The paper presents results of coal behaviour during combustion in oxy-fuel atmosphere. The experiment was performed using 3 meter long Entrained Flow Reactor and 1 meter long Drop Tube Reactor. Three hard coals and two lignites were analysed in order to investigate NOx, SO2 emission and fly ash burnout. The measurements were performed along and at the outlet of a combustion chamber for one- and two - stage combustion. In the second stage of the experiment, kinetic parameters for nitrogen evolution during combustion in oxy - fuel and air were calculated and the division of nitrogen into the volatile matter and the char was measured. The conducted experiment showed that emissions in oxy - fuel are lower than those in air.
The problem of harmful casting resins has been present in foundries for many years. Manufacturers are introducing new products that contain in their composition environmentally and eco-friendly ingredients. Unfortunately, not all types of technology can be used, sometimes environmental benefits are disproportionate to the quality of castings and their price. In the foundry industry, the most popular binders are based on organic compounds (often carcinogenic) and other harmful substances. Due to strict legal regulations regarding environmental protection, as well as care for the foundry's workers' comfort - their occurrence should be reduce to a minimum. These compounds often behave also depending on the conditions of use (temperature, atmosphere). The application of various methods of thermal analysis and spectroscopic methods allows to verify the mechanism of resin decomposition process in relation to conditions in the form in both inert and oxidizing atmosphere. For analysis the resins from cold-box technology, were used TG–DTG–DSC, Py-GC/MS methods and specified the course of changes occurring in combination of different atmosphere.
Drops of molten cast iron were placed on moulding sand substrates. The composition of the forming gaseous atmosphere was examined. It
was found that as a result of the cast iron contact with water vapour released from the sand, a significant amount of hydrogen was evolved.
In all the examined moulding sands, including sands without carbon, a large amount of CO was formed. The source of carbon monoxide
was carbon present in cast iron. In the case of bentonite moulding sand with seacoal and sand bonded with furan resin, in the composition
of the gases, the trace amounts of hydrocarbons, i.e. benzene, toluene, styrene and naphthalene (BTX), appeared. As the formed studies
indicate much higher content of BTX at lower temperature it was concluded that the hydrocarbons are unstable in contact with molten
iron
Prof. Mario Molina, a Nobel Prize winner, talks about his experience in making the harmful effects of chlorofluorocarbons (CFCs) known to scientists, the general public, manufacturers and politicians.
Height, frequency and spatial differentiation of atmospheric precipitation of the summer season for the period 1975-1982 are presented. Results of the respective investigations are compared with atmospheric precipitation in other areas of the western coast of Spitsbergen.
The article presents a review of the researches on sea and atmospheric physics conducted by the Polish expeditions in Antarctica from 1977 to 1990.
Weather forecasting requires knowledge of the laws of atmospheric movement. Apart from classic fluid mechanics, we must consider the rotational motion of our planet, the differential heating of its surface through the absorption of solar radiation, as well as water evaporation and condensation processes.
Meteorological and biometeorological conditions during the warm seasons (June– September) of 1979–2008 are described for the Hornsund area, Spitsbergen. The measure− ments were taken at four sites: at Hornsund, at the Hans Glacier (at its equilibrium line and in the firn section) and at the summit of Fugleberget. The variation of meteorological and biometeorological conditions was analysed in relation to altitude, distance from the sea and the ground type. In warm seasons, the air temperature at Hornsund was 2.2°C higher on aver− age than at the Hans Glacier (central section) and by 2.8°C than at the Hans Glacier (firn sec− tion) and at Fugleberget. The average wind speed recorded at Hornsund was higher (0.6ms−1) than at the Hans Glacier and lower (0.9ms−1) than at Fugleberget. Four biometeorological in− dices were used: wind chill index (WCI), predicted insulation of clothing (Iclp), cooling power (H) and subjective temperature index (STI). The strongest thermal stimuli were ob− served on the Hans Glacier and in the upper mountain areas. The study has found a consider− able degree of spatial variation between the meteorological elements investigated and the biometeorological indices in the Hornsund area. The impact of atmospheric circulation on meteorological elements and biometeorological indices is also presented. The mildest bio− meteorological conditions of the warm season found at Hornsund were associated with air masses arriving from the southwest and west.
The article presents the biometeorological impact of thermal and humidity conditions on the human body in the Hornsund area in the southern Spitsbergen, Svalbard. This was determined based on diurnal air temperature range, the day-to-day variation in average diurnal air temperature and the average diurnal relative humidity. The temporal variability of thermal and humidity biometeorological stimuli in Hornsund was examined for the period 01.11.1978–31.12.2017. A lessening of biometeorological impact was found in the southern Spitsbergen region, including a statistically significant negative trend in strongly- and severely-felt stimuli (according to diurnal air temperature range), and in significant and severe stimuli (according to day-to-day variation in average diurnal air temperature). A non-significant positive trend was observed in the number of days of relative humidity with humid and very humid air. To analyse the spatial variability of the stimuli around the Hornsund fjord, data were used from seven year-round measuring stations for the period 01.07.2014–31.06.2015. The most unfavourable conditions were found on the Hans Glacier, on the summit of Fugleberget and inside the fjord. The paper presents the role of atmospheric circulation on thermal and humidity stimuli. In the Hornsund region, the highest probability of unfavourable sensible temperatures for humans occurring during the year was mostly in winter and early spring. This was related to the advection of air masses from the north-east sector, regardless of baric regime type. It was found that very humid air (> 85%) flowed over Hornsund for practically the entire year from the S–SW as part of both cyclonic and anti-cyclonic systems.
Certain chemical parameters such pH, specific electric conductivity (SpC) and concentrations of chloride ions (Cl-) have been analysed in samples of precipitation collected close to the Polish Polar Station at Hornsund (PPS), SW Spitsbergen. On the basis of seasonal data from years 1993-1994 and 1998-1999, some differences are apparent from the two sets. There is also a marked difference in the seasonal results, especially with respects to pH values; summer precipitation (pH of which can be as low as 3.78) is much more acidic than winter. This was particularly notable in respect of the summer of 1993, and was presumably the result of a relatively unusual atmospheric circulation and a high influx of airborne contaminants from Europe. The wide variation in specific electrical conductivity measurements is considered to be related to variations in wind direction and speed. That precipitation the highest total dissolved salts, of 11.7 mm w.e. (water equivalent), (November 1993), provided 10.7 g of salt per square metre of tundra near the Polish Polar Station. The proximity of the sea, consequently the development of marine aerosols, largely determines the chemical nature of the precipitation. Thus, variations in the chloride ion concentrations during the study periods more or less reflect the variations in the marine aerosol influences on the nature of the polluted precipitation. An analysis of the atmospheric circulation reveals that the most acid precipitation occurs most frequently in the C-8 type of circulation (cyclonic S + SW) and also, less so, for type C-3 (anticyclonic S + SW).
The contribution of mercury and iodine in the particles of atmospheric aerosol and in the surface film of marine waters were estimated in the region of Admiralty Bay, King George Island, South Shetlands. Aerosols were collected with microscopic copper grids and on fibrous filters of microsorban type, and surface film with glassy slides. The obtained data are significant as natural background data.