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Abstract

The results of studies on the use of magnesium alloy in modern Tundish + Cored Wire injection method for production of vermicular graphite cast irons were described. The injection of Mg Cored Wire length is a treatment method which can be used to process iron melted in an electric induction furnace. This paper describes the results of using a high-magnesium ferrosilicon alloy in cored wire for the production of vermicular graphite cast irons at the; Tundish + Cored Wire to be injected methods (PE) for pearlitic-ferritic matrix GJV with about 25 %ferrite content. The results of calculations and experiments have indicated the length of the Cored Wire to be injected basing on the initial sulfur content and weight of the treated melt. The paper presents a microstructure matrix and vermicular graphite in standard sample and different walled castings. The results of numerous trials have shown that the magnesium Tundish + PE Method process can produce high quality vermicular graphite irons under the specific industrial conditions of the above mentioned foundries.

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Authors and Affiliations

E. Guzik
D. Kopyciński
T. Kleingartner
M. Sokolnicki
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Abstract

The results of studies on the use of magnesium alloy in modern Tundish for production of vermicular graphite cast irons were described. This paper describes the results of using a low-magnesium ferrosilicon alloy for the production of vermicular graphite cast irons. The paper presents a vermicular (and nodular) graphite in different walled castings. The results of trials have shown that the magnesium Tundish process can produce high quality vermicular graphite irons under the specific industrial conditions of Foundries - Odlewnie Polskie S.A. in Starachowice. In this work describes too preliminary studies on the oxygen state in cast iron and their effect on graphite crystallization.

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Authors and Affiliations

D. Kopyciński
E. Guzik
A. Nowak
M. Ronduda
M. Sokolnicki
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Abstract

The purpose of the work was to determine the morphology of graphite that occurs in vermicular cast iron, both in the as-cast state and after heat treatment including austenitization (held at a temperature of 890 °C or 960 °C for 90 or 150 min) and isothermal quenching (i.e. austempering, at a temperature of 290 °C or 390 °C for 90 or 150 min). In this case, the aim here was to investigate whether the heat treatment performed, in addition to the undisputed influence of the cast iron matrix on the formation of austenite and ferrite, also affects the morphology of the vermicular graphite precipitates and to what extent. The investigations were carried out for the specimens cut from test coupons cast in the shape of an inverted U letter (type IIb according to the applicable standard); they were taken from the 25mm thick walls of their test parts. The morphology of graphite precipitates in cast iron was investigated using a Metaplan 2 metallographic microscope and a Quantimet 570 Color image analyzer. The shape factor F was calculated as the quotient of the area of given graphite precipitation and the square of its perimeter. The degree of vermicularization of graphite was determined as the ratio of the sum of the graphite surface and precipitates with F <0.05 to the total area occupied by all the precipitations of the graphite surface. The examinations performed revealed that all the heat-treated samples made of vermicular graphite exhibited the lower degree of vermicularization of the graphite compared to the corresponding samples in the as-cast state (the structure contains a greater fraction of the nodular or nearly nodular precipitates). Heat treatment also caused a reduction in the average size of graphite precipitates, which was about 225μm2 for the as-cast state, and dropped to approximately 170-200 μm2 after the austenitization and austempering processes.
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Bibliography

[1] Sorelmetal, On the nodular cast iron. (2006). Warsaw: Ed. Metals & Minerals Ltd.
[2] Tupaj, M., Orłowicz, A. W., Mróz, M., Kupiec, B., et al. (2020). Ultrasonic Testing of Vermicular Cast Iron Microstructure. Archives of Foundry Engineering. 20(4), 36-40. DOI: 10.24425/afe.2020.133345.
[3] Guzik, E. & Kleingartner, T. (2009). A study on the structure and mechanical properties of vermicular cast iron with pearlitic-ferritic matrix. Archives of Foundry Engineering. 9(3), 55-60.
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[5] Zhang, Y., Guo, E., Wang, L., Zhao, S., et al. (2020). Effect of the matrix structure on vermicular graphite cast iron properties. International Journal of Materials Research. 111(5), 379-384. DOI: 10.3139/146.111891.
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[13] Pytel, A., Gazda, A. (2014) Evaluation of selected properties in austempered vermicular cast iron (AVCI). Transactions of Foundry Research Institute. LIV(4), 23-31. DOI: 10.7356/iod.2014.18.
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[16] Jakubus, A., Kostrzewa, J., Ociepa, E. (2021). The influence of parameters of heat treatment on the microstructure and strength properties of the ADI and the AVGI irons. METAL 2021, 30th Anniversary International Conference on Metallurgy and Materials. May 26 - 28, 2021, Brno, Czech Republic, EU (pp.34-39). DOI: 10.37904/metal.2021.4082.
[17] Podrzucki, C. (1991). Cast iron. Structure, properties, applications. vol. 1 and 2, Cracow: Ed. ZG STOP. (in Polish).
[18] Soiński, M.S. & Mierzwa, P. (2011). Effectiveness of cast iron vermicularization including ‘conditioning’ of the alloy. Archives of Foundry Engineering. 11(2), 133-138.
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[24] Soiński, M.S. (1980). Application of shape measurement of graphite precipitates in cast iron in optimising the spheroidizing process. Acta Stereologica. 5(2), 311-317.
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Authors and Affiliations

M.S. Soiński
1
A. Jakubus
1
ORCID: ORCID
B. Borowiecki
1
P. Mierzwa
2

  1. The Jacob of Paradies University in Gorzów Wielkopolski, ul. Teatralna 25, 66-400 Gorzów Wielkopolski, Poland
  2. Czestochowa University of Technology, Poland
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Abstract

The paper presents the results of calorimetric tests of segment elements of fireplace inserts. The aim of the work was to optimize their thermal power by replacing the previously used gray cast iron with flake graphite with gray iron with vermicular graphite and replacing the existing geometry of the heat transfer surface with a more developed one. It turned out that the thermal power of the test segments made of cast iron with vermicular graphite was higher compared to the segments of the same shape made of gray cast iron with flake graphite. It was found that the use of segments made of vermicular cast iron with a ferritic matrix allowed for an increase in the thermal power value by dozen percent, compared to segments of the same shape made of vermicular cast iron with a pearlitic matrix. The test results showed that the thermal power of the test segments depends on the variant of the development of both the heat receiving surface and the heat giving off surface. The highest value of the thermal power was obtained when ribbing in the form of a lattice was used on both of these surfaces, and the lowest when using flat surfaces.
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Bibliography

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[12] Mróz, M., Orłowicz, A.W., Tupaj, M., Jacek-Burek, M., Radoń, M., Kawiński, M. (2019). Improvement of operating performance of a cast-iron heat exchanger by application of a copper alloy coating. Archives of Foundry Engineering. 19(3), 84-87.
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Authors and Affiliations

Marek Mróz
ORCID: ORCID
A.W. Orłowicz
1
ORCID: ORCID
M. Tupaj
1
ORCID: ORCID
M. Lenik
1
ORCID: ORCID
M. Kawiński
2
M.. Kawiński
2

  1. Rzeszow University of Technology, Al. Powstańców Warszawy 12, 35-959 Rzeszów, Poland
  2. Cast Iron Foundry KAWMET, ul. Krakowska 11, 37-716 Orły, Poland
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Abstract

The article presents the results of research on the abrasion resistance of cast iron with vermicular graphite in the as-cast state and after austempering (the latter material is referred to as AVGI – Austempered Vermicular Graphite Iron). Austenitization was carried out at the temperature values of either 900°C or 960°C, and austempering at the temperature values of either 290°C and or 390°C. Both the austenitization and the austempering time was equal to 90 minutes. The change of the pearlitic-ferritic matrix to the ausferritic one resulted in an increase in mechanical properties. Abrasion tests were conducted by means of the T-01M pin-on-disc tribometer. The counter-sample (i.e. the disc) was made of the JT6500 friction material. Each sample was subject to abrasion over a sliding distance of 4000 m. The weight losses of both samples and counter-samples were determined by the gravimetric method. It was found that the vermicular cast iron austenitized at 900°C and austempered at 290°C was characterized by the lowest wear among the evaluated cast iron types. The geometric structure of the surface layer after the dry friction test exhibited irregular noticeable grooves, distinct oriented abrasion traces, plastic flow of the material, microcracks, and pits generated by tearing out the abraded material. The largest surface roughness was found for the AVGI cast iron heat-treated according to the variant 3 (Tγ =900 ºC; Tpi = 390°C), while the smallest one occurred in AVGI cast iron subject to either the variant 2 (Tγ =960 ºC; Tpi = 290°C) or the variant 4 (Tγ =900 ºC; Tpi = 290°C) of heat treatment and was equal to either 2.5 μm or 2.66 μm, respectively. It can be seen that the surface roughness decreases with the decrease in the austempering temperature.
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Bibliography

[1] Hebda, M., Wachal, A. (1980). Tribology. Warsaw: Ed. Scientific and Technical Publishers.
[2] Hebda, M. (2007). Processes of friction, lubrication and wear of machines. Warsaw – Radom: Ed. Institute of Sustainable Technologies - PIB.
[3] Podrzucki, C. (1991). Cast iron. Structure, properties, application. vol. 1 and 2. Krakow: Ed. ZG STOP. (in Polish).
[4] Kopyciński, D., Kawalec, M., et al. (2013). Analysis of the structure and abrasive wear resistance of white cast iron with precipitates of carbides. Archives of Metallurgy and Materials. 58(3), 973-976.
[5] Szajnar, J., Walasek, A. & Baron, C. (2013). Tribological and corrosive properties of the parts of machines with surface alloy layer. Archives of Metallurgy and Materials. 58(3), 931-936.
[6] Kovac, P., Jesic, D., Sovilj-Nikic, S., et al. (2018). Energy aspects of tribological behaviour of nodular cast iron. Journal of Environmental Protection and Ecology. 19(1), 163-172.
[7] Cabanne, P., Forrest, R., Roedter, H. (2006). Sorelmetal about nodular cast iron. Warsaw: Metals & Minerals Ltd.
[8] Gumienny, G. (2013). Effect of carbides and matrix type on wear resistance of nodular cast iron. Archives of Foundry Engineering. 13(3), 25-29.
[9] Jeyaprakash, N., Sivasankaran, S., Prabu G., Yang, Che-Hua, & Alaboodi Abdulaziz S. (2019). Enhancing the tribological properties of nodular cast iron using multi wall carbon nano-tubes (MWCNTs) as lubricant additives. Materials Research Express. 6(4). DOI: https://doi.org/10.1088/2053-1591/aafce9
[10] Wojciechowski A., Sobczak J. (2001) Composite brake discs for road vehicles. Warsaw: Motor Transport Institute.
[11] Guzik, E. (2001). Cast iron refining processes. Selected Issues. Archive of Foundry. Monograph No. 1M, 2001. Ed. PAN.
[12] Duenas, J.R., Hormaza, W. & CastroGüiza, G.M. (2019). Abrasion resistance and toughness of a ductile ironproduced by two molding processes with a shortaustempering. Journal of Materials Research and Technology. 8(3), 2605-2612.
[13] Han, J.M., Zou, Q., Barber, G.C. & et al. (2012). Study of the effects of austempering temperature and time on scuffing behavior of austempered Ni–Mo–Cu ductile iron. Wear. 290-291, 99-105
[14] Du, Y., Gao, X., Wang, X. & et al. (2020). Tribological behavior of austempered ductile iron (ADI) obtained at different austempering temperatures. Wear. 456-457(203396), 1-12. DOI: 10.1016/j.wear.2020.203396
[15] Kochański, A., Krzyńska, A., Chmielewski, T. & Stoliński, A. (2015). Comparison of austempered ductile iron and manganese steel wearability. Archives of Foundry Engineering. 15(spec.1), 51-54.
[16] Myszka, D. (2005). Microstructure and surface properties of ADI cast iron. Archives of Foundry. 5(15), 278-283.
[17] Kumari, R., Rao, P. (2009). Study od’s wear behaviour of austempered ductile iron. Journal of Materials Research. 44, 1082-1093.
[18] Medyński, D. & Janus, A. (2018). Abrasive – wear resistance of austenitic cast iron. Archives of Foundry Engineering. 18(3), 43-48.
[19] Pytel, A. & Gazda, A. (2014). Evaluation of selected properties in austempered vermicular cast iron (AVCI). Works of the Foundry Research Institute. LIV(4), 23-31.
[20] Panneerselvama, S., Martis, C.J., Putatunda, S. K. & Boileau, J. M. (2015). An investigation on the stability of austenite in Austempered Ductile Cast Iron (ADI). Materials Science and Engineering: A. 625, 237-246.
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[27] Polish Standard PN-EN 1563, Founding. Spheroidal graphite cast iron, (2000).
[28] Polish Standard PN-EN ISO 945-1: Microstructure of cast irons. Part 1. Graphite classification by visual analysis. November 2009. Correction PN-EN ISO 945-1:2009/AC. April 2010.
[29] Polish Standard PN-75/H-04661: Grey cast iron, nodular cast iron and malleable. Metallographic examinations. Determining of microstructure.
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[39] makland.com.pl. 28.02.2016, time 13.25.

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Authors and Affiliations

A. Jakubus
1
ORCID: ORCID

  1. The Jacob of Paradies University in Gorzów Wielkopolski, ul. Teatralna 25, 66-400 Gorzów Wielkopolski, Poland
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Abstract

The paper presents results of a study on the effect of passage of time on magnesium content in iron alloys and the effect of magnesium content on the number of vermicular graphite precipitations per unit surface area and value of the longitudinal ultrasonic wave velocity for two different vermicularization methods. The study was carried out with the use of inspection bar castings. For specific production conditions, it has been found that in case of application of both the cored wire injection method and the method of pouring liquid metal over magnesium master alloy on ladle bottom, the satisfactory level of magnesium content in the bottom-pour ladle, for which it was still possible to obtain castings with vermicular graphite, was 0.018% Mg. In case of the cored wire injection method, the “time window” available to a pouring station at which castings of vermicular cast iron are expected to be obtained, was about 5 minutes. This corresponds to the longitudinal ultrasonic wave velocity values exceeding 5500 m/s and the number of graphite precipitations per unit surface area above 320 mm–2. In case of the master alloy method, the respective “time window” allowing to obtain castings of vermicular cast iron was only about 3 minutes long. This corresponds to the longitudinal ultrasonic wave velocity value above 5400 m/s and the number of graphite precipitations per unit surface area above 380 mm–2.

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Authors and Affiliations

M. Tupaj
ORCID: ORCID
A.W. Orłowicz
ORCID: ORCID
Marek Mróz
ORCID: ORCID
B. Kupiec
D. Pająk
M. Kawiński
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Abstract

The paper presents the initial results of investigation concerning the abrasion resistance of cast iron with nodular, vermicular, or flake graphite. The nodular and vermicular cast iron specimens were cut out of test coupons of the IIb type with the wall thickness equal to 25 mm, while the specimens made of grey cast iron containing flake graphite were cut out either of special casts with 20 mm thick walls or of the original brake disk. The abrasion tests were carried out by means of the T-01M tribological unit working in the pin-on-disk configuration. The counterface specimens (i.e. the disks) were made of the JT6500 brand name friction material. Each specimen was abraded over a distance of 4000 m. The mass losses, both of the specimens and of the counterface disks, were determined by weighting. It was found that the least wear among the examined materials was exhibited by the nodular cast iron. In turn, the smallest abrasion resistance was found in vermicular cast iron and in cast iron containing flake graphite coming from the brake disk. However, while the three types of specimens (those taken from the nodular cast iron and from grey cast iron coming either from the special casts or from the brake disk) have almost purely pearlitic matrix (P95/Fe05), the vermicular cast iron matrix was composed of pearlite and ferrite occurring in the amounts of about 50% each (P50/Fe50). Additionally, it was found that the highest temperature at the cast iron/counterface disk contact point was reached during the tests held for the nodular cast iron, while the lowest one occurred for the case of specially cast grey iron.

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Authors and Affiliations

A. Jakubus
ORCID: ORCID
M.S. Soiński

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