumpção
1
ORCID: ORCID
J.C. Fortes Monteiro
2
ORCID: ORCID
V.C. Campideli
2
ORCID: ORCID
D.B. Santos
1
ORCID: ORCID
D.C. Sicupira
2
ORCID: ORCID

  1. Universidade Federal de Minas Gerais, Department of Metallurgical and Materials Engineering, Belo Horizonte, Brazil
  2. Universidade Federal de Ouro Preto, Department of Chemistry, Campus Morro do Cruzeiro, Brazil
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Abstract

The paper presents the research results concerning the chromium-nickel-molybdenum duplex cast steel GX2CrNiMoCuN 25-6-3-3 grade. The aim of studies was the description of the influence of hyperquenching temperature Tp i.e. 1100, 1125 and 1150℃ on microstructure and mainly mechanical properties i.e. tensile strength UTS, yield strength YS, hardness HB, elongation EL and impact energy KV of duplex cast steel GX2CrNiMoCuN 25-6-3-3 grade. The range of studies included ten melts which were conducted in foundry GZUT S.A. Based on the obtained results was confirmed that application of hyperquenching process guarantees the elimination of brittle s phase in the microstructure of studied duplex cast steel. Moreover on the basis of conducted statistical analysis of the researches results is concluded that with the decrease in hyperquenching temperature increases ductility and amount of austenite, while decreases strength and amount of ferrite in studied duplex cast steel GX2CrNiMoCuN 25-6-3-3 grade.

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Authors and Affiliations

P. Jurczyk
ORCID: ORCID
T. Wróbel
ORCID: ORCID
Cz. Baron
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Abstract

The paper, which is a summary and supplement of previous works and research, presents the results of numerical and physical modeling of the GX2CrNiMoCuN25-6-3 duplex cast steel thin-walled castings production. To obtain thin-walled castings with wall in the thinnest place even below 1 mm was used the centrifugal casting technology and gravity casting. The analyzed technology (centrifugal casting) enables making elements with high surface quality with reduced consumption of batch materials and, as a result, reducing the costs of making a unitary casting. The idea behind the production of cast steel with the use of centrifugal technology was to find a remedy for the problems associated with unsatisfactory castability of the tested alloy.

The technological evaluation of the cast construction was carried out using the Nova Flow & Solid CV 4.3r8 software. Numerical simulations of crystallization and cooling were carried out for a casting without a gating system and sinkhead located in a mold in accordance with the pouring position. It was assumed that the analyzed cast will be made in the sand form with dimensions 250×250×120 mm.

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Authors and Affiliations

G. Stradomski
M. Nadolski
ORCID: ORCID
A. Zyska
B. Kania
D. Rydz
ORCID: ORCID
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Abstract

Wheat dwarf virus (WDV) has been one of the most common viruses on cereal crops in Poland in the last years. This single stranded DNA virus is transmitted by the leafhopper spec, Psammotettix alienus (Dahlb.) in a persistent manner. It induces yellowing and streaking of leaves, dwarfing or even death of infected plants. The presence of barley- and wheat-specific forms of WDV (WDV-B and WDV-W) and their vector were previously reported in the country, however the literature data did not include any information on the infectivity of the vector in Poland. A duplex polymerase chain reaction (PCR) procedure was developed and optimized for simultaneous detection and differentiation of both forms in the vector. Two sets of primers amplify 734 bp and 483 bp specific fragments for WDV-W and WDV-B, respectively. The results were verified by a sequencing method. The studies were carried out on insect samples collected in autumn from four different locations in Greater Poland. The results confirmed the presence of WDV-W in the tested samples. They also suggested the concomitant of both forms of the virus in the vector. Additional studies to determine virus-vector relationships should be undertaken.
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Authors and Affiliations

Katarzyna Trzmiel
Tomasz Klejdysz
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Abstract

The paper presents the results of research on the microstructure of GX2CrNiMoCuN25-6-3-3 and GX2CrNiMoCuN25-6-3 cast steels with

a varying carbon content. The cause for undertaking the research were technological problems with hot cracking in bulk castings of duplex

cast steel with a carbon content of approx. 0.06% and with 23% Cr, 8.5% Ni, 3% Mo and 2.4% Cu. The research has shown

a significant effect of increased carbon content on the ferrite and austenite microstructure morphology, while exceeding the carbon content

of 0.06% results in a change of the shape of primary grains from equiaxial to columnar.

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Authors and Affiliations

G. Stradomski
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Abstract

This article discusses the influence of Tungsten Inert Gas (TIG) surfacing of duplex cast steel on its hardness and structure. The samples of 24Cr-5Ni-2.5Mo ferritic-austenitic cast steel were subjected to single-overlay processes with the use of solid wire having the chemical composition similar to that of the duplex cast steel. As a result of the surfacing, the welds were obtained that had no welding imperfections with a smooth transition to the base material. In the test without the heat treatment, directly below the fusion line, we observe a ferrite band with a width of approximately 200 m without visible austenite areas. Some of the samples were then solution treated (1060°C). Both variants, without and after solution heat treatment, were subjected to testing. Significant changes in the microstructure of the joint were observed after the heat treatment process (heat affected zone and weld microstructure changes). In both areas, an increase in the austenite volume fraction after solution heat treatment was observed. Changes in the microhardness of the ferrite in the HAZ area directly below the fusion line were also observed.
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Authors and Affiliations

B. Kalandyk
J. Kasińska
A. Skrzypczyk
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Abstract

The paper is concerned with comparing the methods for determining the ferrite content in castings from duplex stainless steels. It uses Schaeffler diagram, empirical formula based calculation, image analysis of metallographic sample, X-ray diffraction and measurement with a feritscope. The influence of wall thickness of the casting on the ferrite content was tested too. The results of the experiments show that the casting thickness of 25 or 60 mm does not have a significant effect on the measured amount of ferrite. The image analysis of metallographic sample and the measurement with the feritscope appear to be the most suitable methods. On the contrary, predictive methods, such as Schaeffler diagram or empirical formula based calculation are only indicative and cannot replace the real measurements. X-ray diffraction seems to be the least suitable measuring method. Values of ferrite content measured in such a way often deviated from the values measured by image analysis and with feritscope.

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Authors and Affiliations

V. Kaňa
V. Pernica
A. Zadera
V. Krutiš
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Abstract

In the high-alloy, ferritic - austenitic (duplex) stainless steels high tendency to cracking, mainly hot-is induced by micro segregation

processes and change of crystallization mechanism in its final stage. The article is a continuation of the problems presented in earlier

papers [1 - 4]. In the range of high temperature cracking appear one mechanism a decohesion - intergranular however, depending on the

chemical composition of the steel, various structural factors decide of the occurrence of hot cracking. The low-carbon and low-alloy cast

steel casting hot cracking cause are type II sulphide, in high carbon tool cast steel secondary cementite mesh and / or ledeburite segregated

at the grain solidified grains boundaries, in the case of Hadfield steel phosphorus - carbide eutectic, which carrier is iron-manganese and

low solubility of phosphorus in high manganese matrix. In duplex cast steel the additional factor increasing the risk of cracking it is very

"rich" chemical composition and related with it processes of precipitation of many secondary phases.

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Authors and Affiliations

G. Stradomski
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Abstract

This paper presents a baseband model and an enhanced implementation of the wireless full duplex analog method introduced by [1].Unlike usual methods based on hardware and software self- interference cancelation, the proposed design relies on FSK modulation. The principle is when the transmitter of a local end is sending data by modulating the carrier with the appropriate frequency deviation, its own receiver is checking if the remote transmitter is using the opposite deviation. Instead of architectures often used by both non-coherent and coherent receivers that require one filter (matched filter for coherent detection) for each frequency deviation, our design uses one mixer and one single integrator-decimator filter. We test our design using Universal Software Radio Peripheral as radio frequency front end and computer that implements the signal processing methods under free and open source software. We validate our solution experimentally and we show that in-band full duplex is feasible and synthesizable for wireless communications.

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Authors and Affiliations

Jelloul Elmesbahi
Mohammed Khaldoun
Ahmed Errami
Mohammed El Khattabi
Omar Bouattane
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Abstract

The sintered stainless steels of different microstructures (austenitic, ferritic and duplex) were laser surface alloyed with hard powders (SiC, Si3N4) and elemental alloying powders (Cr, FeCr, FeNi) to obtain a complex steel microstructure of improved properties. Laser surface alloying (LSA) involved different strategies of powder placing: the direct powder feeding to the molten metal pool and filling grooves machined on the sample surface by powder, and then laser surface melting. Obtained microstructures were characterised and summarised, basing on LOM, SEM and XRD analysis. The links between base material properties, like superficial hardness and microhardness, derived microstructures and erosion resistance was described. The LSA conditions and alloying powder placement strategies on erosion resistance was evaluated. The erosion wear is lower for Cr, FeCr, FeNi laser alloying, where powders were dissolved in the steel microstructure, and hard phases were not precipitated. Precipitations of hard phases (carbides, silicides, martensite formation) reduce erosion resistance of SiC alloyed stainless steel. The LSA with Si3N4 works better due to lack of precipitates and formation of a soft and ductile austenitic microstructure. The erosion wear at the impingement angle of 90° is high for hard and therefore brittle surface layers obtained as a result of alloying by hard particles (SiC, Si3N4). The softer and ductile austenitic stainless steel resist better than harder ferritic and duplex stainless steel material at studied erodent im pingement angle.

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Authors and Affiliations

Z. Brytan
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Abstract

The aim of this work is to investigate the resistance of cast duplex (austenitic-ferritic) steels to pitting corrosion with respect to the value of PREN (Pitting Resistance Equivalent Number). Pitting corrosion is one of the most common types of corrosion of stainless steels. In most cases, it is caused by the penetration of aggressive anions through the protective passive layer of the steel, and after its disruption, it leads to subsurface propagation of corrosion. The motivation for the research was a severe pitting corrosion attack on the blades of the gypsum-calcium water mixer in a thermal power plant operation.
In order to examine the corrosion resistance, 4 samples of 1.4517 steel with different concentrations of alloying elements (within the interval indicated by the steel grade) and thus with a different PREN value were cast. The corrosion resistance of the samples was evaluated by the ASTM G48 – 11 corrosion test in a 6% aqueous FeCl3 solution at room and elevated solution temperatures. To verify the possible effect of different alloying element concentrations on the mechanical properties, the research was supplemented by tensile and Charpy impact tests. Based on the results, it was found that a significant factor in the resistance of duplex steels to pitting corrosion is the temperature of the solution. For the components in operation, it is therefore necessary to take this effect into account and thoroughly control and manage the temperature of the environment in which the components operate.
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Bibliography

[1] Reardon, A. (2011). 12.5 Duplex Stainless Steels. In metallurgy for the non-metallurgist (2nd Edition). Ohio: ASM International, ISBN 978-1-61503-821-3, Retrieved from https://app.knovel.com/hotlink/pdf/id:kt009JBTT4/metallurgy-non-metallurgist/duplex-stainless-steels
[2] McGuire, M.F. (2008). Duplex stainless steels. in stainless steels for design engineers (91–108) [online]. Materials Park, Ohio 44073-000: ASM International, [cit. 2020-05-19]. ISBN 978-1-61503-059-0., Retrieved from: https://app.knovel.com/hotlink/pdf/id:kt008GRPY2/stainless-steels-design/duplex-stainless-introduction
[3] O'Brien, A. ed. (2011) Stainless and Heat-Resistant Steels. In Welding Handbook, Volume 4 - Materials and Applications, Part 1 [online]. 9th Edition. Miami: American Welding Society (AWS), p. 351 [cit. 2020-05-27]. ISBN 978-1-61344-537-2. Retrieved from https://app.knovel.com/hotlink/pdf/id:kt0095SGE2/welding-handbook-volume/duplex-sta-composition
[4] Revie, R.W. ed. (2011). In Uhlig’s Corrosion Handbook [online]. Third edition. Duplex stainless steels. (695–705). Hoboken, New Jersey: John Wiley & Sons, 2011 [cit. 2020-06-14]. ISBN 978-1-61344-161-9. Retrieved from https://app.knovel.com/hotlink/pdf/id:kt008TZY32/uhlig-s-corrosion-handbook/duplex-sta-history
[5] Prošek, T. & Šefl, V. (2018). Corrosion resistance of stainless steel in drinking water treatment plants and water storage units. Koroze a ochrana materialu. 62(4), 141-147. DOI: 10.2478/kom-2018-0020.
[6] Cicek, V. (2014). Corrosion engineering. Hoboken, New Jersey: Scrivener Publishing/Wiley. ISBN 978-1-118-72089-9. Retrieved from https://app.knovel.com/hotlink/toc/id:kpCE00004B/corrosion-engineering/corrosion-engineering.
[7] Marcus, P. ed. (2012). Corrosion mechanisms in theory and practice. Third edition. Boca Raton: CRC Press, Corrosion technology (Boca Raton, Fla.). ISBN 978-1-4200-9463-3.
[8] G48 - 11(2015). Standard test methods for pitting and crevice corrosion resistance of stainless steels and related alloys by use of ferric chloride solution. West Conshohocken: ASTM International, 2015.
[9] Jargelius-Pettersson, R.F.A. (1998). Application of the pitting resistance equivalent concept to some highly alloyed austenitic stainless steels. Corrosion. 54(2), 162-168. DOI: 10.5006/1.3284840.
[10] (2015). Austenitic-ferritic (duplex) casting materials [online]. Otto Junker, 2015 [cit. 2020-06-25]. Retrieved from: https://www.otto-junker.com/cache/dl-Austenitic-Ferritic-DUPLEX-Casting-Materials-aa4d1dd1db00d37343728c6ba0598a75.pdf

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Authors and Affiliations

P. Müller
1
ORCID: ORCID
V. Pernica
1
ORCID: ORCID
V. Kaňa
1
ORCID: ORCID

  1. Brno University of Technology, Czech Republic
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Abstract

This paper presents an investigation into effect of nitrogen content of shielding gas mixture on weld geometry, microstructure and hardness of pulsed laser welded 2205 duplex stainless steel. Full penetration autogenous welding was performed on 2 mm thick plates using a low power pulsed Nd: YAG laser. light and scanning electron microscopy were used to study the resulting microstructures. It is observed that 2 mm full penetrated joint decreases to 1.8 mm by dominating nitrogen in argon-nitrogen mixture. Different morphologies of austenite phase as well as an increase of 8% of its content can be observed in pure nitrogen shielded welds. Average weld grain size in sample which is welded in nitrogen atmosphere stands at approximately 41 μm which is smaller than that of argon atmosphere which is about 51 μm. Micro-hardness test reveals that hardness values increase from 280 HV in base metal to 307 HV in weld center line and the shielding gas mixture does not significantly influence the weld hardness.

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Authors and Affiliations

E. Hajibaba Gozarganji
A. Farnia
M. Ebrahimnia
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Abstract

The microstructure and corrosion properties of spark plasma sintered yttria dispersed and yttria free duplex and ferritic stainless samples were studied. Spark plasma sintering (SPS) was carried out at 1000°C by applying 50 MPa pressure with holding time of 5 minutes. Linear sweep voltammetry (LSV) tests were employed to evaluate pitting corrosion resistance of the samples. Corrosion studies were carried out in 0.5, 1 and 2 M concentration of NaCl and H2SO4 solutions at different quiet time of 2, 4, 6, 8 and 10 seconds. Yttria dispersed stainless steel samples show more resistance to corrosion than yttria free stainless steel samples. Pitting potential decreases with increase in reaction time from 2 to 10 seconds. Similarly, as concentration of NaCl and H2SO4 increases from 0.5 M to 2 M the corrosion resistance decrements due to the availability of more Cl¯ and SO4 2¯ ions at higher concentration.
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Authors and Affiliations

R. Shashanka
D. Chaira
Kumara Swamy B.E.
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Abstract

The examined material comprised two grades of corrosion-resistant cast steel, namely GX2CrNiMoN25-6-3 and GX2CrNiMoCuN25-6-3-

3, used for example in elements of systems of wet flue gas desulphurisation in power industry. The operating conditions in media heated

up to 70°C and containing Cl- and SO4 ions and solid particles produce high erosive and corrosive wear.The work proposes an application

of the σ phase as a component of precipitation strengthening mechanism in order to increase the functional properties of the material.

The paper presents the results of examination of the kinetics of σ phase precipitation at a temperature of 800°C and at times ranging from

30 to 180 minutes. Changes in the morphology of precipitates of the σ phase were determined using the value of shape factor R.

Resistance to erosion-corrosion wear of duplex cast steel was correlated with the kinetics of sigma phase precipitating.

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Authors and Affiliations

A. Brodziak-Hyska
Z. Stradomski
C. Kolan
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Abstract

High-alloy corrosion-resistant ferritic-austenitic steels and cast steels are a group of high potential construction materials. This is

evidenced by the development of new alloys both low alloys grades such as the ASTM 2101 series or high alloy like super or hyper duplex

series 2507 or 2707 [1-5]. The potential of these materials is also presented by the increasing frequency of sintered components made both

from duplex steel powders as well as mixtures of austenitic and ferritic steels [6, 7]. This article is a continuation of the problems presented

in earlier works [5, 8, 9] and its inspiration were technological observed problems related to the production of duplex cast steel.

The analyzed AISI A3 type cast steel is widely used in both wet exhaust gas desulphurisation systems in coal fired power plants as well as

in aggressive working environments. Technological problems such as hot cracking presented in works [5, 8], with are effects of the rich

chemical composition and phenomena occurring during crystallization, must be known to the technologists.

The presented in this work phenomena which occur during the crystallization and cooling of ferritic-austenitic cast steel were investigated

using numerical methods with use of the ThermoCalc and FactSage® software, as well with use of experimental thermal-derivative

analysis.

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Authors and Affiliations

G. Stradomski
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Abstract

The dry sliding wear behavior of heat-treated super duplex stainless steel AISI 2507 was examined by taking pin-on-disc type of wear-test

rig. Independent parameters, namely applied load, sliding distance, and sliding speed, influence mainly the wear rate of super duplex

stainless steel. The said material was heat treated to a temperature of 850°C for 1 hour followed by water quenching. The heat treatment

was carried out to precipitate the secondary sigma phase formation. Experiments were conducted to study the influence of independent

parameters set at three factor levels using the L27 orthogonal array of the Taguchi experimental design on the wear rate. Statistical

significance of both individual and combined factor effects was determined for specific wear rate. Surface plots were drawn to explain the

behavior of independent variables on the measured wear rate. Statistically, the models were validated using the analysis of variance test.

Multiple non-linear regression equations were derived for wear rate expressed as non-linear functions of independent variables. Further,

the prediction accuracy of the developed regression equation was tested with the actual experiments. The independent parameters

responsible for the desired minimum wear rate were determined by using the desirability function approach. The worn-out surface

characteristics obtained for the minimum wear rate was examined using the scanning electron microscope. The desired smooth surface was

obtained for the determined optimal condition by desirability function approach.

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Authors and Affiliations

M. Davanageri
S. Narendranath
R. Kadoli
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Abstract

The paper discusses possible applications of the percolation theory in analysis of the microstructure images of polycrystalline materials.

Until now, practical use of this theory in metallographic studies has been an almost unprecedented practice. Observation of structures so

intricate with the help of this tool is far from the current field of its application. Due to the complexity of the problem itself, modern

computer programmes related with the image processing and analysis have been used. To enable practical implementation of the task

previously established, an original software has been created. Based on cluster analysis, it is used for the determination of percolation

phenomena in the examined materials. For comparative testing, two two-phase materials composed of phases of the same type (ADI

matrix and duplex stainless steel) were chosen. Both materials have an austenitic - ferritic structure. The result of metallographic image

analysis using a proprietary PERKOLACJA.EXE computer programme was the determination of the content of individual phases within

the examined area and of the number of clusters formed by these phases. The outcome of the study is statistical information, which

explains and helps in better understanding of the planar images and real spatial arrangement of the examined material structure. The results

obtained are expected to assist future determination of the effect that the internal structure of two-phase materials may have on a

relationship between the spatial structure and mechanical properties.

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Authors and Affiliations

W. Trzaskowski
S. Świłło
W. Sobaszek
D. Myszka
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Abstract

The paper presents the results of examination concerning optimization of the σ phase precipitates with respect to the functional properties of ferritic-austenitic cast steel. The examined material comprised two grades of corrosion-resistant cast steel, namely GX2CrNiMoN25-6-3 and GX2CrNiMoCuN25-6-3-3, used for example in elements of systems of wet flue gas desulphurisation in power industry. The operating conditions in media heated up to 70°C and containing Cl- and SO4 ions and solid particles produce high erosive and corrosive wear. The work proposes an application of the σ phase as a component of precipitation strengthening mechanism in order to increase the functional properties of the material. Morphology and quantities of σ phase precipitates were determined, as well as its influence on the erosion and corrosion wear resistance. It was shown that annealing at 800°C or 900°C significantly improves tribological properties as compared with the supersaturated state, and the best erosion and corrosion wear resistance achieved due to the ferrite decomposition δ → γ’ + σ was exhibited in the case of annealing at the temperature of 800°C for 3 hours.

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Authors and Affiliations

Z. Stradomski
A. Brodziak-Hyska
C. Kolan
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Abstract

The current work presents the research results of abrasion wear and adhesive wear at rubbing and liquid friction of new austenitic, austenitic-ferritic (“duplex”) cast steel and gray cast iron EN-GJL-250, spheroidal graphite iron EN-GJS-600-3, pearlitic with ledeburitic carbides and spheroidal graphite iron with ledeburitic carbides with a microstructure of the metal matrix: pearlitic, upper bainite, mixture of upper and lower bainite, martensitic with austenite, pearlitic-martensitic-bainitic-ausferritic obtained in the raw state. The wearing quality test was carried out on a specially designed and made bench. Resistance to abrasion wear was tested using sand paper P40. Resistance to adhesive wear was tested in interaction with steel C55 normalized, hardened and sulfonitrided. The liquid friction was obtained using CASTROL oil. It was stated that austenitic cast steel and “duplex” are characterized by a similar value of abrasion wear and adhesive wear at rubbing friction. The smallest decrease in mass was shown by the cast steel in interaction with the sulfonitrided steel C55. Austenitic cast steel and “duplex” in different combinations of friction pairs have a higher wear quality than gray cast iron EN-GJL250 and spheroidal graphite iron EN-GJS-600-3. Austenitic cast steel and “duplex” are characterized by a lower wearing quality than the spheroidal graphite iron with bainitic-martensitic microstructure. In the adhesive wear test using CASTROL oil the tested cast steels and cast irons showed a small mass decrease within the range of 1÷2 mg.

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Authors and Affiliations

S. Pietrowski
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Abstract

In the spring of 2019, many plants, mainly winter wheat, were observed to have dwarfism and leaf yellowing symptoms. These plants from several regions of Poland were collected and sent to the Plant Disease Clinic of the Institute of Plant Protection – National Research Institute in Poznań to test for the presence of viral diseases. Double antibody sandwich enzyme-linked immunosorbent assay (DAS-ELISA) results showed numerous cases of Wheat dwarf virus (WDV) and a few cases of plant infections caused by Barley yellow dwarf viruses (BYDVs). WDV was detected in 163 out of 236 tested winter wheat plants (69.1%), in 10 out of 27 tested winter barley plants (37%) and in 6 out of 7 triticale plants (85.7%) while BYDVs were found, respectively, in 9.7% (23 out of 236) and in 18.5% (5 out of 27) of tested winter forms of wheat and barley plants. Infected plants came mainly from the regions of Lower Silesia and Greater Poland. Furthermore, individual cases of infections were also confirmed in the following districts: Lubusz, Opole, Silesia, Kuyavia-Pomerania and Warmia-Masuria. Results of Duplex-immunocapture-polymerase chain reaction (Duplex-IC-PCR) indicated the dominance of WDV-W form in wheat and WDV-B form in barley plants. Moreover, results of reverse transcription – polymerase chain reaction (RT-PCR) connected with restriction fragment length polymorphism (RFLP) analysis, performed for 17 BYDVs samples, revealed 8 BYDV-PAS, 4 BYDV-MAV and 2 BYDVPAV as well as the presence of two mixed infections of BYDV-MAV/-PAS and one case of BYDV-MAV/-PAV. Next, RT-PCR reactions confirmed single BYDV-GAV infection and the common presence of BYDV-SGV. To the best of our knowledge, in 2020 the viruses were not a big threat to cereal crops in Poland.

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Authors and Affiliations

Katarzyna Trzmiel
ORCID: ORCID

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