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Abstract

The key feature of thermosensitive polymers is the reversible transition between the hydrophilic and hydrophopic forms depending on the temperature. Although the main research efforts are focused on their application in different kinds of drug delivery systems, this phenomenon also allows one to precisely control the stability of solid-liquid dispersions. In this paper research on the application of poly(N-isopropylacrylamide) copolymers in processing of minerals is presented. In the experiments tailings from flotation plant of one of the coal mines of Jastrzębska Spółka Węglowa S.A. (Poland) were used. A laser particle sizer Fritsch Analysette 22 was used in order to determine the Particle Size Distribution (PSD). It was proved that there are some substantial issues associated with the application of thermosensitive polymers in industrial practice which may exclude them from the common application. High salinity of suspension altered the value of Lower Critical Solution Temperature (LCST). Moreover, the co-polymers used in research proved to be efficient flocculating agents without any temperature rise. Finally, the dosage needed to achieve steric stabilization of suspension was greatly beyond economic justification.

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Authors and Affiliations

Wojciech Bogacz
Marcin Lemanowicz
Andrzej Gierczycki
Anna Mielańczyk
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Abstract

Powdered polyaniline (PANI) was synthesised chemically with different doping anions namely hydrochloric acid, sulphuric acid and para-toluenesulfonic acid (pTSA). Two-step synthetic procedure was utilised at low temperature. The highest reaction efficiency was found for chlorine-doped PANI. Structural characterization with FTIR revealed the vibration bands characteristic to formation of the emeraldine salt. The surface morphology of doped PANIs was studied by SEM images which showed near globular shape and porous structures with different size of the aggregated particles. They were smaller for Cl–- or pTS–-doped PANI while for SO42– the size was markedly larger. The XRD patterns revealed that there are ordered regions especially for pTS– doped PANI, while the highest conductivity value was recorded for Cl– doped one followed by organic pTS– doped and SO42– doped one.

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Authors and Affiliations

S. Golba
M. Popczyk
S. Miga
J. Jurek-Suliga
M. Zubek
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Abstract

The general standards and guidelines recommendations for PCC suggest alternating conditions of curing: starting with wet conditions for effective hydration of Portland cement followed by air-dry conditions for polymer hardening. The often accepted curing regime of PCC covers 5 days of wet curing and then the air-dry curing but it is not the optimum one. The aim of the investigation was to find the best scenario for PCC with two types of polymer modifiers: two-component epoxy resin and water dispersion of polyacrylates. The following exploitation properties were accepted as the criteria of evaluation of PCC curing effectiveness: compressive strength, tensile splitting strength, surface tensile strength (by pull-off method), wear resistance, water penetration under pressure and resistance to carbonation. The optimum time of PCC wet curing is possibly between 7 and 14 days, however, it have to be verified experimentally for specific PCC composition.

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Authors and Affiliations

P. Woyciechowski
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Abstract

The presented article is a report on progress in photovoltaic devices and material processing. A cadmium telluride solar cell as one of the most attractive option for thin-film polycrystalline cell constructions is presented. All typical manufacturing steps of this device, including recrystalisation and junction activation are explained. A new potential field of application for this kind of device - the BIPV (Building Integrated Photovoltaic) is named and discussed. All possible configuration options for this application, according to material properties and exploitation demands are considered. The experimental part of the presented paper is focused on practical implementation of the high- temperature polymer foil as the substrate of the newly designed device by the help of ICSVT (Isothermal Close Space Vapour Transport) technique. The evaluation of the polyester and polyamide foils according to the ICSVT/CSS manufacturing process parameters is described and discussed. A final conclusion on practical verification of these materials is also given.

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Authors and Affiliations

M. Sibińksi
Z. Lisik
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Abstract

The paper is of practical importance and describes the construction of a test rig and the measurement method for determining the relative emissivity coefficient of thermosensitive thin polymer coatings. Polymers are high-molecular chemical compounds that produce chains of repeating elements called ‘mers’. The polymers can be natural and artificial. The former ones form the building material for living organisms, the latter – for plastics. In this work, the words plastics and polymers are used as synonyms. Some plastics are thermosensitive materials with specific physical and chemical properties. The calorimetric method mentioned in the title consists of two steps. The first stage, described here, involves very accurately measuring the emissivity of black paint with the highest possible relative emissivity coefficient, which covers the surface of the heater and the inner surface of the chamber. In the second step, the thermosensitive polymer will be placed on the inner surface of the chamber, while black paint with a known emissivity coefficient will remain on the heater. Such a way of determining the properties of thermosensitive polymers will increase the error of the method itself, but at the same time will avoid melting of the polymer coating. During the tests, the results of which are presented in this work, the emissivity coefficient of the black paint was obtained in the range of 0.958–0.965.
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Authors and Affiliations

Ewa Pelińska-Olko
1

  1. Wrocław University of Science and Technology, Faculty of Mechanical and Power Engineering, Department of Thermodynamics and Renewable Energy Sources, Wybrzeze Wyspianskiego 27, 50-370 Wrocław, Poland
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Abstract

Nanostructured systems based on ZnO nanoparticles composite systems/polymer fibers have attracted a lot of attention in the last years because of their applications in multiple areas. Nanofibres based on polymers are used in many domains such as nanocatalysis, controlled release of medicines, environmental protection and so on. This work show the synthesis of cellulose acetate butyrate (CAB) nanofiber useful as substrates for growing ZnO nanocrystals and that ZnO is an unorganic metal oxide nanoparticle used to improve the piezoelectric properties of the polymer. The piezoelectric propertiesof ZnO-doped polymeric was investigated with atomic force microscopy and measurements were performed, in contact technique, in piezoelectric response mode (PFM).In order to analyze the structural and textural features, the obtained materials were characterized using advanced physical-chemical techniques such as X-ray diffraction (XRD), Atomic Force Microscopy (AFM), Scanning Electron Microscopy (SEM). The XRD patterns show the characteristic reflections of ZnO with a hexagonal type wurtzit structure and the broad peaks of the polymer. The SEM images reveal the presence of ZnO nanoparticles on top of the polymer nanofibres.In most ZnO-based nanocomposites their morphology is uncontrolled (agglomerated granules), but in ase of using cellulose acetobutyrate this becomes controlled by observing through flower-like structures SEM and AFM) The study of the functional properties of ZnO/polymer fiber composite systems showed that they have piezoelectric properties which give them the characteristics of smart material with possible sensor and actuator applications.Recent literature reports that the synthesis and characterization of ZnO-polymer nanocomposites are more flexible materials for various applications.
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Authors and Affiliations

G. Calin
1
ORCID: ORCID
L. Sachelarie
1
ORCID: ORCID
N. Olaru
2
ORCID: ORCID

  1. Apollonia University of Iasi, Faculty of Dental Medicine, 11 Pacurari Str., 700511, Iasi, Romania
  2. Institute of Macromolecular Chemistry “Petru Poni” Iasi, Aleea Grigore Ghica Voda,41A, 700487, Iasi, Romania
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Abstract

The state of the art in the field of composite polymer bridges in Poland is presented below. Such bridges were built from 1999. Some of them are fully composite polymer structure. Others are developed as hybrid structure. There are two kind of structures: steel girders with FRP deck and FRP girders with concrete deck. Different production methods of FRP elements were used: pultrusion and infusion. Some bridges are the result of research programs, but there are also some commercial projects. Also, the short application history of FRP bridges all over the world is presented and material properties of the construction material are given in the paper. Those materials are much more lighter than steel or concrete. Low weight of FRP materials is an advantage but also disadvantage. It is good from structural and economical point of view because the dimensions of girders, piers and foundation will be smaller. From opposite side to light structure could cause problems related to response of structure against dynamic actions. As a final result the fatigue strength and durability will be reduced. Of course, the high cost of FRP (CFRP especially) limits at the moment range of application. The presented in the paper bridge structures show that despite of mentioned above problems they are now in good conditions and their future life looks optimistic. It could be supposed that modification and/or development of FRP production technologies more better utilizing their properties will create more elegant and useful bridges.
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Bibliography


[1] Chróścielewski J., Miśkiewicz M., Pyrzowski Ł, Wilde K., “Composite GFRP U-shaped footbridge”, Polish Maritime Research, Special Issue 2017 S1 (93) 2017 Vol. 24, pp. 25–31.
[2] Chróścielewski J., Miśkiewicz M., Pyrzowski Ł, Sobczyk B., Wilde K., “A novel sandwich footbridge – Practical application of laminated composites in bridge design and in situ measurements of static response”, Composites Part B Vol. 126, 2017, pp. 153–161.
[3] De Corte W., Jansseune A., Van Paepegem W., Peeters J., “Structural behaviour and robustness assessment of an InfraCore inside bridge deck specimen subjected to static and dynamic local loading”, Proceedings of the 21st International Conference on Composite Materials, Xi’an, 2017.
[4] Dong C.J., “Development of a process model for the vacuum assisted resin transfer molding simulation by the response surface method”, Composites: Part A Vol. 37, 2006, pp. 1316–1324.
[5] Grotte, B., Karwowski W., Mossakowski, P., Wróbel, M., Zobel, H., Żółtowski, P.: Steel, arch footbridge with composite polymer deck. „Wroclaw Bridge Days” - „Footbridges – Architecture, design, construction, research”. 29–30 November 2007, pp. 135–146.
[6] Grotte B., Karwowski W., Mossakowski P., Wróbel M., Zobel H., Żółtowski P., “Steel, arch footbridge with composite polymer deck with suspended composite polymer deck over S-11 highway nearby Kórnik”, Inżynieria i Budownictwo 1-2/2009, pp. 69–73.
[7] Karwowski W., “Material - structural conditions of joints in FRP bridges”, Ph. D. thesis, Warsaw University of Technology, Warsaw 2011.
[8] Madaj A., “Composite polymer bridges. New structural solutions of bridge girders”, Mosty 3/2015, pp. 58-60.
[9] Mossakowski P., Wróbel M., Zobel H., Żółtowski P. ,Pedestrian steel arch bridge with composite polymer deck. IV International Conference on “Current and future trends in bridge design, construction and maintenance”. Kuala Lumpur. Malaysia. October 2005.
[10] Mylavarapu R., Patnaik A., Puli K., R. K., “Basalt FRP: A new FRP material for infrastructure market?”, Proceedings of 4th International Conference on Advanced Composite Materials in Bridges and Structures, Canadian Society of Civil Engineers, Montreal, 2004.
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[14] Siwowski T., Rajchel M., Własak L., “Experimental study on static and dynamic performance of a novel GFRP bridge girder”, Composite Structures Vol. 259, 2021.
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Authors and Affiliations

Tomasz Siwowski
1
ORCID: ORCID
Henryk Zobel
2
ORCID: ORCID
Thakaa Al-Khafaji
2
ORCID: ORCID
Wojciech Karwowski
2
ORCID: ORCID

  1. Rzeszow University of Technology, Faculty of Civil & Environmental Engineering & Architecture, ul. Powstancow Warszawy 12, 35-859 Rzeszow, Poland
  2. Warsaw University of Technology, Faculty of Civil Engineering, Al. Armii Ludowej 16, 00-637 Warsaw, Poland
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Abstract

We experimentally studied three different D-shape polymer optical fibres with an exposed core for their applications as surface plasmon resonance sensors. The first one was a conventional D-shape fibre with no microstructure while in two others the fibre core was surrounded by two rings of air holes. In one of the microstructured fibres we introduced special absorbing inclusions placed outside the microstructure to attenuate leaky modes. We compared the performance of the surface plasmon resonance sensors based on the three fibres. We showed that the fibre bending enhances the resonance in all investigated fibres. The measured sensitivity of about 610 nm/RIU for the refractive index of glycerol solution around 1.350 is similar in all fabricated sensors. However, the spectral width of the resonance curve is significantly lower for the fibre with inclusions suppressing the leaky modes.

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Authors and Affiliations

K. Gasior
T. Martynkien
G. Wojcik
P. Mergo
W. Urbanczyk
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Abstract

We experimentally studied three different D-shape polymer optical fibres with an exposed core for their applications as surface plasmon resonance sensors. The first one was a conventional D-shape fibre with no microstructure while in two others the fibre core was surrounded by two rings of air holes. In one of the microstructured fibres we introduced special absorbing inclusions placed outside the microstructure to attenuate leaky modes. We compared the performance of the surface plasmon resonance sensors based on the three fibres. We showed that the fibre bending enhances the resonance in all investigated fibres. The measured sensitivity of about 610 nm/RIUfor the refractive index of glycerol solution around 1.350 is similar in all fabricated sensors. However, the spectral width of the resonance curve is significantly lower for the fibre with inclusions suppressing the leaky modes.

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Authors and Affiliations

K. Gasior
T. Martynkien
G. Wojcik
P. Mergo
W. Urbanczyk
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Abstract

In recent years, a growing problem of water deficit has been observed, which is particularly acute for agriculture. To alleviate the effects of drought, hydrogel soil additives – superabsorbent polymers (SAPs) – can be helpful.
The primary objective of this article was to present a comparison of the advantages resulting from the application of synthetic or natural hydrogels in agriculture. The analysis of the subject was carried out based on 129 articles published between 1992 and 2020. In the article, the advantages of the application of hydrogel products in order to improve soil quality, and crop growth.
Both kinds of soil amendments (synthetic and natural) similarly improve the yield of crops. In the case of natural origin polymers, a lower cost of preparation and a shorter time of biodegradation are indicated as the main advantage in comparison to synthetic polymers, and greater security for the environment.
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Authors and Affiliations

Beata Grabowska-Polanowska
1
ORCID: ORCID
Tomasz Garbowski
1
ORCID: ORCID
Dominika Bar-Michalczyk
1
ORCID: ORCID
Agnieszka Kowalczyk
1
ORCID: ORCID

  1. Institute of Technology and Life Sciences – National Research Institute, Falenty, Hrabska Av. 3, 09-090 Raszyn, Poland
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Abstract

This work aims to determine and compare heat generation and propagation of densely packed gold nanoparticles (Au NPs) induced by a resonant laser beam (532 nm) according to the Mie theory. The heat flux propagation is transferred into the materials, which here are: silica glass; soda-lime-silica glass; borosilicate glass; polymethyl methacrylate (PMMA); polycarbonate (PC); and polydimetylosiloxane (PDMS). This analysis aims to select the optimum material serving as a base for using photo-thermoablation. On the other hand, research focused only on Newtonian heat transfer in gold, not on non-Fourier ones, like the Cattaneo approach. As a simulation tool, a computational fluid dynamics code with the second-order upwind algorithm is selected. Results reveal a near-Gaussian and Gaussian temperature distribution profile during the heating and cooling processes, respectively. Dependence between the maximum temperature after irradiation and the glass thermal conductivity is observed confirming the Fourier law. Due to the maximum heating area, the borosilicate or soda-lime glass, which serves as a base, shall represent an excellent candidate for future experiments.
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Bibliography

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Authors and Affiliations

Piotr Radomski
1
Paweł Ziółkowski
1
Luciano de Sio
2
Dariusz Mikielewicz
1

  1. Gdansk University of Technology, Faculty of Mechanical Engineering and Shipbuilding, Energy Institute, Narutowicza 11/12, 80-233 Gdansk, Poland
  2. Sapienza University of Rome, Department of Medico-Surgical Sciencesand Biotechnologies, Center for Biophotonics, Piazzale Aldo Moro 5,00185 Roma, RM, Italy
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Abstract

The development of civilization contributed to the exponential growth in the production of plastics. Policy of the, so-called, “European Green Deal” places particular emphasis on reducing the use of plastics through various mechanisms, including their reuse, recycling and, in particular, the development of new biodegradable and compostable plastics. In order to check if plastics are suitable for biodegradability and compostability they must undergo a series of tests in accordance with applicable standards. The biodegradation test procedures are very general and allow for the use of different temperatures of the biodegradation process in the test. The aim of the research was to evaluate the influence of temperature on the biodegradation process of selected packaging materials. The obtained results show a significant influence of the temperature of the biodegradation process of all 3 tested types of packaging materials: oxy-biodegradable, corn starch and paper. Statistically significant differences in the biodegradation rate of the tested packaging materials were demonstrated in as low as 40°C, despite the low intensity of the process. As the process temperature increased to 45 and 50°C, a statistically significant increase in CO2 productions was recorded. CO2 is produced by the degradation of polymers and is an indicator for this process. At 50°C, the highest decomposition rate, resulting in the highest CO2 production, was recorded in the case of corn starch films. Oxy-biodegradable material showed worst degradation potential what excludes it from composting processes.
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Bibliography

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  10. Gomez, E.F. & Michel, F.C. Jr. (2013). Biodegradability of conventional and bio-based plastics and natural fiber composites during composting, anaerobic digestion and long-term soil incubation. Polymer Degradation and Stability 98, pp. 2583-2591. DOI:10.1016/j.polymdegradstab.2013.09.018
  11. Gorokhova, E., Ek, K. & Reichelt S. (2020) Algal Growth at Environmentally Relevant Concentrations of Suspended Solids: Implications for Microplastic Hazard Assessment. Frontiers in Environmental Science 19 Nov. 2020. DOI:10.3389/fenvs.2020.551075
  12. Herniou–Julien, C., Mendieta, J.R. & Gutiérrez T.J. (2019). Characterization of biodegradable/non-compostable films made from cellulose acetate/corn starch blends processed under reactive extrusion conditions. Food Hydrocolloids 89, pp. 67–79 DOI:10.1016/j.foodhyd.2018.10.024
  13. Ivankovic, A., Zeljko, K., Talic, S., Martinovic Bevanda, A. & Lasic M. (2017). Biodegradable packaging in the food industry. Arch Lebensmittelhyg 68, pp. 26–38. DOI:10.2376/0003-925X-68-26
  14. Luchese, C.L., Benelli, P., Spada, J.C. & Tessaro I.C. (2018). Impact of the starch source on the physicochemical properties and biodegradability of different starch-based films. Journal of Applied Polymer Science. DOI:10.1002/APP.46564
  15. Maria, P., Cadar, O., Cadar, s., Levei, E., Pojar-Feneşan, M., Balea, A. & Pascalau, V. (2010). Biodegradability determination of vegetal originated packaging materials under controlled composting conditions. Agricultura – Ştiinţă şi practică 1-2, pp. 73-77
  16. Markowicz, F., Król, G., Szymańska-Pulikowska, A. (2018). Biodegradable Package – Innovative Purpose or Source of the Problem. Journal of Ecological Engineering, 20(1), pp. 228–237. DOI:10.12911/22998993/94585
  17. Markowicz, F. & Szymańska-Pulikowska, A. (2019). Analysis of the Possibility of Environmental Pollution by Composted Biodegradable and Oxo-Biodegradable Plastics. Geosciences, 9(11). DOI:10.3390/geosciences9110460
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Authors and Affiliations

Joanna Poluszyńska
1
Tomasz Ciesielczuk
2
ORCID: ORCID
Marcin Biernacki
1
Maciej Paciorkowski
1

  1. Research Network Łukasiewicz – Institute of Ceramics and Building Materials, Division of Material,Processing and Environmental Engineering, Opole, Poland
  2. Opole University, Opole, Poland
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Abstract

Plastic mulch provides a range of benefits including helping modulate soil temperature, reduce soil erosion, evaporation, fertilizer leaching and weed problems and increasing the quality and yields of the product. But when the crops are harvested, plastic mulch needs to be removed from the ground for disposal. Otherwise, these wastes are mixed with the soil and have a negative impact on yields by reducing the access of nutrients and moisture in the soil. The purpose of the current study is, therefore, to propose a roller for plastic mulch retriever which is applicable when the crops are harvested, and the plastic mulch needs to be removed from the ground for disposal. The winding mechanism of the plastic mulch retriever performs the main function and must have the high-quality performance of the winding operation in the removal technology. Research based on requirements of tensile strength test method and changes of strength characteristics of plastic mulch from various factors under natural conditions. The coefficient of compaction of the used plastic mulch (Krel), was the ratio of the diameter of the standard plastic mulch which was wound in the factory to the diameter of the used plastic mulch during the winding.
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Authors and Affiliations

Kanat M. Khazimov
1
ORCID: ORCID
Adilkhan K. Niyazbayev
1
ORCID: ORCID
Zhanbota S. Shekerbekova
2
ORCID: ORCID
Aigul A. Urymbayeva
2
ORCID: ORCID
Gulzhanat A. Mukanova
2
ORCID: ORCID
Tursunkul A. Bazarbayeva
2
ORCID: ORCID
Vladimir F. Nekrashevich
3
ORCID: ORCID
Marat Zh. Khazimov
1 2 4
ORCID: ORCID

  1. Kazakh National Agrarian University, Faculty of IT – Technology, Automation and Mechanization of Agro-Industrial Complex, Valikhanov St 137, Almaty 050000, Kazakhstan
  2. Al-Farabi Kazakh National University, Faculty of Geography and Environmental Sciences, Almaty, Kazakhstan
  3. Ryazan State Agrotechnological University, Ryazan, Russia
  4. Almaty University of Power Engineering and Telecommunications, Faculty of Heat Power Engineering and Heating Engineering, Almaty, Kazakhstan
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Abstract

Ballistic targets are multi-material assemblies that can be made of various materials, such as metal alloys, ceramics, and polymers. Their role is to provide collective or individual ballistic protection against high-speed dynamic penetrators or kinetic fragments. The paper presents the impact behavior with incendiary perforating bullets having 7.62 mm of ballistic packages made of combinations between Dyneema ultra-high-molecular-weight polyethylene and high entropy alloy from alloying system AlCoCrFeNi, by analyzing the dynamic phenomena (deformation, perforation) that take place at high speeds. The geometry evolution of the physical model subjected to numerical simulation allows a very good control over the discretization network and also allows the export for modeling to nonlinear transient phenomena. The results obtained by numerical simulation showed that the analyzed ballistic package does not allow sufficient protection for values of impact velocities over 500 m/sec.
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Authors and Affiliations

I. Voiculescu
1
ORCID: ORCID
V. Geanta
2
ORCID: ORCID
T. Chereches
3
ORCID: ORCID
P. Vizureanu
4
ORCID: ORCID
R. Stefanoiu
2
ORCID: ORCID
A. Rotariu
5
ORCID: ORCID
D. Mitrica
6
ORCID: ORCID

  1. University Politehnica of Bucharest, Faculty of Industrial Engineering and Robotics, 060042 Splaiul Independentei 313, Bucharest, Romania
  2. University Politehnica of Bucharest, Faculty of Materials Science and Engineering, 060042 Splaiul Independentei 313, Bucharest, Romania
  3. UPS PILOR ARM, Laminorului Street, 2, Targoviste, Romania
  4. Gheorghe Asachi Technical University of Iasi, Faculty of Materials Science and Engineering, 67, Dimitrie Mangeron Street, Romania
  5. Military Technical Academy Ferdinand I, 050141, George Cosbuc, 39-49, Bucharest, Romania
  6. National Research-Development Institute for Non-Ferrous and Rare Metals – IMNR, 077145, Biruintei, 102, Pantelimon, Romania
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Abstract

In this study, the bio state of the alloy produced in the modified metal injection system was monitored after sintering. A new system operating with high gas pressure, far from the traditional injection model, has been established for material production. In this system, 316L stainless steel powders were molded using a PEG/PMMA/SA polymer recipe. During molding, approximately 60% 316L and 40% binder by volume were used. The samples obtained were sintered at different temperatures (1100-1300°C) after de-binding. Density measurement (Archimedes) and hardness tests (HV1) of the samples were measured as 6.74 g/cm3 and ~285 HV1, respectively. A potentiodynamic corrosion test was applied to monitor the effect of the amount of oxide in the structure of the 316L stainless steel produced. Corrosion tests were carried out in artificial body solutions. The corrosion rate was measured at the level of 17.08×10–3 mm/y. In terms of biocompatibility, a cytotoxicity test was applied to the samples and the life course of the bacteria was monitored. For the 316L alloys produced, the % vitality reached approximately 103%.
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Authors and Affiliations

Bünyamin Çiçek
1
Yavuz Sun
2
ORCID: ORCID

  1. Hitit University, Vocational School of Technical Sciences, Machine and Metal Technologies Department, Corum, Turkey
  2. Karabuk University, Engineering Faculty, Turkey
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Abstract

In this research, Graphene nanoplatelets (GNP) reinforced epoxy nano composites were fabricated via magnetic stirrer and ultra sonification assisted hand layup method. The impact of different weight percentage of GNP (0, 0.25, 0.50, and 1.0%) on different characteristics of nano composites was evaluated. The microstructure analysis of developed nano composite was determined by Field emission scanning electron microscopy. It was examined that epoxy nano composites containing 0.5 wt.% GNP have the highest tensile, flexural, and impact strength compared to neat epoxy. The reduction in tensile and flexural strength is achieved at 1% of GNP. Adding more nanofiller to a certain limit causes non-uniform dispersion and agglomeration of nanoparticles, which results in a reduction in properties. The 1% GNP reinforced nano composite has the highest value of shore hardness.
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Authors and Affiliations

A. Namdev
1
ORCID: ORCID
R. Purohit
1
A. Telang
1
A. Kumar
1

  1. Maulana Azad National Institute of Technology, Department of Mechanical Engineering Bhopa l, Madhya Pradesh, India
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Abstract

Halloysite is a filler which may be used to produce composites with thermoplastic polymer matrix. This work summarized the results of investigations of processing, structural, mechanical, and thermal properties of the composites with poly(vinyl chloride) (PVC) matrix and raw halloysite (HA) as well as its calcined product (KHA). The effectiveness of calcination was confirmed with X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, and nitrogen adsorption method. The PVC composites with HA as well as KHA were processed in the molten state in the Brabender mixer chamber. The reduction of gelation time and simultaneous increase in maximum torque with filler content were found based on the results of plastographometric analysis. SEM images of PVC/halloysite composites showed a homogeneous distribution of the filler in the polymer matrix. The introduction of halloysite leads to a slight increase in Young’s modulus and tensile strength compared to neat PVC, where the increase of both parameters is greater when KHA is used. The incorporation of 1% KHA led to an increase in impact strength, an effect which may be attributed to toughening of the polymer. A slight improvement of the Vicat softening temperature of 2.7°C for PVC/HA and heat deflection temperature of 2.4°C for PVC/KHA was also ascertained for PVC modified with 10 wt% of filler.
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Authors and Affiliations

Martina Wieczorek
1
ORCID: ORCID
Jolanta Tomaszewska
1
ORCID: ORCID
Tomasz Bajda
2
ORCID: ORCID
Jacek Długosz
3
ORCID: ORCID

  1. Bydgoszcz University of Science and Technology, Faculty of Chemical Technology and Engineering, Al. Prof. S. Kaliskiego 7, 85-796 Bydgoszcz, Poland
  2. AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, Al. A. Mickiewicza 30, 30-059, Kraków, Poland
  3. Bydgoszcz University of Science and Technology, Faculty of Agriculture and Biotechnology, Al. Prof. S. Kaliskiego 7, 85-796 Bydgoszcz, Poland
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Abstract

The targeted modification of the material composition is a common procedure used to improve the parameters of the final products. This paper deals with the targeted modification of polymer systems composition using two various types of alternative fillers. The first type of alternative filler (SVD) has been obtained from energetics where it arises as a by-product of flue gas desulfurization. The second alternative filler used (KAL) is based on waste from glass production. The elastomeric systems designed for the production of car tires and solid wheels for transport systems were used in the role of modified polymer systems. Alternative fillers (SVD, KAL) have been applied as a substitution of commonly used fillers (carbon black, silica). The filler – elastomeric matrix interaction, rheology, cure characteristics, as well as hardness and rebound resilience of vulcanizates, which are important parameters for their industrial application, have been studied in the new prepared polymeric systems. The main output of the work is a new formulation of an elastomeric system for industrial applications with high rebound resilience and low rolling resistance, which is the subject of the international patent [1]. The modification of composition using raw material substitution can also bring significant environmental and economic effects.
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Bibliography

  1.  D. Ondrušová, M. Pajtášová, and I. Labaj, “Elastomer mixture and method of its preparation”, Patent PCT/SK2019/050015(2020). Available on: https://patentscope.wipo.int/search/en/detail.jsf?docId=WO2020130952&_cid=P21-KBV9GG-52072-1
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Authors and Affiliations

Darina Ondrušová
1
Ivan Labaj
1
Mariana Pajtášová
1
Juliana Vršková
1
Slavomíra Božeková
1
Andrea Feriancová
1
Petra Skalková
1

  1. Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, Ivana Krasku 491/30, 020 01 Púchov, Slovakia
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Abstract

Several recent earthquakes have indicated that the design and construction of bridges based on former seismic design provisions are susceptible to fatal collapse triggered by the failure of reinforced concrete columns. This paper incorporates an experimental investigation into the seismic response of nonductile bridge piers strengthened with low-cost glass fiber reinforced polymers (LC-GFRP). Three full-scale bridge piers were tested under lateral cyclic loading. A control bridge pier was tested in the as-built condition and the other two bridge piers were experimentally tested after strengthening them with LC-GFRP jacketing. The LC-GFRP strengthening was performed using two different configurations. The control bridge pier showed poor seismic response with the progress of significant cracks at very low drift levels. Test results indicated the efficiency of the tested strengthening configurations to improve the performance of the strengthened bridge piers including crack pattern, yield, and ultimate cyclic load capacities, ductility ratio, dissipated energy capacity, initial stiffness degradation, and fracture mode.

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Authors and Affiliations

K. Rodsin
Q. Hussain
P. Joyklad
A. Nawaz
H. Fazliani
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Abstract

The article presents the results of research concerning the effect of anthracite dust with 10%, 20%, 30%, 40% and 50% content in composites with a polypropylene matrix on selected properties. Hardness was examined with the Shore’s D method; stiffness, tensile strength as well as (MFR) Melt Flow Rate and (MVR) Melt Volume Rate of the investigated material were evaluated; wettability of the obtained material was also determined. Surface and volume resistivity were also investigated; the thermal properties of the filler were determined by thermogravimetric analysis (TGA). It was found that the investigated polypropylene composites filled with anthracite dust are hydrophobic materials and the composite hardness and stiffness are growing along with the volumetric increase of anthracite. It was noted that anthracite reinforces the material to a limited extent.

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Authors and Affiliations

M. Polok-Rubiniec
A. Włodarczyk-Fligier
B. Chmielnicki
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Abstract

Mechanical properties of FRP such as strength and stiffness as well as the bonding interface between FRP and concrete will be badly deteriorated when exposed to high temperature. Furthermore, the effect of thickness of insulation with different type of concrete strength has not yet been studied elsewhere in numerical studies. Therefore, this study is to assess the thermal-structural behaviour of insulated FRP strengthened RC beam exposed to elevated temperature using ABAQUS. The proposed numerical model of 200 ×300 mm RC beam subjected to 2 hours standard fire curve (ISO 834) had been validated with the analytical solution. The validated numerical model then is used in parametric study to investigate the behaviour of fire damaged normal strength concrete (40 MPa) and high strength concrete (60 MPa) of RC beam strengthened with CFRP using various fire insulation thickness of 12.5 mm, 25 mm and 40 mm, respectively. The result of steel characteristic strength reduction factor is compared with analytical using 500˚C Isotherm methods. The parametric studies indicated that the fire insulation layer is essential to provide fire protection to the CFRP strengthened RC beams when exposed to elevated temperature. The insulation layer thickness of 25 mm had been found to be the optimum thickness to be used as it is able to meet the criteria of temperature distribution and displacement requirement. In conclusion, the numerical model developed using ABAQUS in this study is to carry out assessment on the thermal-structural behaviour of the insulated CFRP-strengthened RC beams at elevated temperature.
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Authors and Affiliations

Ng Chee Keong
1
ORCID: ORCID
Mariyana Aida Ab Kadir
2 3
ORCID: ORCID
Nurizaty Zuhan
2
ORCID: ORCID
Muhammad Najmi Mohamad Ali Mastor
4
ORCID: ORCID
Mohd Nur Asmawisham Alel
5
ORCID: ORCID

  1. Public Work Department, Jalan Sultan Salahuddin, 50582 Kuala Lumpur, Malaysia
  2. School of Civil Engineering, University Teknologi Malaysia, 81310 Skudai, Johor Bahru, Johor, Malaysia
  3. Institute of Noise and Vibration, University Teknologi Malaysia, 81310 Skudai, Johor Bahru, Johor, Malaysia
  4. Candidate, School of Civil Engineering, University Teknologi Malaysia, 81310 Skudai, Johor Bahru, Johor, Malaysia
  5. Engineering Seismology and Earthquake Engineering Research (eSEER), Institute of Noise and Vibration, Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru, Johor, Malaysia
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Abstract

Nondestructive and contactless online approaches for detecting defects in polymer films are of significant interest in manufacturing. This paper develops vision-based quality metrics for detecting the defects of width consistency, film edge straightness, and specks in a polymeric film production process. The three metrics are calculated from an online low-cost grayscale camera positioned over the moving film before the final collection roller and can be implemented in real-time to monitor the film manufacturing for process and quality control. The objective metrics are calibrated to correlate with an expert ranking of test samples, and results show that they can be used to detect defects and measure the quality of polymer films with satisfactory accuracy.
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Authors and Affiliations

Nathir Rawashedeh
1 2
ORCID: ORCID
Paniz Hazaveh
1
Safwan Altarazi
2
ORCID: ORCID

  1. Michigan Technological University, College of Computing, USA
  2. German Jordanian University, School of Applied Technical Sciences, Jordan
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Abstract

Asphalt mixtures are commonly used for the pavement construction for national roads with a high traffic load, as well as local roads with low traffic load. The constructions of local road pavement consisting of thinner, more flexible layers located on less stable subbase than the pavement of national roads, require reinforcement with asphalt layers characterized by increased fatigue life. Technologies that allow quick repairs and reinforcements, while improving the durability of the road pavement are being sought. Such technologies include the use of modifications of asphalt mixtures with special fibers. The paper presents the results of investigations of the properties of asphalt mixtures modified with innovative basalt-polymer fibers FRP. On the basis of the obtained test results according to the Marshall method, stiffness modulus and fatigue durability, the technical properties of asphalt mixtures with FRP fibers addition were improved. This technology significantly increases the fatigue life of asphalt concrete dedicated for repairs and reinforcements of road pavements.

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Authors and Affiliations

P. Radziszewski
M. Sarnowski
A. Plewa
P. Pokorski
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Abstract

Recently, new materials have been developed in the field of bridge design, one of which is FRP composite. To investigate this topic, the Polish National Centre for Research and Development has founded a research project, whose objectives are to develop, manufacture and test a typical FRP bridge superstructures. Two innovative ideas of FRP composite girder-deck structural systems for small and medium span bridges have been proposed. This paper describes the demonstrative bridges and presents the research results on their development and deployment. The finite element analysis and design procedure, structural evaluation in the laboratory and some results of the proof tests carried out on both bridge systems have been briefly presented.

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Authors and Affiliations

T. Siwowski
M. Kulpa
M. Rajchel

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