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Abstract

The results of mechanical reclamation of waste moulding sands with furfuryl resin and activators of new generation are presented.

The aim of the research described in this study was to determine what effect the addition of reclaim obtained in the process of dry mechanical reclamation could have on the properties of furan sands.

The sand supplied by one of the domestic foundries was after the initial reclamation subjected to a two-step proper reclamation

process. The following tests were carried out on the obtained reclaim: pH, S and N content, loss on ignition and comprehensive

sieve analysis. The obtained reclaim was next used as a component of moulding sands with furfuryl resin, wherein it formed 50%

and 80% of the base moulding material, respectively. The strength properties of the ready sand mixtures (bending strength Rg u and tensile strength Rm u ) were determined after the hardening time of 0.5, 1, 2, 4 and 24 hours.

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Authors and Affiliations

J. Kamińska
E. Basińska
M. Angrecki
A. Palma
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Abstract

The aim of the study was to determine the influence of the amount of a commonly used binder in foundry work, furfuryl resin – on the course of the thermal regeneration of used moulding sand. The thermal regeneration procedure was carried out at a temperature of 525°C, the required temperature determined according to a specific procedure, and a lower and less effective temperature of 400°C. On the basis of the ignition losses, the influence of the regeneration temperature on the effects of the procedures carried out was compared. It was found that 400°C was too low to effectively clean the binder matrix, but that the more resin in the spent sand, the more intense the cleaning effect. When the required regeneration temperature for furfuryl resin of 523°C was used, higher binder degradation kinetics were observed due to the additional energy supplied to the process from the combustion of a large amount of organic material in the moulding sand.
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Authors and Affiliations

Mariusz Łucarz
1
ORCID: ORCID
Marcini Brzezińsk
1

  1. AGH University of Krakow , Faculty of Fo undry Engineering, Al. Mickiewicza 30, 30-059 Krakow , Poland
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Abstract

Growing emission requirements are forcing the foundry industry to seek new, more environmentally friendly solutions. One of the

solutions may be the technologies of preparing moulding and core sands using organic biodegradable materials

as binders. However, not only environmental requirements grow but also those related to the technological properties

of moulding sand. Advancing automation and mechanization of the foundry industry brings new challenges related to the moulding sands.

Low elasticity may cause defects during assembly of cores or moulds by the manipulators.

The paper presents the study of flexibility in the room temperature according to new method and resistance to thermal deformation of selfhardening

moulding sands with furfuryl resin, containing biodegradable material PCL. The task of the new additive is to reduce the

moulding sands harmfulness to the environment and increase its flexibility in the room temperature. The impact of the additive and the

effect of the amount of binder on the properties of mentioned moulding sands were analysed. Studies have shown that the use of 5% of

PCL does not change the nature of the thermal deformation curve, improves the bending strength of tested moulding mixtures and

increases their flexibility at room temperature.

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Authors and Affiliations

A. Grabarczyk
K. Major-Gabryś
St.M. Dobosz
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Abstract

The paper presents the impact of biodegradable material - polycaprolactone (PCL) on selected properties of moulding sands. A self-hardening moulding sands with phenol-furfuryl resin, which is widely used in foundry practice, and an environmentally friendly self-hardening moulding sand with hydrated sodium silicate where chosen for testing. The purpose of the new additive in the case of synthetic resin moulding sands is to reduce their harmfulness to the environment and to increase their “elasticity” at ambient temperature. In the case of moulding sands with environmentally friendly hydrated sodium silicate binder, the task of the new additive is to increase the elasticity of the tested samples while preserving their ecological character. Studies have shown that the use of 5% PCL in moulding sand increases their flexibility at ambient temperature, both with organic and inorganic binders. The influence of the new additive on the deformation of the moulding sands at elevated temperatures has also been demonstrated.
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Authors and Affiliations

A. Grabarczyk
S.M. Dobosz
K. Major-Gabryś
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Abstract

The aim of the research was to determine the effect of the primary quality of reclaim from dry mechanical reclamation on the strength properties and service life of moulding sands based on this reclaim. Another aim was to establish the effect of the quality of reclaim, sulphur content - in particular, on the surface quality and thickness of the deformed surface layer in ductile iron castings. The research has revealed differences in the strength parameters and service life (mouldability) of sands based on the tested reclaims, depending on the type of the furfuryl resin used, including resins whose synthesis was done as part of the Żywfur project. Examinations of the structure of the surface layer of test castings poured in moulds made of loose self-hardening sands containing the addition of reclaim have confirmed the occurrence of degenerated spheroidal graphite in this part of the casting. It should be noted here that when massive castings with a long solidification time are made, the graphite degeneration effect can be more visible and the layer with the changed structure can increase in thickness. The research has clearly shown that it is necessary to control the parameters of the reclaim, including sulphur content which is transferred from the hardener and accumulates on the grains. This phenomenon has a negative impact not only on the sand strength and technological properties but also on the surface layer of castings.
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Bibliography

[1] Lewandowski, J.L. (1997). Materials for foundry moulds. Kraków: WN Akapit. ISBN: 83-7108-21-2 (in Polish).
[2] Kamińska, J., Puzio, S., Angrecki, M., Stachowicz, M. & Łoś, A. (2019). Preliminary tests of innovative eco-friendly furfuryl resins and foundry sand mixtures based on these resins. Journal of Ecological Engineering. 20(9), 285-292, DOI: 10.12911/22998993/112510.
[3] Acharya, S.G., Vadher, J.A. & Kanjariya, P.V. (2016). Identification and quantification of gases releasing from furan no bake binder. Archives of Foundry Engineering. 16(3), 5-10. DOI: 10.1515/afe-2016-0039.
[4] Chate, G.R., Patel, GC M., Deshpande, A.S. & Parappagoudar, M.B. (2018). Modeling and optimization of furan moulding sand system using design of experiments and particle swarm optimization. Journal of Process Mechanical Engineering. 232(5), 1-20. DOI: 10.1177/0954408917728636.
[5] Sappinen, T., Orkas, J. & Konqvist, T. (2018). Thermal Reclamation of Foundry Sands Using Repurposed Sand Dryer Equipment. Archives of Foundry Engineering. 18(4), 99-102. DOI: 10.24425/afe.2018.125176.
[6] Kamińska, J., Puzio, S., Angrecki, M. & Łoś, A. (2020). Effect of reclaim addition on the mechanical and technological properties of moulding sands based on pro-ecological furfuryl resin. Archives of Metallurgy and Materials. 65(4), 1425-1429. DOI: 10.24425/amm.2020.133709.
[7] Yan-lei, L., Guo-hua, W., Wen-cai, L., An-tao, C., Liang, Z. & Ying-xin Wang, W. (2017). Effect of reclaimed sand additions on mechanical properties and fracture behavior of furan no-bake resin sand. China Foundry. 14(2), 128-137. DOI: 10.1007/s41230-017-6024-3.
[8] Holtzer, M., Dańko, R., Kmita, A., Drożyński, D., Kubecki, M., Skrzyński, M. & Roczniak, A. (2020). Environmental impact of the reclaimed sand addition to moulding sand with furan and phenol-formaldehyde resin—A comparison, Materials. 13(19), 4395; DOI: https://doi.org/10.3390/ma13194395.
[9] Holtzer, M., Dańko, R. & Kmita, A. (2016). Influence of a reclaimed sand addition to moulding sand with furan resin on its impact on the environment. Water Air and Soil Pollution. 227(16), 1-12. DOI: 10.1007/s11270-015-2707-9.
[10] Hosadyna, M. (2012). The effect of sulphur contained in self-hardening moulding sands on the structure of surface layer in ductile iron castings. Doctoral dissertation, Kraków. (in Polish).
[11] Holtzer, M., Zych, J. & Retel, K. (1996). The effect of mould-liquid cast iron interaction on the surface quality of castings. Przegląd Odlewnictwa. 6(1996), 129-134. (in Polish).
[12] Riposan, I., Chisamera, M., Stan, S., Skaland, T. (2008). Surface graphite degeneration in ductile iron castings for resin molds. Tsinghua Science and Technology. 13(2), 157-163.
[13] Linke, T., Sluis, J.R. (1993). The influence of coatings on the graphite structure in the rim-zone of ductile iron castings. 60th World Foundry Congress, The Netherlands
[14] Hosadyna, M., Dobosz, St.M. & Jelinek, P. (2009). The diffusion of sulphur from moulding sand to cast and methods of its elimination. Archives of Foundry Engineering. 9(4), 73-76.
[15] Sheladiya, M.V., Acharya, S.G., Mehta, K., Acharya, G.D. (2019). Evaluate sulphur diffusion at mould-metal interface in no-bake mould system. Archives of Foundry Engineering. 19(1), 63-70. DOI: 10.24425/afe.2018.125193.
[16] Anca, D., Stan, I., Chisamera, M., Riposan, I. & Stan, S. (2021). Experimental study regarding the possibility of blocking the diffusion of sulfur at casting-mold interface in ductile iron castings. Coatings. 11(673), 1-10. DOI: https://doi.org/10.3390/coatings11060673.
[17] Dańko, J., Dańko, R. & Łucarz, M. (2007). Processes and devices for the matrix regeneration of spent molding sands. Kraków: WN Akapit. ISBN: 978-83-89541-88-8 (in Polish).
[18] Holtzer, M., Bobrowski, A., Drożyński, D., Isendorf, B., Mazur, (2012). Influence of the reclaim on the properties of moulding sands with furfuryl resin applied for moulds for manganese steel castings. Archives of Foundry Engineering. 12(1), 57-62.
[19] Dańko, R., Górny, M., Holtzer, M., Żymankowska-Kumon, S. (2014). Effect of the quality of furan moulding sand on the skin layer of ductile iron castings. ISIJ International. 54(6), 1288-1293. DOI: https://doi.org/10.2355/isijinternational.54.1288.
[20] Pałyga, Ł., Stachowicz, M., Granat, K. (2015). Evaluation of 2D and 3D surface roughness of die castings from alloy AlSi9Cu3. Archives of Foundry Engineering. 15(1), 75-80.

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Authors and Affiliations

J. Kamińska
1
ORCID: ORCID
M. Angrecki
1
ORCID: ORCID
S. Puzio
1
ORCID: ORCID
M. Stachowicz
2
ORCID: ORCID

  1. Łukasiewicz Research Network – Krakow Institute of Technology, Poland
  2. Wroclaw University of Technology, Faculty of Mechanical Engineering, Poland
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Abstract

Increasing demands are imposed on foundries to enforce the manufacture of castings characterized by tight dimensional tolerances, high surface finish and total absence of casting defects. To face these challenges, castings are increasingly made in loose self-hardening sands with furfuryl resin, commonly known as furan sands. In the group of self-hardening sands with synthetic resins, loose self-hardening sands with furfuryl resin enjoy the greatest popularity. The sand mixtures based on furan resins are usually subjected to mechanical reclamation. The consumption of binder and hardener and thus the cost of the sand depend on the quality of reclaim, and mainly on the dust removal degree.

The planned tightening of the environmental protection regulations in the EU countries, including limiting the content of free furfuryl alcohol in resins and reducing the emission of furfuryl alcohol, formaldehyde and BTEX compounds at workplaces, necessitated the development of a new generation of eco-friendly furfuryl resins that have recently appeared on the market.

The main aim of this article was to determine the effect of reclaim content on the sand parameters, such as bending strength, tensile strength, bench life, gas-forming tendency and loss on ignition. Tests were carried out with reclaim content in the sand mixture varying from 50 to 90%. The reclaim obtained by dry mechanical reclamation was supplied by one of the domestic foundries.

The results showed that the highest mechanical properties were obtained in sands containing 60% of the reclaim.

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Authors and Affiliations

J. Kamińska
ORCID: ORCID
S. Puzio
ORCID: ORCID
M. Angrecki
ORCID: ORCID
A. Łoś
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Abstract

Binder jetting (BJ) sand printing is a 3D printing process in which a sand mould or sand core is produced from an STL file. A single layer of a sand matrix consisting of one or more grains in height of sand is applied to a worktable, and then a liquid resin or binder is applied to bond the grains together. This process is repeated until the final result matches the CAD model. The sand matrix is the main component of ceramic cores and moulds. The present study aims to demonstrate the influence of the matrix used on the properties of the resulting moulding sand. Three types of sand matrices were selected for the study. The first was a quartz matrix for 3D printing with binder jetting; this is characterised by a sharp geometry that allows for proper layering during printing. Ordinary quartz sand was also used for the study; this type of sand is usually used for the production of sand cores in the hotbox process, among other things. The shape of this sand is irregular. The last matrix to be tested was Cerabeads sand; this was selected because its spherical geometry clearly distinguishes it from the other two matrices. The matrices were analysed for their grain sizes. Scanning electron microscope images were also taken to compare the geometries and chemical compositions of the respective matrices. In presented research utilises a sand matrix for the production of self-curing compounds with furan resin dedicated for binder jetting 3D printing. The moulding masses were produced in a laboratory circulation mixer. The laboratory moulds were produced with wooden core boxes and pre-compacted by vibration. The samples from the matrix for the 3D printing were produced using the binder jetting method. The samples were produced to determine the flexural strength, tensile strength, gas permeability, hot distortion, and apparent density. It was not possible to carry out tests for the Cerabeads sand, as the obtained moulds were too brittle to perform adequate tests. Tests with the other matrices have shown that the shape and size of the matrix affect the apparent density and gas permeability.
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Bibliography

[1] Mostafaei, A., Elliott, A.M., Barnes, J.E., Li, F., Tan, W., Cramer, C.L., Nandwana, P. & Chmielus, M. (2020). Binder jet 3D printing – process parameters, materials, properties, and challenges. Progress in Materials Science. 119, 100707. DOI: https://doi.org/10.1016/j.pmatsci.2020.100707.
[2] Le Néel, T.A., Mognol, P. & Hascoët, J.-Y. (2018). A review on additive manufacturing of sand molds by binder jetting and selective laser sintering. Rapid Prototyping Journal. 24(8), 1325-1336. https://doi.org/10.1108/RPJ-10-2016-0161.
[3] Gibson, I., Rosen, D. W., Stucker, B., Khorasani, M. (2021). Additive manufacturing technologies. Cham, Switzerland: Springer. DOI:10.1007/978-3-030-56127-7.
[4] Upadhyay, M., Sivarupan, T., & El Mansori, M. (2017). 3D printing for rapid sand casting—A review. Journal of Manufacturing Processes. 29, 211-220. https://doi.org/10.1016/j.jmapro.2017.07.017.
[5] Lewandowski, J.L. (1997). Materials for casting molds. Krakow: Akapit. (in Polish).
[6] Jakubski, J. & Dobosz, S. M. (2007). The thermal deformation of core and moulding sands according to the hot distortion parameter investigations. Archives of Metallurgy and Materials. 52(3), 421.
[7] Ignaszak, Z., Popielarski, P. & Strek, T. (2011). Estimation of coupled thermo-physical and thermo-mechanical properties of porous thermolabile ceramic material using Hot Distortion Plus® test. Defect and Diffusion Forum. 312-315, 764-769. DOI:10.4028/www.scientific.net/DDF.312-315.764. [
8] Dańko, R. (2017). Influence of the matrix grain size on the apparent density and bending strength of sand cores. Archives of Foundry Engineering. 17(1), 27-30. DOI:10.1515/afe-2017-0005.
[9] Sundaram, D., Svidró, J.T., Svidró, J. & Diószegi, A. (2022). A novel approach to quantifying the effect of the density of sand cores on their gas permeability. Journal of Casting & Materials Engineering. 6(2), 33-38. DOI:10.7494/jcme.2022.6.2.33.
[10] Wisniewski, P., Sitek, R., Towarek, A., Choinska, E., Moszczynska, D., & Mizera, J. (2020). Molding binder influence on the porosity and gas permeability of ceramic casting molds. Materials. 13(12), 2735, 1-13. DOI:10.3390/ma13122735.
[11] Dobosz, S.M., Grabarczyk, A., Major-Gabryś, K. & Jakubski, J. (2015). Influence of quartz sand quality on bending strength and thermal deformation of moulding sands with synthetic binders. Archives of Foundry Engineering. 15(2), 9-15. DOI:10.1515/afe-2015-0028.
[12] Multiserw-Morek (2014) Device for testing the strength of molding sands. Retrieved October 15, 2023, from http://multiserw-morek.pl/products,urzadzenia_do_badania_mas_formierskich_i_rdzeniowych,urzadzenie_do_badania_wytrzymalosci_mas_formierskich-1. (in Polish).
13] Bobrowski, A., Kaczmarska, K., Drożyński, D., Woźniak, F., Dereń, M., Grabowska, B., Żymankowska-Kumon, S. & Szucki, M. (2023). 3D Printed (Binder Jetting) Furan Molding and Core Sands—Thermal Deformation, Mechanical and Technological Properties. Materials. 16(9), 3339, 1-17. DOI:10.3390/ma16093339.
[14] Multiserw-Morek (2014) Device for measuring the permeability of molding sands. Retrieved October 15, 2023, from http://multiserw-morek.pl/products,urzadzenia_do_badania_mas_formierskich_i_rdzeniowych,urzadzenie_do_pomiaru_przepuszczalnosci_mas_formierskich. (in Polish).
[15] Multiserw-Morek (2014) A universal device for testing hot-distortion phenomena and bending strength. Retrieved October 15, 2023, from http://multiserw-morek.pl/products,urzadzenia_do_badania_mas_formierskich_i_rdzeniowych,uniwersalny_aparat_do_badania_zjawisk_hot-distortion_oraz_wytrzymalosci_na_zginanie. (in Polish).
[16] Kamińska, J., Puzio, S., Angrecki, M. & Łoś, A. (2020). Effect of reclaim addition on the mechanical and technological properties of moulding sands based on pro-ecological furfuryl resin. Archives of Metallurgy and Materials. 65(4), 1425-1429. DOI: 10.24425/amm.2020.133709.
[17] Major-Gabryś, K. (2019). Environmentally friendly foundry molding and core sands. Journal of Materials Engineering and Performance. 28, 3905-3911. DOI:10.1007/s11665-019-03947-x.
[18] Mitra, S., Rodríguez de Castro, A. & El Mansori, M. (2018). The effect of ageing process on three-point bending strength and permeability of 3D printed sand molds. The International Journal of Advanced Manufacturing Technology. 97, 1241-1251. DOI:10.1007/s00170-018-2024-8.
[19] Sundaram, D., Svidró, J.T., Svidró, J. & Diószegi, A. (2021). On the relation between the gas-permeability and the pore characteristics of furan sand. Materials. 14(14), 3803, 1-14. DOI:10.3390/ma14143803.
20] Łucarz, M., Drożyński, D., Garbacz-Klempka, A., Jezierski, J., Bartocha, D., Wróbel, T., Kostrzewa, K., Feliks, E. (2022). Influence of weather conditions and mechanical reclamation on molding sand with alkali-phenolic binder for manganese cast steel. Materials. 16(1), 71, 1-18. DOI:10.3390/ma16010071.
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Authors and Affiliations

D.R. Gruszka
1
ORCID: ORCID
R. Dańko
1
ORCID: ORCID
M. Dereń
1
A. Wodzisz
1

  1. AGH University of Krakow, Faculty of Foundry Engineering, Poland
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Abstract

Recently, some major changes have occurred in the structure of the European foundry industry, such as a rapid development in the production of castings from compacted graphite iron and light alloys at the expense of limiting the production of steel castings. This created a significant gap in the production of heavy steel castings (exceeding the weight of 30 Mg) for the metallurgical, cement and energy industries. The problem is proper moulding technology for such heavy castings, whose solidification and cooling time may take even several days, exposing the moulding material to a long-term thermal and mechanical load. Owing to their technological properties, sands with organic binders (synthetic resins) are the compositions used most often in industrial practice. Their main advantages include high strength, good collapsibility and knocking out properties, as well as easy mechanical reclamation. The main disadvantage of these sands is their harmful effect on the environment, manifesting itself at various stages of the casting process, especially during mould pouring. This is why new solutions are sought for sands based on organic binders to ensure their high technological properties but at the same time less harmfulness for the environment. This paper discusses the possibility of reducing the harmful effect of sands with furfuryl binders owing to the use of resins with reduced content of free furfuryl alcohol and hardeners with reduced sulphur content. The use of alkyd binder as an alternative to furfuryl binder has also been proposed and possible application of phenol-formaldehyde resins was considered.

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Authors and Affiliations

K. Major-Gabryś
ORCID: ORCID
M. Hosadyna-Kondracka
ORCID: ORCID

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