In this paper we discuss the test results for concretes containing various amounts of ggbs as compared to concretes made with Portland cement. The main objective of these tests is to evaluate the influence of varying air content in such mixtures on the structure and frost resistance of concrete. The authors suggest that the approach presented here allows for a safe design of concrete mixtures in terms of their frost resistance.
The results indicate that concrete can be resistant to surface scaling even at the W/C ratio markedly higher than 0.45. Increased addition of ggbs leads to a decrease in concrete resistance to surface scaling. Proper air entrainment is the fundamental factor for frost-resistant concrete, and the air void system has to be assessed (micropore content A₃₀₀, spacing factor L). The addition of ggbs increases pore diameters, thus, to obtain the appropriate air pore spacing factor, micropore quantities introduced have to be increased.
At thermal junctions of aluminium alloy castings and at points where risering proves to be difficult there appear internal or external
shrinkages, which are both functionally and aesthetically inadmissible. Applying the Probat Fluss Mikro 100 agent, which is based on
nano-oxides of aluminium, results in the appearance of a large amount of fine microscopic pores, which compensate for the shrinking of
metal. Experimental tests with gravity die casting of AlSi8Cu3 and AlSi10Mg alloys have confirmed that the effect of the agent can be of
advantage in foundry practice, leading to the production of castings without local concentrations of defects and without the appearance of
shrinkages and macroscopic gas pores. Also, beneficial effect on the mechanical properties of the metal has been observed.
Molecular motors are nature’s nanomachines, and are the essential agents of movement that are an integral part of many living organisms. The supramolecular machine, called the nuclear pore complex (NPC), controls the transport of all cellular material between the cytoplasm and the nucleus that occurs naturally in all biological cells. In the presence of appropriate chemical stimuli, the NPC opens or closes, like a gating mechanism, and permits the flow of material into and out of the nucleus. As a first step in understanding the design characteristics of the NPC, nanoscale studies were conducted to understand the transport characteristics of an idealized NPC model using CFD analysis, discrete element transport and coupled fluid-solid analysis. Results of pressure and velocity profiles obtained from the models indicate that the fluid density, flexibility of walls and the geometry of the flow passage are important in the design of NPC based nano- and micro-motors.
Fractal analysis is one of the rapidly evolving branches of mathematics and finds its application in different analyses such as pore space description. It constitutes a new approach to the issue of their natural irregularity and roughness. To be properly applied, it should be encompassed by an error estimation. The article presents and verifies uncertainties along with imperfections connected with image analysis and expands on the possible ways of their correction. One of key aspects of such research is finding both appropriate place and the number of photos to take. A coarse- grained sandstone thin section was photographed and then pictures were combined into one, bigger image. Fractal parameters distributions show their change and suggest that the accurately gathered group of photos include both highly and less porous regions. Their amount should be representative and adequate to the sample. The resolution influence on the fractal dimension and lacunarity values was examined. For SEM limestone images obtained using backscattered electrons, magnification in the range of 120x to 2000x was used. Additionally, a single pore was examined. The acquired results point to the fact that the values of fractal dimension are similar to a wide range of magnifications, while lacunarity changes each time. This is connected with changing homogeneity of the image. The article also undertakes a problem of determining fractal parameters spatial distribution based on binarization. The available methods assume that it is carried out after or before the image division into rectangles to create fractal dimension and lacunarity values for interpolation. An individual binarization, although time consuming, provides better results that resemble reality to a closer degree. It is not possible to define a single, correct methodology of error elimination. A set of hints has been presented that can improve results of further image analysis of pore space.
This paper presents the qualitative and quantitative characteristics of microstructures of Neogene clays from Warsaw, Poland. Scanning Electron Microscope (SEM) studies were used for the microstructural analysis of natural clays and clay pastes. Qualitative microstructural changes were observed: from a honeycomb microstructure for the initial clay paste to a turbulent microstructure for the dried paste. It was also noticed that water loss caused by the increase of the suction pressure had a significant impact on the microstructural transformations. Significant changes in the quantitative values of the pore space parameters were also observed. Increase of suction pressure and water loss caused a decrease in porosity and changes in the values of morphometric parameters, such as pore distribution; for example, a significant increase of the number of pores of 0−10 μm size and changes in the geometric parameters of the pore space were noticed with the increase of suction pressure. The pore space with larger isometric pores was modified into a pore space with the dominance of small anisometric and fissure-like pores. The increased degree of anisotropy from a poorly-oriented to a highly-oriented microstructure was also observed. After rapid shrinkage the reduction in the number of pores, maximum pore diameter, and total pore perimeter was recorded. The process of rapid water loss induced the closure of very small pores. A similar effect was observed during the increase of the suction pressure, where the closure of pore space of the clay pastes was observed very clearly.
Direct energy deposition (DED) is a three-dimensional (3D) deposition technique that uses metallic powder; it is a multi-bead, multi-layered deposition technique. This study investigates the dependence of the defects of the 3D deposition and the process parameters of the DED technique as well as deposition characteristics and the hardness properties of the deposited material. In this study, high-thermal-conductivity steel (HTCS-150) was deposited onto a JIS SKD61 substrate. In single bead deposition experiments, the height and width of the single bead became bigger with increasing the laser power. The powder feeding rate affected only the height, which increased as the powder feeding rate rose. The scanning speed inversely affected the height, unlike the powder feeding rate. The multi-layered deposition was characterized by pores, a lack of fusion, pores formed by evaporated gas, and pores formed by non-molten metal inside the deposited material. The porosity was quantitatively measured in cross-sections of the depositions, revealing that the lack of fusion tended to increase as the laser power decreased; however, the powder feeding rate and overlap width increased. The pores formed by evaporated gas and non-molten metal tended to increase with rising the laser power and powder feeding rate; however, the overlap width decreased. Finally, measurement of the hardness of the deposited material at 25℃, 300℃, and 600℃ revealed that it had a higher hardness than the conventional annealed SKD61.
Cauchy paved the way for constructing models in concrete technology, and elsewhere. He determined the (nonflat) surface area in 3D by measuring random total projections. Analogously, he determined the length of a curved line in 2D by way of measuring the total projections. The paper will present the mathematical expressions, because in many branches of concrete technology, modelling is found based on such Cauchy concepts. These branches – fractography in compression, tension or shear, fibre reinforcement and permeability estimation – will briefly be mentioned to demonstrate this. It has been found that, for the discussed fields of engineering relevance, major model parameters for cementitious materials are similar to those developed by Cauchy in the 19th century. In the paper some previous investigations concerning fractography, fibre reinforcement and fracture roughness will be summarized but basically a new development on porosimetry will be presented. Particularly a new achievement of successful implementation of the methodology (also based on Cauchy) for optimizing permeability estimation will be discussed.
Microporous carbon molecular sieves of extremely narrow pore size distribution were obtained by carbonization of a novel raw material (Salix viminalis). The precursor is inexpensive and widely accessible. The pore capacity and specific surface area are upgradable by H3PO4 treatment without significant change of narrowed PSD. The dominating pore size indicates that these molecular sieves are a potential competitor to other nanoporous materials such as opened and purified carbon nanotubes.
Porous metals show not only extremely low density, but also excellent physical, mechanical and acoustic properties. In this study, Hastelloy powders prepared by gas atomization are used to manufacture 3D geometries of Hastelloy porous metal with above 90% porosity using electrostatic powder coating process. In order to control pore size and porosity, foam is sintered at 1200~1300°C and different powder coating amount. The pore properties are evaluated using SEM and Archimedes method. As powder coating amount and sintering temperature increased, porosity is decreased from 96.4 to 94.4%. And foam density is increased from 0.323 to 0.497 g/cm3 and pore size is decreased from 98 to 560 μm. When the sintering temperature is increased, foam thickness and strut thickness are decreased from 9.85 to 8.13mm and from 366 to 292 μm.
The objective of this investigation was comparing the penetration of chloride ions in ordinary and air-entrained concretes containing a waste material Fluidized Bed Combustion Fly Ash (FBCFA). All concretes were tested with 15% and 30% cement replacement by FBCFA, with the same water-binder ratio of 0.45. Two kinds of fly ash coming from fluid bed combustion in two power plants in Poland have been used.
In this study the rapid chloride permeability test – Nordtest Method BUILD 492 method – was used. The microstructure of the concrete was analyzed on thin polished sections and the measurement of air voids sizes and their distribution, using digital image analysis, was carried on according to PN-EN 480-11:2008.
Obtained results have shown a significant influence of partial cement replacement by FBCFA on the chloride ions movements in concrete. It has been found that this kind of addition reduced considerably the chloride ion penetration. The influence of air entrainment on the chloride diffusion coefficients was also measured and it was shown that application of air-entraining admixture for concretes with FBCFA reduce the chloride diffusion coefficient but it should be used with caution.