The article presents a methodology for analysing historical gas production data and determining the gas reserves and the petrophysical parameters of a reservoir-aquifer system. These parameters are obtained from a fitting algorithm using production data sets. A forecast of the future field gas production can be created on the calibrated mathematical model basis. The developed method is based on the material balance assumptions and the widely used Fetkovich and van Everdingen-Hurst equations for calculating water influx. To conduct the calculations and analyse production data, the computer application was developed using Python programming language. A user-friendly graphical interface makes the proposed application convenient and intuitive to use. The software was calibrated based on the literature data from the gas field of known parameters and then validated using five case studies of the actual gas fields in the Polish Carpathian Foredeep. From the tests, very high compatibility between the computed and the real field values were obtained. An additional comparison with the commercial program MatBal confirmed the proper functioning of the application.

The paper presents the results of anaerobic digestion and co-digestion under mesophilic conditions in the OxiTop system and in lab-scale fermentors. The goal of the study was to determine the effect of reaction-based oil waste on biogas production in co-fermentation with sewage sludge (mixture of thickened primary and excess sludge). The average water content in sewage sludge was 97 %, with 70 % of total volatile solids concentration (TVS) in total solids. Weight content of oil waste in the mixture of sewage sludge ranged from 15 to 45 % (w/w) and the increase in TVS to 83.7 % was observed. The primary investigations of gas productivity by manometrie method (OxiTop) showed that biogas production increased with increasing content of oil waste in the mixture with sewage sludge. The rate constant of the first-order kinetics for biogas production was determined. To determine the yield parameters of cofermentation, the experiment was performed in four continuously stirred anaerobic reactors with a working volume of IO drrr'. Organic loading rate (OLR) changed from 0.9 to 3.1 kg TVS/m3•d. High correlation between biogas flow rate and OLR was observed. Volumetric biogas production rate and the average methane content in the biogas increased from 0.79 to 1.98 m3/m3-d and from 52.3 to 62.3 %, respectively, as OLR increased. The results obtained in lab-scale fermentors are promising and open the possibilities of the implementation of co-fermentation of sewage sludge and oil waste.

The article present the results of use of the proposed economic and mathematical apparatus to develop scenarios that provide for the partial or complete elimination of contradictions associated with the pricing policy between oil and gas production and the production of refined products. In the output we noted changes in the material consumption of products of the oil and gas sector of Ukraine. We corrected a certain contradiction between the extractive and processing enterprises of the oil and gas sector. This is related to the uneven distribution of value added between them, which allows extractive enterprises to make a profit, while processing enterprises are at a breakeven point. This situation, as we have seen, also distorts the results of the real assessment of resource efficiency in this sector of the economy. Thus, the research is aimed at developing scenarios that provide for a gradual decrease in the price of extractive products and its simultaneous growth in processing so that the corresponding impact on the economy was minimal. The first scenario envisaged a reduction in the price by –10% for the products of oil and gas companies with a simultaneous increase in the price of refining so that the average share of value added in the country as a whole was not decreased, taking appropriate adjustments of resource efficiency indicators into account. The second scenario was based on the need for deeper price adjustments in the oil and gas sector. Thus, the reduction of the price of products at the extractive enterprises at the level of –20% and its increase it in processing while maintaining the national average share of value added was envisioned. The third scenario provided for the equalization of material consumption in production and processing due to the price factor.

The impact of mechanical pre-treatment of municipal solid waste (MSW) on its biogas production potential was examined. Mechanical separation allowed the following size-fractions to be obtained: fine fraction - mineral fraction of municipal solid waste (MFMSW) (cf> < 20 mm), middle fraction - organic fraction of municipal solid waste (OFMSW) (20 mm< cf>< 80 mm), and coarse fraction (cf>> 80 mm). The most suitable fraction for biological treatment was OFMSW, containing about 76 % of high rate biodegradable organic fraction (HRBOF). The rate constant of degradation for organic compounds in OFMSW was 0.23 d·1• It was shown that total gas production (TGP) during 10 years may achieve 550 m3/Mg OFMSW. Mechanical pre-treatment may allow an 45 % decrease of the amount of landfilled MSW resulting in a reduction of greenhouse gas emissions of up to 70 m3/Mg over 10 years of landfilling (in contrast to MSW landfilling - 213 m3/Mg). The experimental results revealed that gas production potential should be determined on the basis of HRBOF content and measurements of the biogas production.

The Silurian Pelplin Formation is a part of a thick, mud-prone distal fill of the Caledonian foredeep, which stretches along the western margin of the East European Craton. The Pelplin Formation consists of organic carbon- rich mudstones that have recently been the target of intensive investigations, as they represent a potential source of shale gas. The Pelplin mudstones host numerous calcite concretions containing authigenic pyrite and barite. Mineralogical and petrographic examination (XRD, optical microscopy, cathodoluminoscopy, SEM-EDS) and stable isotope analyses (δ13Corg, δ13C and δ18O of carbonates, δ34S and δ18O of barite) were carried out in order to understand the diagenetic conditions that led to precipitation of this carbonate-sulfide-sulfate paragenesis and to see if the concretions can enhance the understanding of sedimentary settings in the Baltic and Lublin basins during the Silurian. Barite formed during early diagenesis before and during the concretionary growth due to a deceleration of sedimentation during increased primary productivity. The main stages of concretionary growth took place in yet uncompacted sediments shortly after their deposition in the sulfate reduction zone. This precompactional cementation led to preferential preservation of original sedimentary structures, faunal assemblages and early- diagenetic barite, which have been mostly lost in the surrounding mudstones during burial. These components allowed for the reconstruction of important paleoenvironmental conditions in the Baltic and Lublin basins, such as depth, proximity to the detrital orogenic source and marine primary productivity. Investigation of the concretions also enabled estimation of the magnitude of mechanical compaction of the mudstones and calculation of original sedimentation rates. Moreover, it showed that biogenic methane was produced at an early-diagenetic stage, whereas thermogenic hydrocarbons migrated through the Pelplin Formation during deep burial.

In this study some of the experimental results of water shut-off treatments in oil and gas production wells were presented. The effect of water saturation of Miocene rocks of the Carpathian Foredeep on the relative permeability to gas was analyzed. Also, wide review of the worldwide publications from the point of view of the results obtained in water shut-off treatments in oil and gas formation was presented. Based on experimental results efficiency of relative permeability modification of sandstone from Szydłowiec to brine and nitrogen by four selected chemicals polymers and microgels was evaluated. Experimental results indicated that trend changes of permeability modification strongly depends on the fluid used in the RPM treatment. Moreover, efficiency of permeability modification to brine depends on flow rate of brine through the core - the lower brine flow rate the higher efficiency of the RPM treatment. RPM product number 1 caused significant loss of permeability to brine ca. 60% and slight permeability modification to gas ca. 18%. This permeability change to brine and gas was obtained by modification of formation wettability what affects well productivity. In the case of product number 2 which is based on microgels technology, also significant modification of selective permeability to brine was observed. Loss of permeability to brine was in the range of 65 to 90% while to gas ca. 50%.