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Abstract

Diffusion multiple method was applied to investigate the alloying elements distribution and interface diffusion reactions in Co-Al-X system, in order to accelerate the alloy development. The diffusion regions of Co-Al-X system at 1173 K were investigated by scanning electron microscope (SEM) and nanoindentation. SEM images show that phases of Co-Al-Ni diffusion interface consisted of β-CoAl + γ Co, γ Co, γ + γ'-(Co, Ni)3Al and γ Ni, while Co-Al-Cr diffusion interface is shaped with δ + γ + β, γ and σ region. TiNiX diffusion layer with high Ni-content was formed in Co-Al-Ti diffusion interface. The diffusion layers during diffusion multiple play an important role in mechanical properties in these alloying systems. The γ + γ' diffusion layer in Co-Al-Ni diffusion interface presented the best comprehensive performance, while the highest hardness (17.48 GPa) was confirmed in Co-Al-Cr diffusion interface due to a large number of brittle phases. Darken method was applied to determine the interdiffusion coefficients of alloying elements in pseudo-binary phase, accordingly the diffusion capacities of alloying elements can be ordered as Al > Ni > Cr in Co-based alloys.
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Authors and Affiliations

Hang Shang
1 2
ORCID: ORCID
Qiuzhi Gao
1 2
ORCID: ORCID
Yujiao Jiang
1 2
ORCID: ORCID
Qingshuang Ma
1 2
ORCID: ORCID
Huijun Li
3
ORCID: ORCID
Hailian Zhang
4
ORCID: ORCID

  1. Northeastern University at Qinhuangdao, School of Resources and Materials, Qinhuangdao, 066004, China
  2. Northeastern University, Shenyang, School of Materials Science and Engineering, 110819, China
  3. Tianjin University, School of Materials Science & Engineering, Tianjin, 300354, China
  4. Daotian High Technology Co., Ltd., Qinhuangdao, 066004, China
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Abstract

The paper presents research on the influence of grain size of selected coals and their structural parameters on the diffusion coefficient and methane sorption isotherms. Two coals from Polish hard coal mines, differing in the coal rank, were tested. Sorption isotherms for methane were determined. An unconventional sequence of pressures 0→0.1→0→0.5→0→1.5 MPa was employed to assess the speed of achieving sorption equilibrium at different pressures. The studies of CH4 accumulation kinetics were performed on various grain classes of the tested coals. Both the sorption capacity of coal and the diffusion coefficient proved to be highly sensitive to the experimental methodology. Critical measurement parameters in terms of determining the diffusion coefficient concerning the assumptions of the Crank model were indicated. The influence of the equivalent radius of coal grain on the process kinetics was demonstrated. The stepwise pressure increase factor was examined in the context of minimising the impact of sorption isotherm non-linearity on the results. The importance of the width of the grain class of coals was determined to reduce their maceral inhomogeneities. These factors are the most common reason that makes it difficult to quantitatively compare diffusion coefficient values.
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Authors and Affiliations

Katarzyna Kozieł
1
ORCID: ORCID
Aleksandra Gajda
1
ORCID: ORCID
Marta Skiba
1
ORCID: ORCID
Norbert Skoczylas
2
ORCID: ORCID
Anna Pajdak
1
ORCID: ORCID

  1. Strata Mechanics Research Institute of the Polish Academy of Sciences, 27 Reymonta Str., 30-059 Kraków, Poland
  2. AGH University of Kraków, Facu lty of Geology, Geoph ysics and Environmental Protection,al. Mick iewicza 30, 30-059 Kraków, Poland
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Abstract

In this paper, a four-pole system matrix for evaluating acoustic performance (STL) is derived using a decoupled numerical method. During the optimization process, a simulated annealing (SA) method, which is a robust scheme utilized to search for the global optimum by imitating a physical annealing process, is used. Prior to dealing with a broadband noise, to recheck the SA method’s reliability, the STL’s maximization relative to a one-tone noise (400Hz) is performed. To assure the accuracy of muffler’s mathematical model, a theoretical analysis of one-diffuser muffler is also confirmed by an experimental data. Subsequently, the optimal results of three kinds of mufflers (muffler A: one diffuser; muffler B: two diffusers; muffler C: three diffusers) have also been compared. Results reveal that the acoustical performance of mufflers will increase when the number of diffusers installed at the muffler inlet increases
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Bibliography

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2. Chang Y.C., Yeh L.J., Chiu M.C. (2004), Numerical studies on constrained venting system with side inlet/outlet mufflers by GA optimization, Acta Acustica united with Acustica, 90(6): 1159–1169.
3. Chang Y.C., Yeh L.J., Chiu M.C. (2005a), Shape optimization on double-chamber mufflers using genetic algorithm, Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science, 219(1): 31–42, doi: 10.1243/095440605X8351.
4. Chang Y.C., Yeh L.J., Chiu M.C., Lai G.J. (2005b), Shape optimization on constrained singlelayer sound absorber by using GA method and mathematical gradient methods, Journal of Sound and Vibration, 1286(4–5): 941–961, doi: 10.1016/j.jsv.2004.10.039.
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8. Chiu M.C. (2010b), Optimal design of multi-chamber mufflers hybridized with perforated intruding inlets and resonated tube using simulated annealing, Journal of Vibration and Acoustics, 132(5): Article ID 054503, doi: 10.1115/1.4001514.
9. Chiu M.C. (2012), Noise elimination of a multi-tone broadband noise with hybrid Helmholtz mufflers using a simulated annealing method, Archives of Acoustics, 37(4): 489–498, doi: 10.2478/v10168-012-0061-0.
10. Chiu M.C. (2013), Numerical assessment for a broadband and tuned noise using hybrid mufflers and a simulated annealing method, Journal of Sound and Vibration, 332(12): 2923–2940, doi: 10.1016/j.jsv.2012.12.039.
11. Chiu M.C. (2014a), Acoustical treatment of multi-tone broadband noise with hybrid side-branched mufflers using a simulated annealing method, Journal of Low Frequency Noise Vibration and Active Control, 33(1): 79–112, doi: 10.1260/0263-0923.33.1.79.
12. Chiu M.C. (2014b), Optimal design on one-layer closefitting acoustical hoods using a simulated annealing method, Journal of Marine Science and Technology, 22(2): 211–217, doi: 10.6119/JMST-013-0503-1.
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23. Yeh L.J., Chang Y.C., Chiu M.C. (2006), Numerical studies on constrained venting system with reactive mufflers by GA optimization, International Journal for Numerical Methods in Engineering, 65(8): 1165–1185, doi: 10.1002/nme.1476.
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Authors and Affiliations

Min-Chie Chiu
1
Ho-Chih Cheng
2

  1. Department of Mechanical and Materials Engineering, Tatung University, Taiwan, R.O.C.
  2. Department of Intelligent Automation Engineering, Chung Chou University of Science and Technology, Taiwan, R.O.C.
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Abstract

The study addresses two groups of issues occurring in modeling and experimental studies of multicomponent nonisobaric diffusion in macroporous materials. The dynamics of such processes is described in terms of systems of nonlinear partial differential equations. A method of orthogonal collocation for resolving the equations is proposed and compared with the method of lines. The second group of problems presented involves numerical simulations of diffusion in aWicke–Kallenbach diffusion cell. Such an apparatus is used in experimental studies. Particular attention is paid to diffusion in a cell closed from both sides. This is an analogue of the Duncan–Toor experiment. The effect of the number of diffusing components and their initial concentrations on the dynamics of diffusion in binary and ternary solution was studied. Hitherto unknown dynamic properties of such processes were detected and discussed.
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Bibliography

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Arnošt D., Schneider P., 1995. Dynamic transport of multicomponent mixtures of gases in porous solids. Chem. Eng. J., 57, 91–99. DOI: 10.1016/0923-0467(94)02900-8.
Boron D., 2020. Izobaryczna metoda stacjonarna wyznaczania współczynników dyfuzji w materiałach porowatych. Przem. Chem., 99, 785–788. DOI: 10.15199/62.2020.5.21.
Boron D., Tabis B., 2020. Udział i znaczenie przepływu lepkiego w nieizobarycznej dyfuzji gazów przez materiały porowate. Przem. Chem., 99, 1717–1716. DOI: 10.15199/62.2020.12.4.
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Gear C.W., 1971. Numerical initial value problems in ordinary differential equations. Prentice-Hall, Englewood Cliffs, New Jersey.
Ho C.K., Webb S.W. (Eds.), 2006. Gas transport in porous media. Springer, Netherlands. DOI: 10.1007/1-4020-3962-X.
Krishna R., Wesseling J.A., 1997. The Maxwell–Stefan approach to mass transfer. Chem. Eng. Sci., 52, 861–911. DOI: 10.1016/S0009-2509(96)00458-7.
Mason E.A., Malinauskas A.P., 1983. Gas transport in porous media: The dusty gas model. Elsevier, Amsterdam.
Remick R.R., Geankoplis C.J., 1970. Numerical study of three-component gaseous diffusion equations in transition region between Knudsen and molecular diffusion. Ind. Eng. Chem. Fundam., 9, 206–210. DOI: 10.1021/i160034a003.
Remick R.R., Geankoplis C.J., 1974. Ternary diffusion of gases in capillaries in the transition region between Knudsen and molecular diffusion. Chem. Eng. Sci., 29, 1447–1455. DOI: 10.1016/0009-2509(74)80169-7.
Schiesser W.E., 1991. Numerical methods of lines integration of partial differential equations. Academic Press, San Diego.
Tabis B., Bizon K. 2020. Opracowanie metody linii do całkowania dynamiki dyfuzji wieloskładnikowej w materiałach makroporowatych. Prace Katedry Inzynierii Chemicznej i Procesowej Politechniki Krakowskiej.
Tabis B., Bizon K., 2018. Dyfuzyjny ruch masy. Dyfuzja w gazach doskonałych i płynach rzeczywistych. Wydawnictwa Politechniki Krakowskiej, Kraków.
Tabis B., Boron D., 2020. Application of the dusty gas model for determining structural parameters of porous media. Przem. Chem., 99, 888–891. DOI: 10.15199/62.2020.6.11.
Tuchlenski A., Uchytil P., Seidel-Morgenstern A., 1998. An experimental study of combined gas phase and surface diffusion in porous glass. J. Membr. Sci., 140, 165–184. DOI: 10.1016/S0376-7388(97)00270-6.
Veldsink J.W., Versteeg G.F., van SwaaijW.M.P., 1994. An experimental study of diffusion and convection of multicomponent gases through catalytic and non-catalytic membranes. J. Membr. Sci., 92, 275–291. DOI: 10.1016/0376-7388(94)00087-5.
Yang J., Cermáková J., Uchytil P., Hamel C., Seidel-Morgenstern A., 2005. Gas phase transport, adsorption and surface diffusion in a porous glass membrane. Catal. Today, 104, 344–351. DOI: 10.1016/j.cattod.2005.03.069.
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Authors and Affiliations

Katarzyna Bizon
1
ORCID: ORCID
Bolesław Tabiś
1

  1. Cracow University of Technology, Faculty of Chemical Engineering and Technology, ul. Warszawska 24, 31-155 Kraków, Poland
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Abstract

The author analyses onymic practices of Poznań–based craftsmen forming guilds. In the names of the inhabitants of Poznań, which stabilised until the end of the 18th century, she seeks traces of the so-called cognomens, i.e. secondary personal designations granted to apprentices who were becoming masters. The names resulted from community acts of creation, which were of ludic nature. Referring to German onymic practices and pointing to the so-called Schleifnamen, the author discusses specific codes of European middle-class culture. She focuses on the transfer of models and patterns to Polish urban communities.

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Authors and Affiliations

Irena Sarnowska-Giefing
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Abstract

The aim of the article is to analyse the spread and diffusion of socio-economic development in Poland in 2004-2016, while considering spatial aspects. Using the linear ordering method in the non-pattern version, a synthetic development measure for all municipalities in Poland was built based on a set of 77 features illustrating various socio-economic aspects, reduced to 25 features. For the measure constructed in this way, the convergence of the beta and sigma type has been examined, divided into 3 groups of municipalities (rural, urban and urban-rural), as well as in regional division. Using the methods of spatial econometrics, the occurrence of spatial effects was examined, in particular the attention was paid to the relationship between the processes of spreading development and spatial forms of diffusion of development. The analysis also allowed to determine the strength of local impacts of spatial connections between individual municipalities.

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Authors and Affiliations

Maciej Pietrzykowski
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Abstract

The main problem in the measurement of airborne sound insulation is the measurement of the sound power radiated by the barrier, in practice performed by measuring the sound pressure level and the acoustic absorption in the receiving room. Large variations of the sound pressure level in a reverberation room indicate the presence of dominating strong standing waves, so that it becomes necessary to install diffusing elements. In ISO 10140, the limits have been defined in which the reverberation time at frequencies at and above 100 Hz should be included. Sometimes, however, in the case of rooms with a large volume, obtaining the required parameters is difficult and sometimes even impossible. It should then be checked whether the measured sound insulation depends on the reverberation time.

The paper presents the results of sound insulation measurements at various reverberation time lengths in subsequent stages of diffusing elements installation in the receiving room. An analysis of diffusing materials amount and arrangement influence on the uniformity of the sound pressure level distribution and reverberation time in the room as well as the value of the measured sound insulation was carried out. Uncertainty of sound insulation measurement with partial uncertainties was adopted as a criterion supporting the assessment of the obtained results.

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Authors and Affiliations

Dominik Mleczko
Tadeusz Wszołek
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Abstract

Permanent grasslands – according to the Water Framework Directive – are typical water related ecosystems so they largely affect water quality, its cycling and balance and therefore deserve protection. They are an element of landscape structure (ecosystem function or service) commonly considered a factor stabilising environmental changes.

Most threats posed to waters in Poland originate from present cropland structure with its definite predominance of arable lands over grasslands. Agriculture should therefore focus on the improvement of land use structure in order to minimise environmental hazards and to guarantee at the same time optimum economic effects. This could be achieved by turning arable lands into grasslands (where justified e.g. on light soils) or at least by maintaining present grassland area (condition in negotiations with the EU) and management that would consider environmental protection.

Increasing the contribution of grasslands to cropland structure or at least maintaining their pre-sent status quo would help to achieve compromise between the goals of farmers and environmental protection. Purposeful utilisation of ecosystem services, particularly those of grasslands, allows to maintain more intensive farming without environmental hazard. Limited should be only such activi-ties whose intensity exceeds regenerative or buffering environmental capacity e.g. on grounds par-ticularly subjected to water pollution or those included into Natura 2000 network.

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Authors and Affiliations

Halina Jankowska-Huflejt
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Abstract

To obtain anti-corrosive thermo-diffusion zinc coatings, the authors use highly effective zinc saturating mixtures. This technology makes it possible to obtain coatings with a high zinc content in the δ-phase as well as a zinc-rich phase of FeZn13 (ζ-phase) on the coating surface. As a result of long-term studies into the corrosion properties of thermo-diffusion zinc (TDZ) coatings conducted by the authors, a number of features of their corrosive behavior have been established. The corrosion rate of those coatings in desalted and chloride-containing media is lower than those of galvanic or hot-dip zinc coatings. The corrosion behavior depends on the content of zinc on the surface and the texture features of the coating. The results showed that on the surface of thermo-diffusion coatings in the corrosion on media containing chloride ions, zinc hydroxychloride (simonkolleite – Zn5Cl2[OH]8[H2O]) has been formed. Compared to coatings obtained by other methods, the rate of simonkolleite formation was higher on TDZ coatings, which might have a positive effect on their resistance in aggressive atmospheres.

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Authors and Affiliations

A. Biryukov
R. Galin
D. Zakharyevich
A. Wassilkowska
A. Kolesnikov
T. Batmanova
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Abstract

The work motivation was to investigate in vitro system simulating drug release from Drug Eluting Stent (DES). The experiments were conducted in a custom designed unit simulating drug release from polymer covering DES in a simplified way. The active substance diffuses from a thin, internal annular layer of hydrogel (imitating “stent”) to the outer cylindrical layer of hydrogel (“artery wall”) and is at once drifted away by coaxially flowing solution (“blood”). The conducted research proved functionality of the experimental unit. The rate of mass transfer depends considerably on the mass driving force and on the affinity of substance-hydrogel. The volumetric flow rate and liquid viscosity did not affect the process significantly. The effective diffusion coefficient was calculated as a process parameter and then used in the other variants. Diffusion in hydrogel is the mechanism limiting the mass transfer in the examined system. For the first attempt, the diffusive model used in literature was employed. The provided calculations are consistent with experimental data and therefore show that despite its simplifications the model allows to estimate the amount of released substance.
In conclusion, the relative substance mass, changing over time, was estimated in the respective parts of the unit. The prospect of determining the relative mass of the substance appearing in the subsequent parts of the system over time provides the opportunity to adjust the respective process parameters, which will facilitate control over the rate of mass release.
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Authors and Affiliations

Anna Adach-Maciejewska
1
ORCID: ORCID
Klaudia Kopka
1

  1. Warsaw University of Technology, Faculty of Chemical and Process Engineering, Waryńskiego 1, 00-645 Warsaw, Poland
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Abstract

The reaction of ilmenite raw materials with sulfuric acid has been investigated to find out the influence of diffusion processes on the course of this reaction. Three different laboratory methods were used to initiate the reaction: mixing ilmenite with 83–85% sulfuric acid at a temperature of 80 °C, mixing ilmenite with 90% sulfuric acid at temperatures of 20–40 °C and adding water, and mixing ilmenite with water and adding 95% sulfuric acid. Changes of thermal power during the process (thermokinetics) were studied with the use of calorimetry. It was found that diffusion processes play an important role when the reaction is initiated by mixing ilmenite with water followed by the addition of sulfuric acid and are less important when the reaction is initiated by mixing ilmenite with concentrated sulfuric acid followed by the addition of water. To explain the influence of diffusion processes on the reaction, the model calculations based on mass and heat balance equations were involved. Model calculations showed that the diffusion and mass transport processes are so fast that the reaction kinetics is mainly influenced by the reaction on the surface of ilmenite particles. The adopted model of calculations showed a very good agreement with experimental results.
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Authors and Affiliations

Maciej Jabłoński
1
Krzysztof Lubkowski
1
ORCID: ORCID
Elwira Wróblewska
1
ORCID: ORCID

  1. West Pomeranian University of Technology Szczecin, Faculty of Chemical Technology and Engineering, Department of Organic and Physical Chemistry, Al. Piastów 42, 71-065 Szczecin, Poland
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Abstract

The mathematical approach to SOFC modelling helps to reduce dependence on the experimental approach. In the current study, six different diffusion mass transfer models were compared to more accurately predict the process behavior of fuel and product diffusion for SOFC anode. The prediction accuracy of the models was extensively studied over a range of parameters. New models were included as compared to previous studies. The Knudsen diffusion phenomenon was considered in all the models. The stoichiometric flux ratio approach was used. All the models were validated against experimental data for a binary (CO-CO2) and a ternary fuel system (H2-15 H2O-Ar). For ternary system, the pressure gradient is important for pore radius below 0.6 μm and current density above 0.5 A/cm2. For binary system, the pressure gradient may be ignored. The analysis indicates that the MBFM is identified to be the best performing and versatile model under critical SOFC operating conditions such as fuel composition and cell temperature. The diffusive slip phenomenon included in MBFM is useful in SOFC operating conditions when fuel contains heavy molecules. The DGMFM is a good approximation of DGM for the binary system.
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Authors and Affiliations

P. Ramakrishnan
1
ORCID: ORCID
Abanti Sahoo
1
ORCID: ORCID

  1. NIT Rourkela, Department of Chemical Engineering, Rourkela, Sector-1, Sundergarh, Odisha, India, 769008
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Abstract

In the paper critical role of including the right material parameters, as input values for computer modelling, is stressed. The presented model of diffusion, based on chemical potential gradient, in order to perform calculations, requires a parameter called mobility, which can be calculated using the diffusion coefficient. When analysing the diffusion problem, it is a common practice to assume the diffusion coefficient to be a constant within the range of temperature and chemical composition considered. By doing so the calculations are considerably simplified at the cost of the accuracy of the results. In order to make a reasoned decision, whether this simplification is desirable for particular systems and conditions, its impact on the accuracy of calculations needs to be assessed. The paper presents such evaluation by comparing results of modelling with a constant value of diffusion coefficient to results where the dependency of Di on temperature, chemical composition or both are added. The results show how a given deviation of diffusivity is correlated with the change in the final results. Simulations were performed in a single dimension for the FCC phase in Fe-C, Fe-Si and Fe-Mn systems. Different initial compositions and temperature profiles were used.
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Bibliography

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[3] Wróbel, M., & Burbelko, A. (2022). A diffusion model of binary systems controlled by chemical potential gradient. Journal of Casting & Materials Engineering. 6(2), 39-44. DOI: 10.7494/jcme.2022.6.2.39.
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[6] Bergethon, P.R. & Simons, E.R. (1990). Biophysical Chemistry: Molecules to Membranes. New York: Springer-Verlag. DOl: 10.1007/978-1-4612-3270-4
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Authors and Affiliations

M. Wróbel
1
ORCID: ORCID
A. Burbelko
1
ORCID: ORCID

  1. AGH University of Science and Technology, Faculty of Foundry Engineering, al. A. Mickiewicza 30, 30-059 Krakow, Poland
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Abstract

By means of small wind turbines, it is possible to create distributed sources of electricity useful in areas with good wind conditions. Sometimes, however, it is possible to use small wind turbines also in areas characterized by lower average wind speeds during the year. At the small wind turbine design stage, various types of technical solutions to increase the speed of the wind stream, as well as to optimally orientate it, can be applied. The methods for increasing the efficiency of wind energy conversion into electricity in the case of a wind turbine include: the use of a diffuser shielding the turbine rotor and the optimization of blades mounted on the turbine rotor. In the paper, the influence of the diffuser and rotor blades geometry on the efficiency of an exemplary wind turbine for exploitation in the West Pomeranian Province is investigated. The analyses are performed for three types of the diffuser and for three types of rotor blades. Based on them, the most optimal shapes of the diffuser and blades are selected due to the efficiency of the wind turbine. For the turbine with the designed diffuser, calculations of the output power for the assumed different values of the average annual wind speed and the constant Betz power factor and the specified generator efficiency are made. In all the analyzed cases, the amount of energy that can be generated by the turbine during the year is also estimated. Important practical conclusions are formulated on the basis of these calculations. In the final part of the paper, a 3D model of the wind turbine with the diffuser and rotor blades chosen based on earlier analyses is presented. As a material for the diffuser and rotor blades, glass fiber type A is applied. By means of calculations using the finite element method, the limit displacement of the turbine structure under the influence of a hurricane wind are determined. Based on these calculations, the correctness of the modelled small wind turbine structure has been demonstrated.

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Authors and Affiliations

Kamil Krzysztof Skorupa
Rafał Grzejda
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Abstract

The purpose of this paper is to introduce a new chaotic oscillator. Although different chaotic systems have been formulated by earlier researchers, only a few chaotic systems exhibit chaotic behaviour. In this work, a new chaotic system with chaotic attractor is introduced. It is worth noting that this striking phenomenon rarely occurs in respect of chaotic systems. The system proposed in this paper has been realized with numerical simulation. The results emanating from the numerical simulation indicate the feasibility of the proposed chaotic system. More over, chaos control, stability, diffusion and synchronization of such a system have been dealt with.
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Authors and Affiliations

Suresh Rasappan
1
K.A. Niranjan Kumar
1

  1. Department of Mathematics, Vel Tech Rangarajan Dr.Sagunthala R&D Institute of Science and Technology, Avadi, Chennai-62, India
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Abstract

The safety of mining operations in hard coal mines must be constantly developed and improved. There is ongoing multi-directional research focused at best recognition of the phenomenon associated with the properties of the coal-gas system and its connections with mining and geological conditions. This article presents the results of sorption experiments on coals from the Upper Silesian Coal Basin, which are characterized by varying degrees of coalification. One of the parameters that describes the kinetics of methane sorption, determining and providing valuable information about gas hazard and in particular the risk of gas and rock outbursts, is the effective diffusion coefficient De. It is derived from the solution of Fick’s second law using many simplifying assumptions. Among them is the assumption that the carbon matrix consists of only one type of pore – micropores. In fact, there are quite often at least two different mechanisms, which are connected to each other, related to the diffusion of methane from the microporous matrix and flows occurring in voids and macropores. This article presents both the unipore and bidisperse models and a set of comparisons which fit them to experimental curves for selected coals. For some samples the more complex bidisperse model gave much better results than the classic unipore one. The supremacy of the bidisperse model could be associated with the differences in the coal structure related to the coalification degree. Initial results justify further analyses on a wider set of coals using the methodology developed in this paper.

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Authors and Affiliations

Marcin Karbownik
Jerzy Krawczyk
ORCID: ORCID
Tomasz Schlieter
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Abstract

This paper concerns analytical considerations on a complex phenomenon which is diffusive-inertial droplet separation from the twophase vapour-liquid flow which occurs in many devices in the power industry (e.g. heat pumps, steam turbines, organic Rankine cycles, etc.). The new mathematical model is mostly devoted to the analysis of the mechanisms of diffusion and inertia influencing the distance at which a droplet separates from the two-phase flow and falls on a channel wall. The analytical model was validated based on experimental data. The results obtained through the analytical computations stay in a satisfactory agreement with available literature data.
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Authors and Affiliations

Jarosław Mikielewicz
1
Oktawia Dolna
1
Roman Kwidziński
1

  1. Institute of Fluid Flow Machinery, Polish Academy of Sciences, Fiszera 14, 80-231 Gdansk, Poland
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Abstract

The presence of more than one solute diffused in fluid mixtures is very often requested for discussing the natural phenomena such as transportation of contaminants, underground water, acid rain and so on. In the paper, the effect of nonlinear thermal radiation on triple diffusive convective boundary layer flow of Casson nanofluid along a horizontal plate is theoretically investigated. Similarity transformations are utilized to reduce the governing partial differential equations into a set of nonlinear ordinary differential equations. The reduced equations are numerically solved using Runge-Kutta-Fehlberg fourth-fifth order method along with shooting technique. The impact of several existing physical parameters on velocity, temperature, solutal and nanofluid concentration profiles are analyzed through graphs and tables in detail. It is found that, modified Dufour parameter and Dufour solutal Lewis number enhances the temperature and solutal concentration profiles respectively.

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Authors and Affiliations

Manjappa Archana
Bijjanal Jayanna Gireesha
Ballajja Chandrappa Prasannakumara
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Abstract

One of the most effective designs to control the road traffic noise is the T-shaped barrier. The aim of this study was to examine the performance of T-shape noise barriers covered with oblique diffusers using boundary element method. A 2D simulation technique based on the boundary element method (BEM) was used to compute the insertion loss at the center frequency of each one-third octave band. In designed barriers, the top surface of the T-shaped noise barriers was covered with oblique diffusers. The width and height of the barrier stem and the width of its cap were 0.3, 2.7, and 1 m, respectively. Angles of he oblique diffusers were 15, 30, and 45 degrees. The oblique diffusers were placed on the top surface with two designs including same oblique diffusers (SOD) and quadratic residue oblique diffusers (QROD). Barriers considered were made of concrete, an acoustically rigid material. The barrier with characteristics of QROD, forward direction, and sequence of angles (15, 30, and 45 degrees) had the greatest value of the overall A-weighted insertion loss equal to 18.3 to 21.8 dBA at a distance of 20 m with various heights of 0 to 6 m.

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Authors and Affiliations

Mohammad Reza Monazzam
Milad Abbasi
Saeid Yazdanirad
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Abstract

The article presents research data on the amount of salts in the irrigated soils of the Mughan-Salyan massif, their composition, water-salt regime, and their forecast. It was found that the soils on the territory of the massif were saline to varying degrees. In general, the area of non-saline soils in the massif is 125,650 ha, mildly – 272,070 ha, moderately – 210,560 ha, highly – 125,850 ha, very highly – 109,450 ha and saline soils – 27,520 ha. The absorbed bases in the soils of the massif were studied, and it was determined that they change depending on the amount of salts as follows: in mildly saline soils, Ca – 57.82–68.31%, Mg – 25.26–36.28%, Na – 5.49–6.43%; in moderately saline soils – 56.77–65.76%, 27.03–35.58%, 7.12–7.94%, respectively; in highly saline areas – 54.05–64.75%, 24.94–43.67% and 9.19– 14.42%. As you can see, the soils are mildly and moderately saline.
The soils in the surveyed areas are saline to varying degrees (i.e., the average value of salts in the 0–100 cm layer of the soil varies between 0.25 and 1.00%). The biological product used in these soils contains a wide range of macro and microelements, humic acids, fulvic acids, amino acids, vitamins and enzymes that do not contain BioEcoGum mineral fertilisers. This biological product was used for the first time and one of the main goals was to study the improvement of water-physical properties of soils after its use. Therefore, the water-salt regime of the soils of the study area was studied on three experimental sites selected for the area, the number of irrigations for different plants, and their norms were determined taking into account the depth of groundwater in the soils and shown in tabular form. They are widely used in farms and these regions, taking into account the proposed irrigation norms and their quantity.
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Authors and Affiliations

Mustafa Mustafayev
1
ORCID: ORCID
Zulfiya Tukenova
2
ORCID: ORCID
Mereke Alimzhanova
3
ORCID: ORCID
Kazhybek Ashimuly
4
ORCID: ORCID
Farid Mustafayev
1
ORCID: ORCID

  1. Institute of Soil Science and Agrochemistry of Azerbaijan National Academy of Science, M. Rahim St, 5, AZ10073, Baku, Azerbaijan Republic
  2. Al-Farabi Kazakh National University, Faculty of Geography and Environmental Sciences, Department of UNESCO in Sustainable Development, Almaty, Republic of Kazakhstan
  3. Al-Farabi Kazakh National University, Faculty of Thermal Physics and Technical Physics, Department of Physics and Technology, Almaty, Republic of Kazakhstan
  4. Scientific Production Center of Microbiology and Virology, Almaty, Republic of Kazakhstan
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Abstract

In the paper, differential quadrature method (DQM) is used to find numerical solutions of reaction-diffusion equations with different boundary conditions. The DQM-method changes the reaction- diffusion equation (ordinary differential equation) into a system of algebraic equations. The obtained system is solved using built-in procedures of Maple®(Computer Algebra System-type program). Calculations were performed with Maple®program. The test problems include reaction-diffusion equation applied in heterogeneous catalysis. The method can be employed even in relatively hard tasks (e.g. ill-conditioned, free boundary problems).

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Authors and Affiliations

Mirosław K. Szukiewicz
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Abstract

Acquiring labels in anomaly detection tasks is expensive and challenging. Therefore, as an effective way to improve efficiency, pretraining is widely used in anomaly detection models, which enriches the model's representation capabilities, thereby enhancing both performance and efficiency in anomaly detection. In most pretraining methods, the decoder is typically randomly initialized. Drawing inspiration from the diffusion model, this paper proposed to use denoising as a task to pretrain the decoder in anomaly detection, which is trained to reconstruct the original noise-free input. Denoising requires the model to learn the structure, patterns, and related features of the data, particularly when training samples are limited. This paper explored two approaches on anomaly detection: simultaneous denoising pretraining for encoder and decoder, denoising pretraining for only decoder. Experimental results demonstrate the effectiveness of this method on improving model’s performance. Particularly, when the number of samples is limited, the improvement is more pronounced.
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Authors and Affiliations

Xianlei Ge
1 2
Xiaoyan Li
3
Zhipeng Zhang
1

  1. School of Electronic Engineering, Huainan Normal University, China
  2. College of Computing and Information Technologies, National University, Philippines
  3. School of Computer, Huainan Normal University, China
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Abstract

The present research investigates the nitriding kinetics of the near-beta-titanium alloy of Ti-Al-Nb-Fe-Zr-Mo-V system at 750, 800, and 850°C in gaseous nitrogen at 10 5 Pa for 2, 4, and 8 h. The parabolic coefficient kp of the layer’s growth rate and the nitriding activation energy E are set as the kinetic parameters of the nitrided layer’s growth. The activation energy for the formation of a nitride layer is ~108 kJ/mol. The authors discuss the morphology of the nitride layers as well as their roughness and surface hardness. The study determines the effective diffusion coefficient for the growth of diffusion layers in the temperature range of 750...850°C: Def = D0 × exp (– E/RT), where D0 = 0.0177 m 2/s; E = 215.7 kJ/mol. The friction coefficient of the disk from near-beta-titanium alloy with a bronze block is lowered by significantly more than 10 times after gas nitriding, and the temperature in the friction zone is reduced by 2.5 times.
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Authors and Affiliations

A.G. Luk’yanenko
1
ORCID: ORCID
I.M. Pohrelyuk
1
ORCID: ORCID
V.M. Fedirko
1
ORCID: ORCID
A.G. Molyar
2
V.S. Trush
1
ORCID: ORCID
T.M. Kravchyshyn
1

  1. G.V. Karpenko Physico-Mechanics Institute of the NAS of Ukraine, Department of Material Science Bases of Surface Engineering, 5, Naukova Str., 79060 Lviv, Ukraine
  2. G.V. Kurdyumov Institute for Metal Physics of the NAS of Ukraine, Department of Physics of Strength and Ductility of Inhomogeneous Alloys,36 Academician Vernadsky Boulevard, 03142 Kyiv, Ukraine

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