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Abstract

Alkali-aggregate reactivity (AAR) is one of the major causes of damage in concrete. Potential susceptibility of aggregates to this reaction can be determined using several methods. This study compares gravel alkali reactivity results obtained from different tests conducted on coarse aggregates with complex petrography. The potential for the reactivity in the aggregates was revealed in the chemical test using treatment with sodium hydroxide. Optical microscopy, scanning electron microscopy and X-ray diffraction were used to identify the reactive constituents. The expansion measured in the mortar bars test confirmed that the aggregate was potentially capable of alkali silica reactivity with consequent deleterious effect on concrete.

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Authors and Affiliations

Z. Owsiak
P. Czapik
J. Zapała-Sławeta
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Abstract

The process of historical building conservation includes the repair of mortars eroded due to material and environmental factors. Identification of old mortar constituents is necessary to enable duplicating the material. Information on the binder and aggregate types and contents can be obtained from microscopic observation used in combination with instrumental methods. This paper presents the results of microstructure and mineral composition tests of mortars collected from the walls of thirteenth century buildings. A combination of techniques was used, which included X-ray diffraction, transmitted light optical microscopy and scanning electron microscopy with micro-area elemental composition analysis. The test results revealed porous lime and sand mortars with a binder-aggregate ratio often beyond the commonly adopted values. The mortars contained sand grains of up to 0.5 mm and larger pieces of limestone, flint, feldspar and brick. Transmitted light optical microscopy and scanning microscopy were found to be essential techniques for mortar characterization in existing buildings and structures.

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Bibliography

  1.  C.J. Groot, P. Bartos, and J.J. Hughes, “Historic mortars: Characteristic and tests – concluding summary and state-of-the-art”, in Proc. Intern RILEM workshop, Advanced Concrete and Masonry Centre, University of Paisley, Scotland, 1999.
  2.  J. Elsen, “Microscopy of historic mortars – a review”, Cem. Conc. Res. 36, 1416‒1424 (2006).
  3.  L. Czarnecki and D. Van Gemert, “Scientific basis and rules of thumb in civil engineering: conflict or harmony?”, Bull. Pol. Ac.: Tech. 64(4), 665‒673 (2016).
  4.  K.M. Haneefa, S.D. Rani, R. Ramasamy, and M. Santhanam, “Microstructure and geochemistry of lime plaster mortar from a heritage structure”, Constr. Build. Mater. 225, 538–554, (2019).
  5.  G. Borsoi, A. Santos Silva, P. Menezes, A. Candeias, and J. Mirao, “Analytical characterization of ancient mortars from the archaeological roman site of Pisoes (Beja, Portugal)”, Constr. Build. Mater. 204, 597–608 (2019).
  6.  B. Middendorf, G. Baronio, K. Callebaut, and J. Hughes, “Chemical – mineralogical and physical – mechanical investigation of old mortars”, in Proc. Intern. RILEM workshop, Advanced Concrete and Masonry Centre, University of Paisley, Scotland, 1999, pp. 53‒60.
  7.  J.J. Hughes, S. Cuthbert, and P. Bartos, “Alteration textures in historic Scottish lime mortars and the implications for practical mortar analysis”, Proc. of the 7th Euro seminar on Microscopy Applied to Building Materials, Delft, 1999, pp. 417‒426.
  8.  E. Sandström-Malinowski, “Historic mortars revived”, Proc. of the Intern. RILEM-workshop Repair mortars for historic masonry, Delft, 2005.
  9.  L.B. Sickels, “Organics vs. synthetics: their use as additives in mortars”, Proc. of the ICCROM Symposium Mortars, Cements and Grouts used in the Conservation of Historic Buildings, Rome, 1981, pp. 25‒53.
  10.  J. Elsen, A. Brutsaert, M. Deckers, and R. Brulet, “Microscopically study of ancient mortars from Tournai (Belgium)”, Mater. Charact. 53, 289‒295 (2004).
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Authors and Affiliations

Zdzisława Owsiak
1

  1. Kielce University of Technology, Aleja Tysiąclecia Państwa Polskiego 7, 25-314 Kielce, Poland
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Abstract

The results from the experimental research are presented in the abstract. The experimental research involved utilization of the sludge from the mine water treatment plant of Coal Quarry ČSA/Czechoslovak Army/ (hereinafter “ČSA”) and Coal Quarry Jana Švermy (hereinafter “JŠ”) in the segment of thermal insulation mortars. The mine water treatment is described below including chemical and mineralogical sludge composition as the additional component of the binding material in the polyurethane thermal insulation mortars. Furthermore the composition of experimental mixtures of the thermal insulation polyurethane mortar is presented in the work and its physical-mechanical properties. The monitored elements included the strength characteristics, heat conductivity coefficient λ, and water vapour diffusion coefficient μ.

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Authors and Affiliations

V. Václavík
J. Daxner
J. Valíček
V. Dombek
T. Dvorský
M. Kušnerová
B. Václavíková
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Abstract

The article is an attempt to compare the impact of the use of various types of limestone as the main constituent of cement on selected mortar properties. Four different limestones were added in amount of 15, 30, 40% to CEM I 42.5 R to obtain limestone cemens. Rheological properties (yield stress, plastic viscosity) of fresh mortar, tensile and compressive mortar strength, early shrinkage, and drying shrinkage were tested. Obtained results indicate that both tensile and compressive strength decreases with the increase of the limestone content in cement. Limestone can worsen or improve workability, depending on distribution of limestone grains. The addition of limestone increases the early shrinkage, but reduces the shrinkage after 28 days. Studies show that the granulation of limestone plays an important role in determining the influence of limestone on mortar properties.

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Authors and Affiliations

J. Gołaszewski
G. Cygan
M. Gołaszewska
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Abstract

In the paper, which can be treated as a continuation of research intended to identify the time period when the Rotunda of St. Nicholas in Przemyśl had been built, we made another attempt to define the period of the church’s construction based on the current state of the art and with the use of precise research equipment. Our study was aimed at defining the structures of the building’s material obtained via chemical and crystalline composition analysis of collected mortar samples. We also attempted to define the site of the quarry from where the material used to build the church had been procured from, using tools to assess their chemical and crystalline compositions. We identified the composition of the samples via in situ and laboratory testing (instrumental analyses). The findings allowed us to determine the chemical and crystalline composition of mortars and the chemical and crystalline composition of stone and to compare it with other dated buildings.
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Bibliography

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Gosztyła, M., Proksa, M. (1997), Kościół św. Mikołaja w Przemyślu na tle rotund prostych w Polsce, Przemyśl, Parafia Św. Jana Chrzciciela przy Bazylice Archikatedralnej.
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Klimek, B. ‘Metody badań zapraw historycznych — problematyka konserwatorska’, Budownictwo i Architektura, 2015 14(2), pp. 63–69.
Koperski, A. (ed.) (2004), Dzieje Przemyśla, T. 1 Osadnictwo pradziejowe i wczesnośredniowieczne, cz. 2 Analiza źródeł i synteza, Przemyśl: Towarzystwo Przyjaciół Nauk w Przemyślu.
Kubica, E. ‘Stan badań archeologicznych nad zabytkami wczesnośredniowiecznej architektury monumentalnej Małopolski, Rusi Halickiej i Wołynia’, Materiały Archeologiczne, Vol. 29, 1996, pp. 63–110.
Kubica-Kabacińska, E. (2001), ‘Stan i potrzeby badań archeologicznych nad najstarszymi zabytkami architektury sakralnej w Małopolsce’ [in:] Dzieje Podkarpacia, Vol. 5 Początki chrześcijaństwa w Małopolsce, pp. 215–222.
Malinowski, A. ‘Średniowieczne materiały kostne z cmentarzyska w Jarosławiu i podziemiach katedry w Przemyślu’, Rocznik Przemyski, Vol. 12, 1968, pp. 37–50.
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Pająk, R. et al. (2007), Objaśnienia do mapy geośrodowiskowej Polski 1:50000, Arkusz Przemyśl (1027), Warszawa: Państwowy Instytut Geologiczny, p. 11.
Pianowski, Z. (2001), ‘Rotunda św. Mikołaja w Przemyślu w świetle badań archeologiczno-architektonicznych [in:] Dzieje Podkarpacia, Vol. 5 Początki chrześcijaństwa w Małopolsce, pp. 223–274.
Pianowski, Z., Proksa, M. (1998), Rotunda św. Mikołaja w Przemyślu: po badaniach archeologiczno-architektonicznych w latach 1996–1998, Przemyśl: Archiwum Państwowe w Przemyślu, p. 71.
Pianowski, Z., Proksa, M. (2000), ‘Przemyśl — podziemia katedry. Badania archeologiczno-architektoniczne rotundy św. Mikołaja’ [in:] Buko, A., Świechowski, Z. (eds.) Osadnictwo i architektura ziem polskich w dobie Zjazdu Gnieźnieńskiego, Warszawa, pp. 235–238.
Pianowski, Z., Proksa, M. (2008), Najstarsze budowle Przemyśla. Badania archeologiczno-architektoniczne do roku 2006, Rzeszów: Fundacja Rzeszowskiego Ośrodka Archeologicznego, p. 64.
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Authors and Affiliations

Marek Gosztyła
1
ORCID: ORCID
Krystian Sikorski
1
ORCID: ORCID

  1. Rzeszów University of Technology, Faculty of Civil and Environmental Engineering and Architecture
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Abstract

Mortar feedstock is extruded to form bead and it is selectively placed line by line in the material extrusion additive manufacturing. With respects to part building process healthiness, load-supporting ability of overlaid beads is emphasized as buildability. Buildability is primarily dependent on thixotropic properties of feedstock and vertical overlapping schedule. In the present study, water-to-binder (w/b) ratio was chosen as material aspect to assess buildability. Uneven bead shape evolution and premature failure were highlighted owing to low yield stress of high w/b ratio feedstock. Feedstock with optimum w/b ratio showed good buildability even at the interval time of 19 sec.

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Authors and Affiliations

Jinsoo Park
Hojae Lee
Hanshin Choi
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Abstract

The article presents and describes the methodology of the conservation of stone structures that are architectural monuments discovered as part of the work carried out during archaeological excavations in Tanais. The authors’ experiences presented in the article result from many years of cooperation between the Faculty of Civil Engineering at Warsaw University of Technology and the Antiquity of Southeastern Europe Research Centre at the University ofWarsaw. Examples of preserved masonry structures come from an excavation in Tanais near Rostov-on-Don. Works on stone structures located in the area of archaeological excavation are characterised by a unique specificity covering both formal issues, resulting from international standards and agreements regulating the conservation of historic buildings, as well as technical and environmental issues. The primary technical issues include ensuring the safety of further excavation works, protection of masonry structures against the destructive effects of atmospheric conditions and preparing the structure for possible exhibition in archaeological parks organized on the site of excavations. The article presents the procedures that should be used to conserve this type of structure and the specific sustainable technological and material solutions used in the shown objects.
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Authors and Affiliations

Wojciech Terlikowski
1
ORCID: ORCID
Ewa Sobczyńska
1
ORCID: ORCID
Martyna Gregoriou-Szczepaniak
1
ORCID: ORCID
Kacper Wasilewski
1
ORCID: ORCID

  1. Warsaw University of Technology, Faculty of Civil Engineering, Amii Ludowej 16, 00-637 Warsaw, Poland
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Abstract

The tower at Lublin Castle, known as the donjon, is the only monument of Romanesque art on the eastern side of the Vistula River. The cylindrical, brick building is part of the Lublin Castle complex. During contemporary restoration work, the 13th-century walls were uncovered, making it possible to retrieve the original materials. The article presents the mineralogical, chemical and granulometric characteristics. The analytical methodology included: qualitative mineralogical analysis of the whole sample by X-ray diffraction (XRD); morphological studies with elemental evaluation and microanalysis of the binder by scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM-EDS). Residue determination of hydrochloric acid-insoluble parts and their granulometric analysis were performed. This methodology enabled to determine the composition of the mortars. It was found that the tested mortars have a similar mineralogical structure, but slightly differ in the proportion of individual components, primarily aggregate fractions. The samples consist mainly of quartz, calcite, and silicates. Moreover, the lime binder of the mortars was shown to be microcrystalline in nature. The aggregate used in historical mortars predominantly consisted of quartz sand and minerals of the feldspar and silicate group. The condition of the mortars requires conservation interventions. The performed characterization of the historic mortars was important for designing compatible restoration mortars.
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Authors and Affiliations

Beata Klimek
1
ORCID: ORCID

  1. Lublin University of Technology, Faculty of Civil Engineering and Architecture, Department of Conservation and Built Heritage, Nadbystrzycka St. 40, 20-618 Lublin, Poland
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Abstract

Calcium Sulfoaluminate cements (CSA) may be an alternative to Portland cements due to their very high early strength and more environmentally friendly production technology, however they are characterized by a short setting time and high cost. A possible solution to these problems is to mix CSA cement with other binders or additives. In order to test this possibility, CSA cement was mixed with Portland cement and limestone in the amount of 10, 20 and 30 wt. %. A hydration heat test was carried out in the first 72 hours after the components were mixed, measured were compressive and flexural strength after 1, 2, 7 and 28 days, and rheological properties, including early shrinkage. A negative interaction between CSA and CEM I 42.5R was observed, leading to deterioration of mechanical properties of the mortars. The study did not indicate a similar negative interaction between CSA cement and limestone.
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Authors and Affiliations

Jacek Gołaszewski
1
ORCID: ORCID
Małgorzata Gołaszewska
2
ORCID: ORCID

  1. Prof., DSc., PhD., Eng., Silesian University of Technology, ul. Akademicka 5, 44-100 Gliwice, Poland
  2. PhD., Eng., Silesian University of Technology, ul. Akademicka 5, 44-100 Gliwice, Poland
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Abstract

In this study, the results of experiment research on building mortars based on dry mixtures with the use of granite dust are given. It also shows the possibilities of their industrial release. In the conditions of energy resources shortage, gradual exhaustion of natural raw materials, aggravation of environmental problems, an important direction in the production of building mixtures is the development of mixes with waste materials from various industries. In particular, granite dust, which simultaneously allows to rationally use natural mineral material and solve environmental problems. Based on the obtained data, experimental and statistical models of physical and mechanical properties of fresh and hardened mortar are constructed and ways of optimizing their compositions and improving the properties of mortars are analyzed. It is established that the use of granite dust and some additives provides high standardized parameters for mortar mixture and bricklaying process, including plasticity, compressive strength and others at the low level of cement consumption. Fresh mortar mixtures have a prolonged slump retention.

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Authors and Affiliations

Grzegorz Prokopski
ORCID: ORCID
Vitaliy Marchuk
ORCID: ORCID
Andriy Huts
ORCID: ORCID
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Abstract

In this study, cubic and cylindrical cement mortar specimens were first subjected to high temperatures, then the cubic and cylindrical specimens were taken out and conducted with uniaxial compressive test and splitting tensile test, respectively. The effect of the length to side ratio on the uniaxial compressive properties and the effect of thickness-to-diameter ratio on the splitting tensile properties of cement mortar specimens after high temperature were studied. Test results show that: (1) With temperature increasing from 25°C (room temperature) to 400°C, the compressive strength and elastic modulus of cubic specimens with three kinds of side lengths decrease; the decreasing rates of compressive strength and elastic modulus of cubic specimen with side length of 70.7 mm is higher than those of cubic specimens with side length of 100 mm and 150 mm, and the strain at the peak stress of cubic specimens with three kinds of side lengths increase. (2) After the same temperature, the tensile strength of cylindrical specimen decreases with the thickness-to-diameter ratio increasing from 0.5 to 1.0. The decreasing rate of tensile strength of cylindrical specimen with thickness-to-diameter ratio is highest when the temperature is 25°C (room temperature), followed by that after the temperature of 200°C, and that after the temperature of 400°C is the lowest.

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Authors and Affiliations

L.X. Xiong
X.J. Zhang
Z.Y. Xu
D.X. Geng
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Abstract

The effect of the air-entraining agent on properties of mortar mixtures as well as on the compressive strength of hardened mortars was the objective of this study. Such mortars contain a certain amount of evenly spread closed air-voids pores with dimensions of 0.02-0.05 mm. On the one hand, the presence of a large volume of such air bubbles results in the reduction of mechanical properties of mortar. On the other hand, the use of this technological approach improves rheological properties of mortar mixture. The effect of the air entrainment on the flow, density, volume of entrained air of mortar mixture and compressive strength of hardened mortar was established. Obtained results show substantial increasing in the mortar flow at cement to sand ratio 1:2 by 1.8 times. The further decrease of C:S ratio results in a slight increase of the flow and even negligible its decrease at C:S = 1:4 compared to the reference mortar. The increase of the volume of entrained air results in the decrease of the density and compressive strength of mortar, but improve the resistance to freezing/thawing cycles. The results of this study can be a guide for mortar mix design to choose the most appropriate mix proportion to produce economically efficient mortars.
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Authors and Affiliations

Zinoviy Blikharskyy
1
Taras Markiv
2
Khrystyna Sobol
3
Yurii Turba
3
Jacek Selejdak
4

  1. Faculty of Civil Engineering, Czestochowa University of Technology, 69 St. Dabrowskiego, 42-201 Czestochowa, Poland
  2. Department of Building Production, Institute of Civil Engineering and Building Systems, Lviv Polytechnic National University, S. Bandery Street 12, 79013 Lviv, Ukraine
  3. Department of Highways and Bridges, Institute of Civil Engineering and Building Systems, Lviv Polytechnic National University, S. Bandery Street 12, 79013 Lviv, Ukraine
  4. Faculty of Civil Engineering, Czestochowa University of Technology, 69 St. Dabrowskiego,42-201 Czestochowa, Poland
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Abstract

Soluble silica from palm oil clinker was extracted using Laine’s method. It involved two major steps, namely water reflux and distillation. The use of 480 g of POCP and 12 hours of distillation in the extraction experiment resulted in 53.50% of dissolved silica, which was the highest gain among the trial experiments and was chosen as an optimum parameter for the subsequent characterisation analysis. In addition, its effect on cement hydration was studied by including it as a filler in mortar mixtures. Mortar with 7.50% of extracted silica gained high strength in the early days of curing and performed well throughout the maturing age. The rapid hardening properties of soluble silica-based mortar would promote the potential of soluble silica as an additive for rapid hardening.
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Authors and Affiliations

A.H. Ismail
1
ORCID: ORCID
A. Kusbiantoro
1
ORCID: ORCID
L.T. Yian
2
ORCID: ORCID
K. Muthusamy
3
ORCID: ORCID
N.A.M. Mortar
4
ORCID: ORCID

  1. Universiti Tun Hussein Onn Malaysia, Faculty of Engineering Technology, Johor, Malaysia
  2. Universiti Teknologi Malaysia, Faculty of Engineering, Johor, Malaysia
  3. Universiti Malaysia Pahang, Faculty of Civil Engineering Technology Pahang, Malaysia
  4. Universiti Malaysia Perlis (UniMAP), Centre of Excellence Geopolymer & Green Technology (CEGeoGTech), 01000 Perlis, Malaysia
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Abstract

An attempt was made in the present work to study the compressive strength and microstructure of geopolymer containing high calcium fly ash (HCFA) and silica fume. Concentration of sodium hydroxide solution 8M, 10M, 12M & 14M, liquid to binder ratio 0.5 and sodium hydroxide to sodium silicate ratio 2.5 were selected for the mixes. Geopolymer mortar test results indicated that the mix with 40% silica fume by the weight of HCFA yielded higher compressive strength under ambient curing. The XRD pattern typically shows the major portion of amorphous phase of geopolymer. The existence of C-A-S-H gel, N-A-S-H gel and hydroxysodalite gel products were observed through SEM which developed dense microstructure and thus enhanced strength of HCFA and silica fume geopolymer.

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Authors and Affiliations

V.C. Prabha
V. Revathi

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