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Abstract

The article discusses the process of copper production in a slurry furnace and in a converter, with the indication of corrosion effects of the extractor. The furnace shaft and settling furnace of the flash furnace were analyzed. The basic factors determining the choice of singlestage technology of copper smelting in relation to the exploitation of refractory materials were indicated. The effects of dissolving the furnace lining material through slag have been presented. Structural analysis results using a scanning microscope are also included. The kinetics of destruction of ceramic materials under the influence of copper slag were evaluated. It has been shown that detailed analyzes are necessary in order to extend the time of furnace extensibility of furnaces in copper processes. The surface layer of the crucible softens due to saturation with slag reagents and is then washed out and moves in the solid form to the slag. The research in the article indicate not only the possibility of dissolution of the ceramic material in the molten slag, but also possibility of erosive activity of the slag on that material.
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Authors and Affiliations

M. Wędrychowicz
B. Basiura
A.W. Bydałek
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Abstract

Discusses an attempt to optimize the operation of an electric furnace slag to be decopperisation suspension of the internal recycling

process for the production of copper. The paper presents a new method to recover copper from metallurgical slags in arc-resistance electric

furnace. It involves the use of alternating current for a first period reduction, constant or pulsed DC in the final stage of processing. Even

distribution of the electric field density in the final phase of melting caused to achieve an extremely low content of metallic copper in the

slag phase. They achieved by including the economic effects by reducing the time reduction.

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Authors and Affiliations

W. Wołczyński
A.W. Bydałek
S. Biernat
A. Bydałek
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Abstract

This article presents the results of studies into the phase and chemical composition of blast furnace slag in the context of its reuse. In practice, blast furnace slags are widely used in the construction industry and road building as a basis for the production of, for example, cements, road binders and slag bricks. T hey are also used in the production of concrete floors, mortars, and plasters. Blast furnace slag is mainly used as a valuable material in the production of hydraulic binders, especially cement that improves the mechanical properties of concretes.
The favorable physical and mechanical properties of slags, apart from economic aspects, are undoubtedly an asset when deciding to use them instead of natural raw materials. In addition to the above, there is also the ecological aspect, since by using waste materials, the environmental interference that occurs during the opencast mining of natural aggregates is reduced. S pecifically, this means waste utilization through secondary management.
However, it should be kept in mind that it is a material which quite easily and quickly responds to environmental changes triggered by external factors; therefore, along with the determination of its physical and mechanical properties, its phase and chemical composition must be also checked.
The studies showed that the predominant component of the blast furnace slag is glass which can amount up to 80%. In its vicinity, metallic precipitate as well as crystallites of periclase, dicalcium silicates and quartz can be found. With regard to the chemical composition of the slag, it was concluded that it meets the environmental and technical requirements regarding unbound and hydraulically bound mixtures. In case of the latter, in terms of its chemical composition, the slag meets the hydraulic activity category CA3. It also meets the chemical requirements for using it as a valuable addition to mortars and concretes, and it is useful in the production of CEM II Portland-composite cement, CEM III blast-furnace cement and CEM V composite cements. The blast furnace slag is a valuable raw material for cement production. Cement CEM III/C contains 81–95% of blast furnace slag in accordance with E N 197-1:2012. In 2019, the Polish cement industry used 1,939,387.7 tons of slag.
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Authors and Affiliations

Iwona Jonczy
1
ORCID: ORCID
Bartłomiej Grzesik
2
ORCID: ORCID
Andrzej Norbert Wieczorek
1
Anna Gerle
3
Paweł Nuckowski
4
Marcin Staszuk
4
ORCID: ORCID

  1. Silesian University of Technology, Faculty of Mining, Safety Engineering and Industrial Automation, Gliwice, Poland
  2. Silesian University of Technology, Faculty of Civil Engineering, Gliwice, Poland
  3. Łukasiewicz Research Network, Institute of Ceramics and Building Materials, Refractory Materials Division in Gliwice, Poland
  4. Silesian University of Technology, Faculty of Mechanical Engineering, Gliwice, Poland
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Abstract

In the paper the methodology of furnace exit gas temperature calculations by using well known normative standard method CKTI is presented. There are shown changes in methodology approach for three editions of it and in additional developments. Furnace exit gas temperature for two stoker grate boilers is calculated. By using described methods, it was possible to determine their effectiveness by comparing with measurements. Knowledge of the furnace exit gas temperature allows to define the division into irradiated and convection surfaces, which has an impact on the design features of the boiler as well as its dimensions and weight.
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Bibliography

[1] Kashnikov S.P., Tsygankov V.N.: Calculation of Boiler Units. In Examples and Problems. Gosenergoizdat, Moscow 1951 (in Russian).
[2] Kuznetsov N.V., Mitor V.V., Dubovsky I.E., Karasina E.S. (Eds.): Thermal Calculation of Boiler Units. Normative Method (2nd Edn.). Energia, Moscow 1973 (in Russian).
[3] Blokh A.G.: Heat Transfer in Steam Boiler Furnaces. Energoatomizdat, Moscow 1984 (in Russian).
[4] Blokh A.G.: Heat Transfer in Steam Boiler Furnaces, Springer Verlag, 1988.
[5] Kagan G.M.: Thermal Calculation of Boilers. Normative Method (3rd Edn.). NPO CKTI, Sankt-Peterburg 1998 (in Russian).
[6] Ye Weijie, Cheng Leming (Eds.): Thermal Calculation Method for Grate-Firing and Fluidized Bed Industrial Boiler, General Methods of Calculation and Design for Industrial Boiler. Standards Press, Bejing 2003 (in Chinese).
[7] Zhang Y.: Theory and Calculation of Heat Transfer in Furnaces. Elsevier, 2016.
[8] Kamenetskii B.Ya.: Applicability of the standard method for calculating heat transfer in furnaces with stokers. Therm. Eng. 53(2006), 2, 138–142.
[9] Kamenetskii B.Ya.: Calculation of heat transfer in boiler furnaces during firing of fuel in a bed. Therm. Eng. 55(2008), 5, 442–445.
[10] EN 12952-15. Water tube boilers and auxiliary installations – Part 15: Acceptance tests.
[11] EN ISO 9001:2015. Quality management systems – Requirements.
[12] EN ISO 14001:2015. Environmental management systems. Requirements with guidance for use.
[13] PN-N-18001:2004. Occupational health and safety management systems – Requirements
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Authors and Affiliations

Łukasz Rutkowski
1
Ireneusz Szczygieł
2

  1. Boilers Manufacturer SEFAKO S.A., Przemysłowa 9, 28-340 Sedziszów, Poland
  2. Silesian University of Technology Institute of Thermal Technology, Konarskiego 22, 44-100 Gliwice, Poland
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Abstract

Aiming at the problems of delay and couple in the sintering temperature control system of lithium batteries, a fuzzy neural network controller that can solve complex nonlinear temperature control is designed in this paper. The influence of heating voltage, air inlet speed and air inlet volume on the control of temperature of lithium battery sintering is analyzed, and a fuzzy control system by using MATLAB toolbox is established. And on this basis, a fuzzy neural network controller is designed, and then a PID control system and a fuzzy neural network control system are established through SIMULINK. The simulation shows that the response time of the fuzzy neural network control system compared with the PID control system is shortened by 24s, the system stability adjustment time is shortened by 160s, and the maximum overshoot is reduced by 6.1%. The research results show that the fuzzy neural network control system can not only realize the adjustment of lithium battery sintering temperature control faster, but also has strong adaptability, fault tolerance and anti-interference ability.
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Bibliography

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[2] Zhu, D.Q. & Jiang, K.R. (2009). Design and simulation of fuzzy neural network controller for drying process. Journal of System Simulation. 21(15), 4768-4771. DOI: 10.16182/j.cnki.joss.2009.15.079.
[3] Zhang, Z.M., Zhang, J.Y. & Feng, X.G. (2019). Design of hot blast stove temperature control system based on RBF neural network tuning. Journal of Hebei University of Science and Technology. 40(06), 503-511. DOI: 10.7535/hbkd.2019yx06007.
[4] Bai, G.Z. & Yu, J.H. (2016). PID parameter self-tuning based on improved fuzzy neural network. Computer Application Research. 33(11), 3358-3363+3368. DOI: 10.3969/j.issn.1001-3695.2016.11.035.
[5] Li, C.L. & Huang, C.Z. (2010). Design of temperature control system based on fuzzy neural network. Microcomputer Information. 26(07), 75-76+98. DOI: 10.3969/j.issn.2095-6835.2010.07.031.
[6] Li, G.Q., Tong, S.H. & Lu, L.X. (2013). Analysis of the temperature field in a continuous sintering furnace for solar cells. Computer Simulation. 30(01), 188-192+218. DOI: 10.3969/j.issn.1006-9348.2013.01.043.
[7] Huang, B., Xie, G.J., Liang, W.S. & Zhang, J.W. (2018). Application of heating furnace temperature control system based on hybrid fuzzy PID. Electric Drive. 48(02), 43-46. DOI: 10.19457/j.1001-2095.20180208.
[8] Zhou, G.L., Peng, Y.F. & Dong, H.S. (2007). Design of adaptive fuzzy PID controller based on T-S model. Industrial Instrumentation and Automation. 2, 22-25. DOI: CNKI: SUN: GYZD.0.2007-02-005.
[9] Tan, M., Cheng, C.H. & Lu, C. (2006). Research on the temperature control system of vacuum sintering furnace based on neural network. Measurement and Control Technology. 2, 31-32+53. DOI: 10.19708/j.ckjs.2006.02.010.
[10] Wang, J.P. & Ku, M.S. (2010). Application of FNN on atmospheric heating furnace of distillation unit. Computer Measurement and Control. 18(11), 2649-2651. DOI: 10.16526/j.cnki.11-4762/tp.2010.11.003. [11] Chen, B.F., Yin, P.L. & Ma, L. (2010). Research on temperature control system based on fuzzy neural network. Computer and Digital Engineering. 38(07), 54-57. DOI: 10.3969/j.issn.1672-9722.2010.07.016.
[12] Li, M.H. & Li, Z.Q. (2012). Research on Decoupling Control Strategy of Injection Molding Machine Barrel Temperature Based on Neural Network. Ceramics. 4, 17-19. DOI: 10.19397/j.cnki.ceramics.2012.04.004.
[13] Hu, Y.N. & Ma, W.M. (2017). Research and application of paper quantitative moisture control strategy based on FNN decoupling. China Paper. 36(07), 48-53. DOI: 10.11980/j.issn.0254-508X.2017.07.009. [14] Zhang, L., Zhang, J.C., Han, H.G. & Qiao, J.F. (2020). Process control of biochemical phosphorus removal in sewage treatment based on fuzzy neural network. CIESC Journal. 71(03). 1217-1225. DOI: 10.11949/0438-1157.20191514.
[15] Tao, X.M., Luo, L. & Liu, Z.G. (2015). Research and simulation of injection molding machine barrel temperature control algorithm based on segmented PID. Plastics. 44(03), 68-70. DOI: CNKI: SUN: SULA.0.2015-03-022.
[16] Zhou, P.Q. (2016). Research on synchronization control technology of double winches based on fuzzy neural network. Machine Design and Manufacture. 9, 64-68. DOI: 10.19356/j.cnki.1001-3997.2016.09.017.
[17] Li, J.J., Xu, Y., Zhang, G., Wei, Z.Y. & Zhang, Y.B. (2015). Irrigation controller design based on BP neural network prediction and fuzzy control. Machine Design and Research. 31(05), 150-154. DOI: 10.13952/j.cnki.jofmdr. 2015.0207.
[18] Luo, C.N., Hao, R.K. & Yang, W. (2018). Boiler temperature control simulation in industrial production process. Computer simulation. 35(09), 358-362. DOI: 10.3969/j.issn.1006-9348.2018.09.074.
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Authors and Affiliations

Zou Chaoxin
1
Li Rong
1
Xie Zhiping
1
Su Ming
1
Zeng Jingshi
2
Ji Xu
1
Ye Xiaoli
1
Wang Ye
1

  1. Guizhou Normal University, China
  2. Guizhou Zhenhua New Material Co., Ltd., China
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Abstract

The article presents the results of model research concerning the change of technology of argon blowing into liquid steel at the ladle furnace, using the dual plug system. The results of numerical simulations were verified with experimental data carried out on the water model device. The verified model was used to perform numerical simulations to predict the impact of using a new gas injection technology – with different flow rates – on the time to achieve the assumed degree of metal chemical homogenization after alloy addition. Simulation results show that argon blowing metal bath in dual plug mode can effectively reduce mixing time compared to conventional technology with the same gas flow rates. Generally, the use of the dual plug system is beneficial for reducing the bath mixing time, however, the assumed optimal proportion of gas blown through individual plug should be followed. Finally, numerical predictions were used to perform experimental melt under industrial conditions. Industrial verification has clearly confirmed the validity of numerical modeling and showed that also in industrial conditions, a shorter time of chemical homogenization was obtained for the dual plug system.
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Authors and Affiliations

M. Warzecha
1
A. Hutny
1
P. Warzecha
1
Z. Kutyła
2
T. Merder
3

  1. Czestochowa University of Technology, Faculty of Production Engineering and Materials Technology, 19 Armii Krajowej Av., 42-200 Czestochowa, Poland
  2. CMC Poland Sp. z o.o., 82 Piłsudskiego Str., 42-400 Zawiercie, Poland
  3. Silesian University of Technology, Faculty of Materials Engineering and Metallurgy, 8 Krasinskiego Str., 40-019 Katowice, Poland
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Abstract

The article presents the results of tests of the application of magnetic fuel activators, which improve the efficiency of metallurgical furnaces and positively affect the ecological aspects of their work. Energy indicators for metallurgical furnaces during operation before and after installation of magnetic fuel activators as well as the results of composition and concentration of emitted pollutants are included in the paper. The magnetic activation of liquid and gaseous fuels modifies their structure. As a result of the activation, the fuel mixture is selectively saturated with oxygen in the zone of free fuel flow. The combustion conditions were close to optimal, which is confirmed by the reduction of pollutants in the exhaust gases. Fuel saving in the combustion process is also a measurable economic effect. The tests included ovens of several types: pusher furnace, one and two chamber furnaces and a furnace with a rotary shaft. Several-month measurement cycles were carried out on each of them. The experiments consisted in the analysis of gas and heat consumption per month in individual furnaces before and after the use of magnetic fuel activators. The effectiveness of using activators was determined on the basis of the results of the tests carried out. As a result of a twelve-month test cycle on the pusher type furnace, a 36% reduction in gas consumption and a 22% reduction in heat consumption were achieved. After a seventeen-month measurement cycle on chamber furnaces, a 35% reduction in gas consumption and 6% in heat consumption were achieved. The tests on furnaces with a rotary shaft lasted fourteen months and showed a reduction in gas consumption by 8%. An improvement in the composition of fumes in the furnace atmosphere was achieved in all units with magnetic activators installed, as well as a reduction in the emission of harmful pollutants into the atmosphere from the installation.

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Authors and Affiliations

Przemysław Szymanek
Anna Pajdak
ORCID: ORCID
Arkadiusz Szymanek
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Abstract

The research involved coal from 11 coal mines in the USCB in Poland, intended for combustion in power plants and for home furnaces. It has been stated that the content of As, Cd, Co, Cr, Cu, Mo, Ni, Pb, Sb and Zn in the ash of coal fines from the USCB with a density of <1.30 × 103 kg/m3 is the largest, and in the ash fraction with a density >2.00 × 103 kg/m3 is the smallest The fraction ash of coal fine with a density> 2.00 × 103 kg/m3 has the greatest impact on the content of As, Cd, Co, Cr, Mo, Pb and Zn in whole coal fines from the USCB. In turn, the largest impact on the content of Cu, Ni and Sb in whole fine coal ash has the fraction of coal fine having a density of 1.60–2.00 × 103 kg/m3 (for Cu) and fraction with a density <1.35 × 103 kg/m3 (Ni and Sb). The main carriers of elements in fine coal ash, thus in future furnace waste, are the grains of aluminosilicates and iron oxides resulting from the combustion of probably fusinite and semifusinite and the combustion of adhesions of these macerals with dolomite, ankerite and pyrite. The purification of fine coal from the matter with a density >2.00 × 103 kg/m3 may reduce the sulfur content (by 40%), the content of main element oxides (from 33% to 85%) and the content of ecotoxic elements (from 7% to 59%) in fine coal ash, i.e. in potential furnace wastes. Due to the small content of mineral matter, ash and sulfur in coal, small content of Al, Fe, Ca, Mg, Na, K, P oxides and high content of SiO2 in coal ash, low value of the Rogi sinterability index, small inclination of coal fine to slag the furnaces and boiler fouling by sludge, the investigated coal was favorable for technological reasons, fuel in power plants and for home furnaces

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Authors and Affiliations

Henryk R. Parzentny
Leokadia Róg
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Abstract

Compacted graphite iron, also known as vermicular cast iron or semiductile cast iron is a modern material, the production of which is increasing globaly. Recently this material has been very often used in automotive industry. This paper reviews some findigs gained during the development of the manufacturing technology of compacted graphite iron under the conditions in Slévárna Heunisch Brno, Ltd. The new technology assumes usage of cupola furnace for melting and is beeing developed for production of castings weighing up to 300 kilograms poured into bentonite sand moulds.

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Authors and Affiliations

J. Heunisch
O. Bouska
A. Zadera
K. Nedelova
F. Kobersky
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Abstract

The article analyzes the influence of selected factors on the activity rate of cement binder containing 50% of ground granulated blast furnace slag in its composition. These factors are the chemical and mineral composition of Portland cement CEM I, the degree of grinding of granulated blast furnace slag and Portland cement, and the water/binder ratio. This slag content is characteristic for blast furnace cement CEM III/A. In addition to the application effects, this type of cement is a low-carbon binder (there is a reduction of CO 2 emissions by about 45% compared to Portland cement CEM I). The use of this type of cement in the composition of concrete enables the obtaining of concrete with a very small carbon footprint. Based on the results of our own research, it was found that such a high proportion of ground granulated blast furnace slag in the binder composition leads to a significant reduction in the early compressive strength of standard mortars (after two and seven days of setting). This results in a significant reduction in the use of these types of binders (cements) in selected areas of construction, e.g. prefabrication and high-strength concrete. Analyzing the obtained results of their own research, the authors concluded that the early strength of these types of binders can be significantly improved by increasing the specific surface area (degree of grinding) of Portland cement CEM I and lowering the water/slag ratio (w/s, where: s = cement + slag). The proposed material and technological modifications also enable the obtaining of higher compressive strength at all tested dates. The strength of the standard (after twenty-eight days and over longer periods) is comparable to or higher than that of Portland cement CEM I.
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Authors and Affiliations

Arkadiusz Janic
1
ORCID: ORCID
Zbigniew Giergiczny
2
ORCID: ORCID

  1. Technology Centrum Betotech sp. z o.o., Dąbrowa Górnicza, Poland;
  2. Faculty of Civil Engineering Silesian University of Technology, Gliwice, Poland
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Abstract

Blast furnace and cupola furnace are furnace aggregates used for pig iron and cast iron production. Both furnace aggregates work on very similar principles: they use coke as the fuel, charge goes from the top to down, the gases flow against it, etc. Their construction is very similar (cupola furnace is usually much smaller) and the structures of pig iron and cast iron are very similar too. Small differences between cast iron and pig iron are only in carbon and silicon content. The slags from blast furnace and cupola furnace are very similar in chemical composition, but blast furnace slag has a very widespread use in civil engineering, primarily in road construction, concrete and cement production, and in other industries, but the cupola furnace slag utilization is minimal. The contribution analyzes identical and different properties of both kinds of slags, and attempts to explain the differences in their uses. They are compared by the contribution of the blast furnace slag cooled in water and on air, and cupola furnace slag cooled on air and granulated in water. Their chemical composition, basicity, hydraulicity, melting temperature and surface were compared to explain the differences in their utilization.

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Authors and Affiliations

A. Pribulová
P. Futáš
J. Petrík
M. Pokusová
M. Brzeziński
J. Jakubski
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Abstract

This paper elucidated the potential of electron backscatter diffraction analysis for ground granulated blast furnace slag geopolymers at 1000°C heating temperature. The specimen was prepared through the mechanical ground with sandpaper and diamond pad before polished with diamond suspension. By using advanced technique electron backscatter diffraction, the microstructure analysis and elemental distribution were mapped. The details on the crystalline minerals, including gehlenite, mayenite, tobermorite and calcite were easily traced. Moreover, the experimental Kikuchi diffraction patterns were utilized to generate a self-consistent reference for the electron backscatter diffraction pattern matching. From the electron backscatter diffraction, the locally varying crystal orientation in slag geopolymers sample of monoclinic crystal observed in hedenbergite, orthorhombic crystal in tobermorite and hexagonal crystal in calcite at 1000°C heating temperature.
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Authors and Affiliations

Ikmal Hakem Aziz
1
ORCID: ORCID
Mohd Mustafa Al Bakri Abdullah
2
ORCID: ORCID
Mohd Arif Anuar Mohd Salleh
2
ORCID: ORCID
Sorachon Yoriya
3
ORCID: ORCID
Rafiza Abd Razak
4
ORCID: ORCID
Rosnita Mohamed
1
ORCID: ORCID
Madalina Simona Baltatu
5
ORCID: ORCID

  1. Universiti Malaysia Perlis (UniMAP), Geopolymer & Green Technology, Centre of Excellence (CEGeoGTech), Perlis, Malaysia
  2. Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Perlis, Malaysia
  3. National Metal and Material Technology Center (MTEC), National Science and Technology Development Agency (NSTDA), 114, Thailand Science Park, Pahonyothin Rd., Khlong 1, Khlong Luang, Pathum Thani 12120, Thailand
  4. Department of Civil Engineering Technology, Faculty of Engineering Technology, Universiti Malaysia Perlis (UniMAP), 02100 Padang Besar, Perlis, Malaysia
  5. Gheorghe Asachi Technical University of Iasi, Faculty of Materials Science and Engineering, 700050, Iasi, Romania
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Abstract

Steel loss related to the formation of scale is a parameter that is of great importance in the charge heating process. The value of steel loss determined by the thickness of the scale layer affects the intensity of the heat transfer process in the heating furnace, but also constitutes a significant element in the heat-material balance. Reducing the loss of steel during charge heating has a positive effect on heat consumption and material losses, which is extremely important in the context of energy and resource savings, the main elements of sustainable development processes. The methodology of determining the loss of steel to scale in an industrial heating furnace is presented in the paper. The results of calculations for various charge temperatures at the entrance to the furnace are presented. The influence of furnace operating conditions on steel loss is discussed.
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Authors and Affiliations

J. Boryca
1
ORCID: ORCID
T. Wyleciał
1
ORCID: ORCID
D. Urbaniak
1
ORCID: ORCID

  1. Czestochowa University of Technology, 19 Armii Krajowej Av., 42-200 Czestochowa, Poland
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Abstract

This study investigated the suitability of Ijero-Ekiti quartz as a refractory raw material for industrial furnace applications. In order to ascertain its prospective applications, the thermal behaviour, mineralogical composition and chemical composition were determined. Ijero-Ekiti quartz was characterized using Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Thermogravimetric and Differential Thermal analysis (TGA and DTA). Its thermal conductivity with specific heat coefficient was determined. The outcome revealed that the quartz sample has a high purity of 94.3% SiO 2, making it suitable as a refractory material. The XRD analysis revealed the presence of alpha-quartz as the dominant crystal phase, which is desirable for refractory applications. The FTIR analysis indicated the absence of hydroxyl (-OH) groups. This indicates a low risk of failure and damage such as spalling, cracking and other forms of damage when produced into bricks. The TGA and DTA displayed significant mass losses and large endothermic bands, which were connected to the dehydroxylation of the quartz rock samples. Based on the demonstrated qualities, the quartz rock sample could be subjected to thermal processing. This study therefore established that Ijero-Ekiti quartz is a suitable raw material for refractory applications due to its high purity, alpha-quartz dominant crystal phase, absence of hydroxyl groups, and uniform morphology.
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Bibliography

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Authors and Affiliations

B.V. Omidiji
1
O.B. Ogundipe
2
H.A. Owolabi
1

  1. Obafemi Awolowo University, Ile-Ife, Nigeria
  2. Landmark University, Omu-Aran, Nigeria
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Abstract

Heat consumption and steel loss for scale determine the costs of a heating process. The heating rate influences both. This paper evaluates the heating rate of a long charge made of three various materials, depending on the changes of the furnace atmosphere on the rotary furnace circumference. Numerical computing was performed based on a formulated heat transfer model in the rotary furnace chamber, while considering the growth of the scale layer. One heating curve was selected, which has allowed the heating time to be reduced by 36% while limiting the scale loss by 40%. It was also shown that the thermal stresses and strains should not lead to fractures of the charge heated.
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Authors and Affiliations

B. Hadała
1
ORCID: ORCID
M. Rywotycki
1
ORCID: ORCID
Z. Malinowski
1
ORCID: ORCID
Sz. Kajpust
2
S. Misiowiec
2

  1. AGH University of Science and Technology, Al. A. Mickiewicza 30, 30-059 Krakow, Poland
  2. Zarmen FPA Sp. z o.o., 39 Filarskiego Str., 47-330, Zdzieszowice, Poland
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Abstract

Refractories are the basic material for the construction of the lining of a melting furnace used, among other things, in the foundry industry. The article describes a comparative study of the influence of the type of moulding on the quality of the finished refractory product. A method for making products from refractory materials was proposed and a test methodology was developed. The results, based on a classic study of the quality of these materials, confirm a strong influence on the quality of the materials obtained in terms of reduced porosity and homogeneity of pore size.
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Authors and Affiliations

Alicja Trela
1
ORCID: ORCID
Alena Pribulová
2
ORCID: ORCID
Peter Futas
2
ORCID: ORCID

  1. AGH University of Krakow, Faculty of Foundry Engineering, Al. Mickiewicza 30, 30-059 Kraków, Poland
  2. Technical University Kosice, Department of Metallurgy, Slovakia
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Abstract

Both the steel loss to scale and the scale adhesion are very important parameters of the heating process. High values of steel loss (large thickness of the scale layer) reduce the heat exchange intensity in the furnace chamber, which results in higher energy consumption. A low adhesion value adversely affects the operation of heating furnaces, while too high value causes the scale to roll into a steel product and deteriorate its purity and quality.
The paper presents the research methodology and the results of measurements of steel loss and scale adhesion. The effect of the excess air combustion ratio values on loss of steel and scale adhesion for constant furnace efficiency is discussed. This influence was described by mathematical dependencies. The tests were carried out for traditional technology and rational technology, enabling the reduction of steel losses to scale and energy consumption.
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Authors and Affiliations

T. Wyleciał
1
ORCID: ORCID
J. Boryca
1
ORCID: ORCID
D. Urbaniak
2
ORCID: ORCID

  1. Czestochowa University of Technology, Faculty of Production Engineering and Materials Technology, Department of Production Management,19 Armii Krajowej Av., 42-201 Czestochowa, Poland
  2. Czestochowa University of Technology, Faculty of Mechanical Engineering and Computer Science, Department of Thermal Machinery, 19 Armii Krajowej Av., 42-201 Czestochowa, Poland
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Abstract

Refractories are the basic material for the construction of the lining of a melting furnace used, among other things, in the foundry industry. The article describes a comparative study of the influence of the type of moulding on the quality of the finished refractory product. A method for making products from refractory materials was proposed and a test methodology was developed. The results, based on a classic study of the quality of these materials, confirm a strong influence on the quality of the materials obtained in terms of reduced porosity and homogeneity of pore size.
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Authors and Affiliations

Alicja Trela
ORCID: ORCID
M. Brzeziński
1
ORCID: ORCID
A. Pribulova
2
ORCID: ORCID
Peter Futas
ORCID: ORCID

  1. AGH University of Krakow, Faculty of Foundry Engineering, Al. Mickiewicza 30, 30-059 Krakow, Poland
  2. Technical University, Department of Metallurgy, Kosice, Slovakia
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Abstract

Iron black commonly employs in thermal insulation riser sleeves due to its ability to react with aluminum powder, generating heat. However, the complex production process and unstable composition of iron black lead to high production costs. The potential of using arc furnace flue ash (AFFA) as a complete substitute for iron black and MnO2 and KNO3 oxidizing agents in conventional riser sleeves was investigated in this study. Waste material can be transformed into a valuable resource, while production costs can be reduced by utilizing arc furnace flue ash. The research examined the impact of varying types and amounts of arc furnace flue ash on riser sleeve temperature and holding time by conducting single-factor and orthogonal optimization experiments. The orthogonal optimization experiment determined that the optimum ratio of each oxidant was 6 % arc flue ash, 3 % MnO2 and 6 % KNO3. At this time, the highest temperature was 1512 ℃ and the holding time was 244 s. Results indicated that different types of arc furnace flue ash used as an oxidizing agent demonstrated superior holding capacity and heat generation performance compared to iron black. Additionally, a comparative analysis of factory casting experiments using ductile iron 600-3 (IS) revealed that both arc furnace flue ash and iron black risers effectively countered shrinkage. However, arc furnace flue ash risers exhibited improved mechanical properties, as evidenced by the hardness of the castings.
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Bibliography

[1] Lu, J.J., Qian, J.B., Yang, L. & Wang, H.F. (2023). Preparation and performance optimization of organosilicon slag exothermic insulating riser. Archives of Foundry Engineering. 23(1), 75-82. DOI: 10.24425/afe.2023.144283.
[2] Vasková, I., Conev, M. & Hrubovčáková, M. (2017). The influence of using different types of risers or chills on shrinkage production for different wall thickness for material EN-GJS-400-18LT. Archives of Foundry Engineering. 17(2), 131-136. DOI: 10.1515/afe-2017-0064.
[3] Sowa, L., Skrzypczak, T. & Kwiatoń, P. (2019). The influence of riser shape on feeding effectiveness of solidifying casting. Archives of Foundry Engineering. 19(4), 91-94. DOI: 10.24425/afe.2019.129636.
[4] Krajewski, P.K., Gradowski, A. & Krajewski, W.K. (2013). Heat exchange in the system mould - riser - ambient. part ii: surface heat emission from open riser to ambient. Archives of Metallurgy and Materials. 58(4), 1149-1153. DOI: 10.2478/amm-2013-0140.
[5] Xu, X. Hui,G,D. Ma, B, H . et al. (2017). Research on high efficiency heat insulation risers for casting. Casting technology. 38(03), 726-728. (in Chinese).
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[9] Chen, J. (2022). Application of steelmaking electric arc furnace ash in sintered bricks[J]. Brick and Tile, 2020 (7): 25-27. DOI:10.16001/j.cnki.1001-6945.2020.07.011.
[10] Wang, J., Zhang, Y.Y., Cui, K.K., Fu. T., Gao, J.J. Shahid Hussain, Tahani Saad AlGarni. (2021). Pyrometallurgical recovery of zinc and valuable metals from electric arc furnace dust – A review. Journal of Cleaner Production. 298, 126788. DOI:10.1016/j.jclepro.2021.126788.
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[12] Lin, X.L. Peng. Z.W., Yan. J.X., Li. Z., Z. Hwang, J.Y. Zhang, Y.B., Li, G.H., Jiang, T. (2017). Pyrometallurgical recycling of electric arc furnace dust. Journal of Cleaner Production. 149, 1079-1100. DOI:10.1016/j.jclepro.2017.02.128.
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Authors and Affiliations

Junjie Zhu
1
ORCID: ORCID
Jian Feng
2
ORCID: ORCID
Ling Liu
1
ORCID: ORCID
Huafang Wang
1
ORCID: ORCID
Jijun Lu
1
ORCID: ORCID

  1. School of Mechanical Engineering and Automation, Wuhan Textile University, China
  2. CRRC Corporation Limited, China
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Abstract

Electromagnetic processing of molten copper is provided in a special kind of electrical furnace called an induction furnace with a cold crucible (IFCC), making it possible to successfully remove impurities from the workpiece. In order to analyze the process in a sufficient way not only electromagnetic, thermal and flow but also metallurgical and mass transfer phenomena in the coupled formulation should be taken into consideration. The paper points to an analysis of the kinetic process of lead evaporation from molten copper. It was shown that mass transport in the gas phase determines the rate of the analyzed evaporation process. The possibility of removal of lead from molten copper is analyzed and described.
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Authors and Affiliations

Albert Smalcerz
1
ORCID: ORCID
Leszek Blacha
1
ORCID: ORCID
Jerzy Barglik
1
ORCID: ORCID
Ivo Dolezel
2
ORCID: ORCID
Tadeusz Wieczorek
1
ORCID: ORCID

  1. Silesian University of Technology Krasinskiego 8, 40-019 Katowice, Poland
  2. Faculty of Electrical Engineering, University of West Bohemia Univerzitní 26, 301 00 Pilsen, Czech Republic
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Abstract

Titanium alloys belonging to the group of modern metallic materials used in many industries, including the aerospace industries. Induction crucible vacuum furnaces and induction furnaces with cold crucible are most commonly used for their smelting. When operating these devices, one can deal with an adverse phenomenon of decrease in the content of alloy elements that are characterized by higher equilibrium vapour pressure than the matrix metal or titanium, in the metal bath. In the paper, results of the study on aluminium evaporation from the Ti-Al-Nb, Ti-Al-V and Ti-Al alloys (max 6.2 % wt.) during smelting in a vacuum induction melting (VIM) furnace are presented. The experiments were performed at 10 to 1000 Pa for 1973 K and 2023 K. A significant degree of aluminium loss has been demonstrated during the analysed process. The values of relative aluminium loss for all the alloys ranged from 4 % to 25 %. Lowering the pressure in the melting system from 1000 Pa to 10 Pa resulted in increased values of aluminium evaporation flux from 4.82⋅10-5 to 0.000327 g⋅cm-2⋅s-1 for 1973 K and from 9.28⋅10-5 to 0.000344 g⋅cm-2⋅s-1 for 2023 K. The analysis of the results obtained took into account the value of the actual surface of the liquid metal. In the case of melting metals in an induction furnace, this surface depends on the value of power emitted in the charge. At greater power, we observe a significant increase in the bath surface due to the formation of a meniscus.
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Authors and Affiliations

Albert Smalcerz
ORCID: ORCID
Leszek Blacha
ORCID: ORCID
J. Łabaj
1
ORCID: ORCID

  1. Silesian University of Technology, Faculty of Materials Engineering and Metallurgy, ul. Krasińskiego 8, 40-019 Katowice, Poland
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Abstract

In this paper, the results of the study on aluminium evaporation from the Al-Zn alloys (4.2% weight) during remelting in a vacuum induction furnace (VIM) are presented. The evaporation of components of liquid metal alloys is complex due to its heterogeneous nature. Apart from chemical affinity, its speed is determined by the phenomena of mass transport, both in the liquid and gas phase. The experiments were performed at 10-1000 Pa for 953 K - 1103 K. A significant degree of zinc loss has been demonstrated during the analysed process. The relative values of zinc loss ranged from 4 to 92%. Lowering the pressure in the melting system from 1000 Pa to 10 Pa caused an increase in the value of density of the zinc evaporating stream from 3.82⋅10-5 to 0.000564 g⋅cm-2⋅s-1 at 953 K and 3.32⋅10-5 to 0.000421 g⋅cm-2⋅s-1 for 1103 K. Based on the results of the conducted experiments. it was found that evaporation of zinc was largely controlled by mass transfer in the gas phase and only for pressure 10 Pa this process was controlled by combination of both liquid and gas phase mass transfer.
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Authors and Affiliations

Albert Smalcerz
ORCID: ORCID
Leszek Blacha
ORCID: ORCID
B. Węcki
1
ORCID: ORCID
D.G. Desisa
2
ORCID: ORCID
J. Łabaj
3
ORCID: ORCID
M. Jodkowski
1
ORCID: ORCID

  1. Department of Testing and Certification "ZETOM", Poland
  2. Department of Industrial, Informatics Silesian University of Technology, Joint Doctorate School, Poland
  3. Faculty of Materials Engineering, Silesian University of Technology, Poland
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Abstract

In this study, solidification/stabilization (S/S) of electric arc furnace dust (EAFD) which is generated during the production of steel from scrap metals and classified as hazardous waste were investigated by using different ratios of cement and low grade MgO (LG MgO) as binding agents. Type I PC 42.5 R portland cement and LG MgO which contains 70–80% MgO were used. S/S blocks that contain different ratios of binding agents which have 1/0.5 – 1/1 – 1/2 – 1/3 – 1/4 – 1/5 cement/LG MgO ratio and S/S blocks which contain only cement and no LG MgO agents were prepared. These blocks, which contain 3 different waste ratios according to weight, 20%, 30% and 40% respectively, were produced and exposed to 28-day water purification. At the end of the purification process, S/S blocks were extracted using TCLP (Toxicity Characteristic Leaching Procedure) tests in order to determine the leaching behavior of Zn, Pb, and Cd in S/S blocks. By the end of this study, it was concluded that the recovery of EAFD is possible and applicable by immobilization. The findings of the study concluded that environmental performances or structural properties of blocks contain 30% waste by weight are suitable. This method is a proper one for recovering and treatment of EAFD with mixture of cement and LG MgO.

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Authors and Affiliations

Ahmet Can Bayraktar
Edip r Avşa
İsmail Toröz
Kadir Alp
Asude Hanedar

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