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Abstract

The problem of governments’ over-indebtedness is one of the most important challenges for today’s EMU governance. As numbers suggest, the problem of extensive deficits has appeared in the EMU long before the burst of the global financial crisis. We suspect that the membership in a currency area might be partially blamed for such progression of indebtedness. This paper examines the determinants of government risk premiums in the EU Member States to answer if the risk premium assigned by the market may give currency area Member States additional incentives for profligacy. Controlling other factors, we investigate the pattern in which fiscal deficits and GDP growth affect the yield of 10-year-maturity government bonds in the euro area and the non-euro area EU Member States. Our results are straightforward. The market penalizes EU countries that do not belong to the euro area for bad economic performance and extensive deficits from 4 to 7 times stronger. Our estimates confirm the strong impact of the common credibility problem in the EMU but also support the key role of financial stress in determining the cost of government debt.

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Authors and Affiliations

Grzegorz Poniatowski
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Abstract

This paper presents research results of composite tubes filled with self-compacting concrete. The impact of the selected materials and geometric factors on resistance to the vertical shear was evaluated in this study. The resistance of the tested members was compared with recommendations given in Eurocode PN-EN 1994-1-1. From the results obtained in the tests it can be deduced that more parameters should be taken into consideration when determining resistance to the vertical shear in the interface between steel and concrete than PN-EN 1994-1-1 recommends.

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Authors and Affiliations

M. Szadkowska
E. Szmigiera
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Abstract

The recent financial crisis has seen huge swings in corporate bond spreads. It is analyzed what quality VAR-based forecasts would have had prior and during the crisis period. Given that forecasts of the mean of interest rates or financial market prices are subject to large uncertainty independent of the class of models used, major emphasis is put on the quality of measures of forecast uncertainty. The VAR considered is based on a model first suggested in the literature in 2005. In a rolling window analysis, both the model’s forecasts and joint prediction bands are calculated making use of recently proposed methods. Besides a traditional analysis of the forecast quality, the performance of the proposed prediction bands is assessed. It is shown that the actual coverage of joint prediction bands is superior to the coverage of naïve prediction bands constructed pointwise.

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Authors and Affiliations

Anna Staszewska-Bystrova
Peter Winker
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Abstract

Different methods are used for production of bronze bearings. In terms of technical specifications, the success of each of these methods

depends on the bond’s strength and in terms of economic, the production method is important. In this study, the aim is to study the strength

and microstructure of steel-bronze thrust bearing bond that has been produced through the casting using pre-mold. In this study, in order to

bond, the raw metals are chemically washed with sulfuric acid solution for five minutes at first. Then, the molten bronze SAE660 is cast in

a structural steel S235JR pre-mold. The bond’s strength has been measured using the shear test three times; the measurement of bond’s

length has been done using field emission scanning electron microscope (FESEM). The results indicate that the strength of the bond is at

least 94.8 MPa and bond’s length is 0.45 micrometers. Therefore, this method was successful for trust bearing application.

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Authors and Affiliations

M. Zaheri
S.E. Vahdat
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Abstract

The advancing degradation of the ecosystem and the occurring climate changes demand decisive action to be taken by citizens, aimed at levelling the results of the lack of balance between the natural environment and business operations. The growing importance of ecology is reflected on the international financial market in the form of green bonds. This article is devoted to green bonds which are a specific group of securities, namely ecological debt instruments. Despite the green debt being one of the most recent segments of the capital market, its very dynamic expansion can be observed year by year. The article is aimed at identifying the conditions for the development of the global environmental bonds market, specifically the factors stimulating and inhibiting the process. The article is a review in character and the following research methods were used in order to achieve the desired objective: analysis of subject literature and data analysis from the green bonds market, a case study, a descriptive and an inductive method.

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Authors and Affiliations

Anna Laskowska
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Abstract

The aim of the paper is to investigate the shear failure mechanisms in T-shape, single span and simply supported beams exclusively reinforced with longitudinal glass fiber reinforced polymer (GFRP) bars. Usually the critical shear crack in RC beams without stirrups develops through the theoretical compression strut reducing the shear strength following the shear failure. The main parameter affecting the crack pattern and the shear strength of the beams is the shear slenderness. However, the test results presented in the paper indicated the new arching effect due to the bond losing between the GFRP flexural reinforcement and concrete. This failure mode revealed unexpected critical crack pattern and failure mode. The research of concrete beams flexurally reinforced with GFRP bars without stirrups indicated two failure modes: typical shear-compression and a new one leading by the bond losing between the ordinary reinforcement and concrete.

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Authors and Affiliations

M. Kaszubska
R. Kotynia
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Abstract

To improve the mechanical performance of BiTe-based thermoelectric modules, this study applies anti-diffusion layers that inhibit the generation of metal intercompounds and an electroless nickel/electrode palladium/mission gold (ENEPIG) plating layers to ensure a stable bonding interface. If a plated layer is formed only on BiTe-based thermoelectric, the diffusion of Cu in electrode substrates produces an intermetallic compound. Therefore, the ENEPIG process was applied on the Cu electrode substrate. The bonding strength highly increased from approximately 10.4 to 16.4 MPa when ENEPIG plating was conducted to the BiTe-based thermoelectric element. When ENEPIG plating was performed to both the BiTe-based thermoelectric element and the Cu electrode substrate, the bonding strength showed the highest value of approximately 17.6 MPa, suggesting that the ENEPIG process is effective in ensuring a highly reliable bonding interface of the BiTe-based thermoelectric module.
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Bibliography

[1] L.D. Hicks, Effect of quantum-well structures on the thermoelectric figure of merit, Phys. Rev. B 47, 12727-12731 (1993).
[2] H.J. Goldsmid, R.W. Douglas, The use of semiconductors in thermoelectric refrigeration, J. Appl. Phys. 5, 386 (1954).
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[5] F.D. Rosi, Thermoelectricity and thermoelectric power generation, Solid State Electron. 11, 833-868 (1968).
[6] R. Venkatasubramanian, E. Siivola, T. Colpitts, B. O’Quinn, Thinfilm thermoelectric devices with high room-temperature figures of merit, Nature 413, 597-602 (2001).
[7] R.C. Sharma, Y.A. Chang, The Se-Sn (selenium-tin) system, Bull. Alloy Phase Diagr. 7, 68-72 (1986).
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[9] L. Lo, A. Wu, Interfacial reactions between diffusion barriers and thermoelectric materials under current stressing, J. Electron. Mater. 41, 3325-3330 (2012).
[10] I . Kato, T. Kato, H. Terashima, H. Watanabe, H. Honma, Influences of electroless nickel film conditions on electroless Au/ Pd/Ni wire bondability, Trans. JIEP. 3, 78-85 (2010).
[11] S.H. Bae, J.Y. Choi, I. Son, Effect of electroless Ni-P plating on the bonding strength of PbTe thermoelectric module using silver alloy-based brazing, Mater. Sci. Forum 985, 16-22 (2020).
[12] S. Bae, S. Kim, S. Yi, I. Son, K. Kim, H. Chung, Effect of surface roughness and electroless Ni-P plating on the bonding strength of Bi-Te-based thermoelectric modules, Coatings 9, 213-221 (2019).
[13] Y.T. Choi, S.H. Bae, I. Son, H.S. Sohn, K.T. Kim, Y.W. Ju, fabrication of aluminum-based thermal radiation plate for thermoelectric module using aluminum anodic oxidization and copper electroplating, J Nanosci. Nanotechnol. 18, 6404-6409 (2018).
[14] J . Yoon, S.H. Bae, H.S. Sohn, I. Son, K. Park, S. Cho, K.T. Kim, Fabrication of a Bi2Te3-based thermoelectric module using tin electroplating and thermocompression bonding, J Nanosci. Nanotechnol. 19, 1738-1742 (2019).
[15] K.H. Kim, I. Seo, S,H. W. Kwon, J. K. Kim, J.W. Yoon, S. Yoo, Effects of Ni-P bath on the brittle fracture of Sn-Ag-Cu solder/ ENEPIG solder joint, J. Welding and Joining. 35, 97-202 (2017).
[16] J .H. Back, S. Yoo, D.G. Han, S.B. Jung, J.W. Yoon, Effect of thin ENEPIG plating thickness on interfacial reaction and brittle fracture rate of Sn-0.3Ag-0.5Cu solder joints, Weld. Join. 36, 52-60 (2018).
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Authors and Affiliations

Subin Kim
1
ORCID: ORCID
Sung Hwa Bae
2
ORCID: ORCID
Injoon Son
1
ORCID: ORCID

  1. Kyungpook National University, Department of Materials Science and Metallurgical Engineering, Daegu, Republic of Korea
  2. Kyushu University Graduate School of Engineering, Department of Materials Process Engineering, Fukuoka, Japan
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Abstract

The paper presents research results of bond tests in completely concrete encased steel Isection columns made of self-compacting concrete (SCC). The results of push-out tests obtained by elements made of SCC were compared with those elements, which were made of vibrated concrete. The influence of selected factors on resistance to the vertical shear was considered in this study. The analysis of research results shows that the resistance to the vertical shear between steel I-section and SCC concrete depends on distance between stirrups and concrete age. Shrinkage has important influence on interfacial bond forces. The test results were compared with a recommendations given in the Design code – Eurocode 4. This standard can be used only for composite elements made of lightweight and vibrated concrete. In the case of completely concrete encased I-section composite columns the shear resistance after 28 days and after concrete shrinkage was higher than design resistance strength given in the standard. This means that the design value of the shear strength given in the standard should be verified and checked, if it can be applied to elements made of SCC concrete. Further tests should be carried out to determine the value of shear resistance for such elements.
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Authors and Affiliations

Magdalena Szadkowska
1
ORCID: ORCID
Elżbieta Szmigiera
1
ORCID: ORCID

  1. Warsaw University of Technology, Faculty of Civil Engineering, Al. Armii Ludowej 16, 00-637 Warsaw, Poland
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Abstract

Background: Studies on the effect of root canal rinsing protocols on fiber post bonding to dentin are inconclusive. This study reports investigation of this topic. Objectives: to determine effects of irrigation protocol by means of a push-out test on the strength of adhesion between the post and dentin in an in vitro study.
Materials and Method: Thirty human single-rooted teeth were prepared using hand instruments and the step-back technique, filled with gutta-percha, sealed with AH Plus (Dentsply), and divided into three groups: A: rinsed with NaCl; B: rinsed with 2% chlorhexidine (CHX); C: not rinsed before cementa-tion of posts. The fiber posts were set using RelyX and Built-it. The tooth roots were sliced and the push- out test was performed. The area of contact between the post and dentin was calculated and the destroying force was established. The results were statistically analyzed.
Results: The mean adhesive strength was 10.69 MPa in group A, 16.33 MPa in group B, and 16.72 MPa in C. The adhesive strength in group B and C was statistically significantly higher than in group A (p = 0.0016, ANOVA).
Conclusion: Rinsing root canals with CHX seems to be the most effective method prior to setting a fiber post.
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Bibliography

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Authors and Affiliations

Bartosz Ciapała
1
Krzysztof Górowski
2
Wojciech I. Ryniewicz
2
Andrzej Gala
2
Jolanta E. Loster
2

  1. Department of Integrated Dentistry, Institute of Dentistry, Jagiellonian University Medical College, Kraków, Poland
  2. Department of Dental Prosthetics and Orthodontics, Institute of Dentistry, Jagiellonian University Medical College, Kraków, Poland
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Abstract

In the article the author analyses the impact of the Financial Crisis, especially the Greek fiscal one, on the sCDS prices in Europe. The aim of the article is to assess the ability of the sCDS premia to price the risk of countries before and during the Greek crisis. The author analyses sCDS premia of maturity 10 years together with the so called bond-spreads, i.e. the spreadsbetween the countries’ bond indexes and the risk free rate of the region (in our case it was the yield of German bonds of corresponding maturity – 10 years).The idea was to check whether there occurred any discrepancies in the risk valuation via the two measures, as a consequence of the Greek crisis. The data is taken daily and covers the period of 2008‒2012. Based upon the results obtained in the research we conclude that the Greek crisis indeed influenced the relationships between the two measures of risk, however the degree of the influence was different in different countries. The relationships between the two measures of risk were totally broken only in the case of Greece, while in the other countries the relationships either were not distorted or had been broken already at the beginning of the financial crisis (2008/2009). The Greek problems were indeed reflected in volatilities of all analysed instruments; however triggering the credit event affected only Greek bonds dynamics.

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Authors and Affiliations

Agata Kliber
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Abstract

The goal of the paper is to verify the direction of sovereign risk transmission between sovereign CDS and sovereign bond markets in the Central European economies: the Czech Republic, Hungary and Poland. We focus on the hectic crisis period of 2008-2013. On the one hand, the sCDS market is said to react faster to the news than the sovereign bonds market. On the other hand, the bond market is related more closely to the internal situation of the country than the sCDS one and thus can price the sovereign risk more accurate. Moreover, the relationships between the markets can change during crisis time. We find that in the case of most risky and most indebted economy in Hungary there was a feedback between sCDS and sovereign bonds risk. In the case of Poland sCDS market risk Granger caused the risk of sovereign bonds – if we exclude instantaneous causality from the analysis; when it is included, feedback occurred. Eventually, in the case of the Czech Republic the risk of sCDS market Granger caused risk of the bonds market.
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Authors and Affiliations

Barbara Będowska-Sójka
Agata Kliber
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Abstract

The Sn-Ag-Cu-based solder paste screen-printing method has primarily been used to fabricate Bi2Te3-based thermoelectric (TE) modules, as Sn-based solder alloys have a low melting temperature (approximately 220℃) and good wettability with Cu electrodes. However, this process may result in uneven solder thickness when the printing pressure is not constant. Therefore, we suggested a novel direct-bonding method between the Bi2Te3-based TE elements and the Cu electrode by electroplating a 100 µm Sn/ 1.3 µm Pd/ 3.5 µm Ni bonding layer onto the Bi2Te3-based TE elements. It was determined that there is a problem with the amount of precipitation and composition depending on the pH change, and that the results may vary depending on the composition of Pd. Thus, double plating layers were formed, Ni/Pd, which were widely commercialized. The Sn/Pd/Ni electroplating was highly reliable, resulting in a bonding strength of 8 MPa between the thermoelectric and Cu electrode components, while the Pd and Ni electroplated layer acted as a diffusion barrier between the Sn layer and the Bi2Te3 TE. This process of electroplating Sn/Pd/Ni onto the Bi2Te3 TE elements presents a novel method for the fabrication of TE modules without using the conventional Sn-alloy-paste screen-printing method.
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Bibliography

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Authors and Affiliations

Seok Jun Kang
1
ORCID: ORCID
Sung Hwa Bae
2
ORCID: ORCID
Injoon Son
1
ORCID: ORCID

  1. Kyungpook National University, Department of Materials Science and Metallurgical Engineering, Daegu, Republic of Korea
  2. Kyushu University, Graduate School of Engineering, Department of Materials Process Engineering, Fukuoka, Japan
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Abstract

In this paper examinations of high-temperature wetting tests of 3 systems of liquid alloy – cast iron in contact with ceramic materials: magnesia ceramics in combination with natural graphite were presented. After wettability testing, the microscopic observations of the morphology of the sample surface and the cross-section microstructure with the chemical composition in micro-areas were examined. One of the objective of this work was also to verify whether the graphite content would affect the wettability of the magnesia ceramics. The study of high-temperature wetting kinetics of the liquid alloy in contact with the ceramic material, by the "sessile drop" method with capillary purification (CP) procedure was conducted. Under the test conditions, at a temperature of 1450°C and time 15 minutes, all 3 experimental systems showed a non-wetting behaviour. The average contact angle for the system with cast iron drop on magnesia ceramics was 140°, on magnesia ceramics with 10 parts per weight of graphite was 137° and on magnesia ceramics with 30 parts per weight of graphite - 139°.
Microscopic observations revealed that in the case of the sample consisting of the cast iron drop on the substrate with magnesia ceramics, the formation of fine separations was not observed, unlike the systems with the substrate with magnesia ceramics and the addition of natural graphite. Numerous, fine droplets accumulate on the graphite flakes and consist mainly of Si as well as Fe and O. On the other hand, the rough MgO grains have a gray, matt surface, without fine separations. The conducted observations indicate the mechanical nature of the bonding - liquid metal penetrates into the pores of the rough ceramics of the substrate. However, in the case of systems of cast iron drop with magnesia ceramics and addition of graphite, probably the adhesive connection and the physical attraction of elements derived from cast iron drop with the flake graphite appeared as well.
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Authors and Affiliations

M. Hosadyna-Kondracka
1
ORCID: ORCID
R. Nowak
1
P. Turalska
1
G. Bruzda
1
Ł. Boroń
1
M. Wawrylak
1

  1. Łukasiewicz Research Network - Krakow Institute of Technology, Poland
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Abstract

Carbon nanotubes (CNTs) are a good reinforcement for metal matrix composite materials; they can significantly improve the mechanical, wear-resistant, and heat-resistant properties of the materials. Due to the differences in the atomic structure and surface energy between CNTs and aluminum-based materials, the bonding interface effect that occurs when nanoscale CNTs are added to the aluminum alloy system as a reinforcement becomes more pronounced, and the bonding interface is important for the material mechanical performance. Firstly, a comparative analysis of the interface connection methods of four CNT-reinforced aluminum matrix composites is provided, and the combination mechanisms of various interface connection methods are explained. Secondly, the influence of several factors, including the preparation method and process as well as the state of the material, on the material bonding interface during the composite preparation process is analyzed. Furthermore, it is explained how the state of the bonding interface can be optimized by adopting appropriate technical and technological means. Through the study of the interface of CNT-reinforced aluminum-based composite materials, the influence of the interface on the overall performance of the composite material is determined, which provides directions and ideas for the preparation of future high-performance CNT-reinforced aluminum-based composite materials.
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Authors and Affiliations

Rong Li
1
ORCID: ORCID
Zhilin Pan
1
ORCID: ORCID
Qi. Zeng
ORCID: ORCID
Xiaoli Ye
1

  1. School of Mechanical & Electrical Engineering Guizhou Normal University, Guyiang, Guizhou, China
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Abstract

WC-8Co cemented carbide was prepared by a high-temperature liquid phase sintering in argon at 5-200 Pa. Three microtextured grooves with a spacing of 500, 750, and 1000 μm were prepared on the surface of WC-8Co cemented carbide. TiAlCrSiN multi-element hard coating was deposited on the WC-8Co cemented carbide microtextured surface with multi-arc ion plating technology. The Vickers hardness and fracture toughness of coated and uncoated WC-8Co cemented carbide with or without a microtextured surface were investigated. The effect of different microtextured spacing on the interface bonding strength of the TiAlCrSiN coating was analyzed. The results show that with the reduction of the microtextured spacing, the Vickers hardness of the cemented carbide slightly decreases, and the fracture toughness slightly increases. The microtextured surface can improve the interface bonding strength between the coating and the substrate. The smaller the microtextured spacing, the larger the specific surface area and the higher the surface energy, so the interface bonding strength between the coating and the substrate increases.
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Authors and Affiliations

ManFeng Gong
1 2
GuangFa Liu
1 2
Meng Li
1 3
XiaoQun Xia
1
Lei Wang
1
ORCID: ORCID
JianFeng Wu
1 2
ShanHua Zhang
1 2
Fang Mei
1

  1. Lingnan Normal University, School of Mechatronics Engineering, Zhanjiang 524048, China
  2. Guangdong Ocean University, School of Mechanical Engineering, Zhanjiang 524088, China
  3. Northwestern Polytechnical University, School of Materials Science and Engineering, Xian 710072, China
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Abstract

The paper presents research program of bond between glass fiber reinforced polymer bars and concrete in reference to the steel bars. Bond between the reinforcement and concrete is a crucial parameter governing a behaviour of reinforced concrete members and transferring of the internal forces from concrete to the reinforcement. The use of FRP bars as an equivalent reinforcement to steel in concrete structures has increased in recent years. The FRP bars are very different from steel, mainly due to much lower elasticity modulus and their anisotropic structure. Good performance of FRP reinforced concrete requires sufficient interfacial bond between bars and concrete. However, there are no specific standards referring to the surface preparation of these bars, that leads to variable bond behaviour of the composite reinforcement to the concrete. The objective of the study was to investigate the influence of variable parameters on the bond behaviour to concrete. The experimental program consisted of eighteen beam bond specimens varying in: bar diameter (12 mm, 16 mm, 18 mm) and type of reinforcement (GFRP sand – coated and steel bars). Although the GFRP bars indicated good bond behaviour to concrete, the average bond strength was slightly lower than that of steel reinforcement of 16mm and 18 mm, while it was higher for the GFRP bars of 12 mm diameter.

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Authors and Affiliations

D. Szczech
R. Kotynia
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Abstract

Introduction: Dentin hypersensitivity is a painful clinical condition. The frequency of its occurrence varies from 8 to 57%, depending on tested group and different methods of investigations. Recommended desensitizing agents have different mechanism of action and effectiveness. We are still looking for solutions that will improve their effectiveness and simultaneously allow for wider use of e.g. as a base material, counteracting postoperative hypersensitivity, reducing marginal microleakage. The aim of the study was to assess the effect of a selected desensitizing agent occluding dentin tubules with calcium hydroxyapatite on marginal microleakage formation of a class V composite restorations subjected to thermocycles.

Materials and Methods: In study it was used 40 molars and premolars, which were alternately assigned into two groups. In both groups standardized cavities were prepared. In the study group (study group — SG) before application of bonding agent Teethmate Desensitizer (f. Kuraray, Noritake Dental Inc., Okayama, Japan) was used. In the control group (control group — CG) OptiBond All-in-one (f. Kerr, Bioggio, Switzerland) bonding agent was used and cavities were filled using composite material Gradia Direct (f. GC Europe N.V., Leuven, Belgium). After storage in saline, teeth were subjected to 600 thermo-cycles, passive dye penetration test was done, teeth were cut in the area of filling, according to its long axis. Under light microscope magnification value of microleakage was measured and marginal microleakage rate (M) was counted. The results of the tests were statistically analyzed using the package STATISTICA 12.0 (StatSoft, USA).

Results: The average value of M for the SG group was 0.46 (min 0.05, max 0.76, SD 0.226) and for CG was 0.22 (min 0, max 0.74, SD 0.235). The differences between M values were statistically significant (p = 0.0094).

Conclusion: A reduction in the number of retention sites for the bonding system, facilitates the formation of microleakage in the experimental conditions and reduces the degree of adhesion of the composite material to the hard tissues of the tooth.

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Authors and Affiliations

Elżbieta Zarzecka-Francica
Joanna Gołda
Olga Górnicka
Barbara Śliwowska
Przemysław Kustra
Małgorzata Pihut
Joanna Zarzecka
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Abstract

A cold roll bonding process is applied to fabricate an AA6061/AA5052/AA6061/AA5052 multi-layer sheet. Two AA6061 and two AA5052 sheets with 2mm thickness are stacked alternately to each other, and reduced to a thickness of 2 mm by multi-pass cold rolling. The roll bonded multi-layer sheet is then hardened by natural aging (T4) and artificial aging (T6) treatments. The as roll-bonded sheet shows a typical deformation structure that the grains are elongated to the rolling direction. However, after T4 and T6 aging treatments, it has a recrystallization structure consisting of the coarse equiaxed grains in both AA5052 and AA6061 sheets. The as rolled material shows a lamella structure in which AA5052 and AA6061 sheets are stacked alternately to each other, having higher hardness in AA5052 than in AA6061. However, T4 and T6 aging treated materials show a different lamella structure in which the hardness of the AA6061 layers is higher than that of the AA5052 layers. The strengths of the T4 and T6 age-treated specimens are found to increase by 1.3 and 1.5 times respectively, compared to that of the starting material.

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Authors and Affiliations

Seong-Hee Lee
ORCID: ORCID

Authors and Affiliations

Sang-Hyeon Jo
1
ORCID: ORCID
Seong-Hee Lee
1
ORCID: ORCID

  1. Mokpo National University, Advanced Materials Science and Engineering, Muan-gun , Jeonnam 58554, Korea
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Abstract

The paper presents the results of theoretical calculations in terms of the G4MP2 composite method for cyprodinil–α-cyclodextrin (C 0@α-CD) and cyprodinil–β-cyclodextrin (C 0@β-CD) systems. Studies also covered analogous systems consisting of the anion (C ) and the cation (C +) of cyprodinil. The geometries of the cyprodinil molecule and ions were optimized on the basis of the DFT theory, using hybrid (B3LYP, PBE0), pure (B97-D) and “meta” (M06-2X) GGA functionals for selected Pople basis sets [6-311++G(d,p), 6-311++G(2d,p), 6-311++G(2d,2p)] and Dunning basis set (aug-cc-pVDZ). The research results suggest that the affinity of “guest” molecules for “hosts” is relatively low. Theoretical studies of the “guest-host” systems allow to predict the properties of the designed preparations.
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Authors and Affiliations

Jakub T. Hołaj-Krzak
1
ORCID: ORCID

  1. Institute of Technology and Life Sciences – National Research Institute, Falenty, 3 Hrabska Avenue, 05-090 Raszyn, Poland
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Abstract

Thermal spraying methods are commonly used to regenerate damaged surface or change materials surface properties. One of the newest methods is cold spraying, where coating is deposited of material in the solid state. Therefore shape and size of the powder particles are very important parameters. The article presents the influence of copper powder morphology on mechanical properties of the coatings (adhesion, hardness, Young’s modulus) deposited with the Low Pressure Cold Spraying method on the AA1350 aluminium alloy substrate. The coatings were deposited using two commercially available copper powders with spherical and dendritic morphology and granulation of –40+10 µm. The bond strength of coatings was determined with the pull off method, the hardness with the Vickers method at load of 2.94 N, while the Young’s modulus through measurement of nanoindentation. Microstructure of the coatings was analysed using the light and scanning electron microscopy (SEM). Shape of the powder influences mechanical properties of the coating significantly. The coatings deposited with dendritic powder had low mechanical properties, hardness of the 81 HV0.3 order and adhesion of about 4 MPa. However changing powder morphology to spherical increased hardness of the coating to 180 HV0.3 and adhesion to 38.5 MPa.
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Authors and Affiliations

D. Grygier
1
ORCID: ORCID
M. Rutkowska-Gorczyca
1
ORCID: ORCID
M.G. Winnicki
2
ORCID: ORCID
T. Wojdat
2
ORCID: ORCID

  1. Wroclaw University of Science and Technology, Faculty of Mechanical Engineering, Department of Vehicle Engineering, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
  2. Wroclaw University of Science and Technology, Faculty of Mechanical Engineering, Department of Metal Forming, Welding and Metrology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
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Abstract

Ultrasound-promoted transient liquid phase bonding (U-TLP) is a high quality, high efficiency, and low-cost method for fast bonding of difficult-wetting materials in the atmospheric environment. In this paper, U-TLP was used to bond SiC particles reinforced aluminium-based metal matrix composite which particle volume fraction was 70%. The pure zinc foil was used as the intermediate layer. The effects of ultrasonic on microstructure evolution and mechanical properties of joints during the transient liquefaction stage were investigated. The mechanism of ultrasonic effects in the transient liquefaction stage of U-TLP was also inducted. The results showed that high volume fraction SiCp/Al MMCs were bonded well at low temperature in the air environment. Ultrasonic vibration can remove the oxide film on the surface of aluminum matrix composites, enhance the wettability of SiC particles with weld metal, promote atomic diffusion and homogenization of SiC particles, and improve the welding quality and efficiency. Reasonable increase of ultrasonic vibration time could effectively improve the joint strength.
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Authors and Affiliations

Changzhuang Zhou
1
ORCID: ORCID
Lin Ma
1 2
ORCID: ORCID
Chao Zhu
1
ORCID: ORCID
Qinghe Cui
1
ORCID: ORCID
Jindi Liang
1
ORCID: ORCID
Yujian Song
1
ORCID: ORCID

  1. Shenyang Aerospace University, School of Materials Science and Engineering, Shenyang 110136, China
  2. The University of Queensland, Australia
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Abstract

A paste containing Cu(II) formate rods was prepared, and characteristics of sinter bonding at 250°C under a pressure of 10 MPa were investigated to accomplish a high-speed die attachment for wide-bandgap power chips on Cu finish in air. Synthesis of the plate-type Cu formate particles from CuO was accomplished through a wet reaction for 180 min. Cu, formed in situ in the bondline by pyrolysis of the formate during heating for the attachment, was sufficiently active to lead high-speed sintering within a carbon dioxide-hydrogen atmosphere derived from the pyrolysis, and the oxide layer on the Cu finish was reduced by the hydrogen. As a result, sinter bonding for 10 min formed a robust bonding with a shear strength approaching 27 MPa.

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Authors and Affiliations

Kyeong Hwan Jo
Jong-Hyun Lee
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Abstract

The stainless steel/aluminum multilayer composites were prepared by one-step explosive welding using ammonium nitrate explosive with two different thicknesses. The microstructure and mechanical properties of the multilayer composites were examined. There is a thin metallurgical melting zone at each bonding interface, consisting mostly of iron and aluminum elements. However, the micro-crack appears in the second metallurgical bonding zone obtained using the explosive of 24 mm thickness. The micro-hardness values at the four bonding interfaces are higher than those of bulk 1060 aluminum and 304 stainless steel. The yield strength of the multilayer composites obtained in the two cases is higher than that of the original 304 stainless steel while the tensile strength is between those of the original 1060 aluminum and 304 stainless steel. Meanwhile, the tensile strength and yield strength of multilayer composites obtained by explosive welding with explosive of 20 mm thickness are relatively higher.
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Authors and Affiliations

Xiaoyan Hu
1
ORCID: ORCID
Yingbin Liu
1
ORCID: ORCID
Li Yang
2
ORCID: ORCID
Xiaochen Huang
3
ORCID: ORCID

  1. North University of China, School of Environment and Safety Engineering, Taiyuan 030051, China
  2. Military Products Research Institute, Shanxi Jiangyang Chemical Co., Ltd., Taiyuan 030051, China
  3. Capital Aerospace Machinery Corporation Limited, Beijing 100076, China

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