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Abstract

This paper analyses the possibility of applying thermal barrier coatings (TBCs) onto a substrate made of the AlSi7Mg alloy, intended for, among other things, internal combustion engine components. Engine components made of aluminum-silicon alloys, especially pistons and valve heads, are exposed to high temperature, pressure and thermal shock resulting from the combustion of the fuel-air mixture. These factors cause degradation of these components and can lead to damage. To minimize the risk of damage to engine components caused by heat stress, one way is to apply TBCs. Applying TBCs coatings to engine components improves their durability, increases power output and reduces fuel consumption. The research scope includes the application of an Al2O3-TiO3 coating via the APS (Air Plasma Spraying or Atmospheric Plasma Spraying) method onto a substrate of the AlSi7Mg alloy, analysis of the microstructure and chemical composition of the substrate and coating material, and assessment of the quality of the coating's bond with the AlSi7Mg alloy substrate using the scratch test method.
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Bibliography

[1] Chen, C., Sun, C., Wang, W., Qi, M., Han, W., Li, Y., Liu, X., Yang, F., Gou, L. & Guo, Z. (2022). Microstructure and mechanical properties of in-situ TiB2/AlSi7Mg composite via powder metallurgy and hot extrusion. Journal of Materials Research and Technology. 19, 1282-1292. https://doi.org/10.1016/j.jmrt.2022.05.117.
[2] Rambabu, P., Eswara Prasad, N., Kutumbarao, V.V., Wanhill, R.J.H. (2017). Aluminium Alloys for Aerospace Applications. In: Prasad, N., Wanhill, R. (eds) Aerospace Materials and Material Technologies . Indian Institute of Metals Series. Springer, Singapore. https://doi.org/10.1007/978-981-10-2134-3_2.
[3] Sonsino, C.M. & Franz, R. (2017). Multiaxial fatigue assessment for automotive safety components of cast aluminium EN AC-42000 T6 (G-AlSi7Mg0. 3 T6) under constant and variable amplitude loading. International Journal of Fatigue. 100(2), 489-501. https://doi.org/10.1016/j.ijfatigue.2016.10.027.
[4] Dolata, A.J., Dyzia, M., Jaworska, L. & Putyra, P. (2016). Cast hybrid composites designated for air compressor pistons. Archives of Metallurgy and Materials. 61(2A), 705-708. http://dx.doi.org/10.1515%2Famm-2016-0120.
[5] Siadkowska, K. & Czyż, Z. (2019). Selecting a material for an aircraft diesel engine block. Combustion Engines. 58(3), 4-8. DOI: http://dx.doi.org/10.19206/CE-2019-301.
[6] Floweday, G., Petrov, S., Tait, R.B. & Press, J. (2011). Thermo-mechanical fatigue damage and failure of modern high performance diesel pistons. Engineering Failure Analysis. 18(7), 1664-1674. https://doi.org/10.1016/j.engfailanal.2011.02.002.
[7] Azadi, M., Mafi, A., Roozban, M. & Moghaddam, F. (2012). Failure analysis of a cracked gasoline engine cylinder head. Journal of Failure Analysis and Prevention. 12, 286-294. https://doi.org/10.1007/s11668-012-9560-6.
[8] Krstic, B., Rasuo, B., Trifkovic, D., Radisavljevic, I., Rajic, Z. & Dinulovic, M. (2013). Failure analysis of an aircraft engine cylinder head. Engineering Failure Analysis. 32, 1-15. https://doi.org/10.1016/j.engfailanal.2013.03.004.
[9] Jing, G.X., Zhang, M.X., Qu, S., Pang, J.C., Fu, C.M., Dong, C., Li, S. X., Xu, C.G. & Zhang, Z.F. (2018). Investigation into diesel engine cylinder head failure. Engineering Failure Analysis. 90, 36-46. https://doi.org/10.1016/j.engfailanal.2018.03.008.
[10] Sharma, P., Dwivedi, V.K. & Kumar, D. (2021). A review on thermal barrier coatings (TBC) usage and effect on internal combustion engine. Advances in Fluid and Thermal Engineering: Select Proceedings of FLAME 2020, 77-85. https://doi.org/10.1007/978-981-16-0159-0_8.
[11] Dhomne, S. & Mahalle, A.M. (2019). Thermal barrier coating materials for SI engine. Journal of materials research and technology. 8(1), 1532-1537. https://doi.org/10.1016 /j.jmrt.2018.08.002.
[12] Gürbüz, H. (2022). Experimental investigation of the effects of ethanol‐diesel mixture on the performance and emissions of the thermal barrier coated diesel engine. Environmental Progress & Sustainable Energy. 41(1), e13718. https://doi.org/10.1002/ep.13718.

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Authors and Affiliations

Marek Mróz
ORCID: ORCID
Patryk Rąb
ORCID: ORCID

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Abstract

This paper presents the possibility of improving the scratch resistance of the AZ91 magnesium alloy by applying a WCCoCr coating using the Air Plasma Spraying (APS) method. The coating thickness ranged from 140 to 160 m. Microstructural studies of the AZ91 magnesium alloy were performed. The chemical composition of the WCCoCr powder was investigated. The quality of the bond at the substrate–coating interface was assessed and a microanalysis of the chemical composition of the coating was conducted. The scratch resistance of the AZ91 alloy and the WCCoCr coating was determined. The scratch resistance of the WCCoCr powder-based coating is much higher than the AZ91 alloy, as confirmed by scratch geometry measurements. The scratch width in the coating was almost three times smaller compared to the scratch in the substrate. Observations of the substrate–coating interface in the scratch area indicate no discontinuities. The absence of microcracks and delamination at the transition of the scratch from the substrate to the coating indicates good adhesion. On the basis of the study, it was found that there was great potential to use the WCCoCr powder coating to improve the abrasion resistance of castings made from the AZ91 alloy.
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Bibliography

[1] Wanhill, R.J.H. (2017). Carbon fibre polymer matrix structural composites. Aerospace Materials and Material Technologies. 1, 309-341. https://doi.org/10.1007/978-981-10-2134-3_14.
[2] Dziadoń, A. & Mola, R. (2013). Magnesium – directions of shaping mechanical properties. Obróbka plastyczna Metali. XXIV(4). (in Polish).
[3] Mordike, B.L. & Ebert, T. (2001). Magnesium: Properties – application – potential. Materials Science and Engineering. 302(1), 37-45. DOI: 10.1016/S0921-5093(00)01351-4.
[4] Wang, G.G. & Weiler, J.P. (2023). Recent developments in high pressure die-cast magnesium alloys for automotive and future applications. Journal of Magnesium and Alloys. 11(1), 78 87. DOI: doi.org/10.1016/j.jma.2022.10.001.
[5] Liu, B., Yang, J., Zhang, X., Yang, Q., Zhang, J., Li, X. (2022). Development and application of magnesium alloy parts for automotive OEMs: A review. Journal of Magnesium and Alloys. 11(1), 15-47. DOI: 10.1016/j.jma.2022.12.015.
[6] Janik, B. (2011). Application of magnesium alloys in aviation. Prace Instytutu Lotnictwa. 57(221), 102-108. (in Polish).
[7] Prasad, S.V.S., Prasad, S.B., Verma, K., Mishra, R.K., Kumar, V. & Singh, S. (2021). The role and significance of Magnesium in modern day research – A review. Journal of Magnesium and alloys. 10(1), 1-61. DOI: 10.1016/j.jma.2021.05.012.
[8] Blawert, C., Hort, N. & Kainer, K.U. (2004). Automotive applications of magnesium and its alloys. Transaction of the Indian Institute of Metals. 57(4), 397-408.
[9] Chen, H. & Alpas A.T. (2000). Sliding wear map for the magnesium alloy Mg-9Al-0.9Zn (AZ91). Wear. 246(1-2), 106-116. DOI: 10.1016/S0043-1648(00)00495-6.
[10] Walczak, M., Caban, J. & Pliżga, P. (2015). Tribological characteristic of magnesium alloys used in means of transport. TTS Technika Transportu Szynowego. 22(12), 1614-1617.
[11] Parco, M., Zhao, L., Zwick, J., Bobzin, K. & Lugscheider, E. (2007). Investigation of particle flattening behaviour and bonding mechanisms of APS sprayed coatings on magnesium alloys. Surface and Coating Technology. 201(14), 6290-6296. DOI: 10.1016/j.surfcoat.2006.11.034.
[12] Morelli, S., Rombol`a, G., Bolelli, G., Lopresti, M., Puddu, P, Boccaleri, E., Seralessandri, L., Palin, L., Testa, V., Milanesio, M. & Lusvarghi, L. (2022). Hard ultralight systems by thermal spray deposition of WC-CoCr onto AZ31 magnesium alloy. Surface and Coating Technology. 451, 129056 1-26. DOI.org/10.1016/j.surfcoat.2022.129056.
[13] Gray, J.E. & Luan, B. (2002). Protective coatings on magnesium and its alloys – a critical review. Journal of Allys and Compounds. 336(1-2), 88-113. DOI: 10.1016/S0925 8388(01)01899-0.
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Authors and Affiliations

Marek Mróz
1
ORCID: ORCID
Sylwia Olszewska
1
ORCID: ORCID
Patryk Rąb
1
ORCID: ORCID

  1. Rzeszow University of Technology, Poland
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Abstract

The paper presents results of a study on the effect of passage of time on magnesium content in iron alloys and the effect of magnesium content on the number of vermicular graphite precipitations per unit surface area and value of the longitudinal ultrasonic wave velocity for two different vermicularization methods. The study was carried out with the use of inspection bar castings. For specific production conditions, it has been found that in case of application of both the cored wire injection method and the method of pouring liquid metal over magnesium master alloy on ladle bottom, the satisfactory level of magnesium content in the bottom-pour ladle, for which it was still possible to obtain castings with vermicular graphite, was 0.018% Mg. In case of the cored wire injection method, the “time window” available to a pouring station at which castings of vermicular cast iron are expected to be obtained, was about 5 minutes. This corresponds to the longitudinal ultrasonic wave velocity values exceeding 5500 m/s and the number of graphite precipitations per unit surface area above 320 mm–2. In case of the master alloy method, the respective “time window” allowing to obtain castings of vermicular cast iron was only about 3 minutes long. This corresponds to the longitudinal ultrasonic wave velocity value above 5400 m/s and the number of graphite precipitations per unit surface area above 380 mm–2.

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Authors and Affiliations

M. Tupaj
ORCID: ORCID
A.W. Orłowicz
ORCID: ORCID
Marek Mróz
ORCID: ORCID
B. Kupiec
D. Pająk
M. Kawiński
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Abstract

The paper presents results of a study concerning an AlSi7Mg alloy and the effect of subjecting the liquid metal to four different processes: conventional refining with hexachloroethane; the same refining followed by modification with titanium, boron, and sodium; refining by purging with argon carried out in parallel with modification with titanium and boron salts and strontium; and parallel refining with argon and modification with titanium, boron, and sodium salts. The effect of these four processes on compactness of the material, parameters of microstructure, and fatigue strength of AlSi7Mg alloy after heat treatment. It has been found that the highest compactness (the lowest porosity ratio value) and the most favorable values of the examined parameters of microstructure were demonstrated by the alloy obtained with the use of the process including parallel purging with argon and modification with salts of titanium, boron, and sodium. It has been found that in the fatigue cracking process observed in all the four variants of the liquid metal treatment, the crucial role in initiation of fatigue cracks was played by porosity. Application of the process consisting in refining by purging with argon parallel to modification with Ti, B, and Na salts allowed to refine the microstructure and reduce significantly porosity of the alloy extending thus the time of initiation and propagation of fatigue cracks. The ultimate effect consisted in a distinct increase of the fatigue limit value.

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Authors and Affiliations

M. Tupaj
ORCID: ORCID
A.W. Orłowicz
ORCID: ORCID
A. Trytek
ORCID: ORCID
Marek Mróz
ORCID: ORCID
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Abstract

The paper presents the assumptions and methodology for investigating equivalent heat load testing of hot aircraft engine components. The basic heat loads occurring in an aircraft engine during aircraft flight are characterised. Diagrams of the proposed heat loads are presented, together with the number of cycles, and a test bench is characterised and shown to enable equivalent heat load testing of aircraft engine components.
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Bibliography

[1] Hejwowski, T., Weroński, A. (2000). Manufacture of wear-resistant coatings. Lublin: Politechnika Lubelska. (in Polish).
[2] Research stand in WSK PZL Rzeszów.
[3] Chaur, - Jeng Wang, & Jiaun, - Sheng Lin (2002). The oxidation of MAR M247 superalloy with Na2SO4 coating. Materials Chemistry and Physics. 76, 123-129. DOI: 10.1016/S0254-0584(01)00527-2.
[4] Goebel, J.A., Petit, F.S. & Howard, G.W. (1973). Mechanism for the hot corrosion of nickel base alloys. Metallurgical Transactions. 4, 261-270. https://doi.org/10.1007/BF02649626.
[5] Su, C.Y., Lih, W.C., Chou, C.P. & Tsai, H.C. (2001). Activated diffusion brased repair for IN 738 hot section components of gas turbine. Journal of Materials Processing Technology. 115(3), 326-332.

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Authors and Affiliations

Marek Mróz
ORCID: ORCID
A.W. Orłowicz
1
ORCID: ORCID
M. Tupaj
1
ORCID: ORCID
M. Lenik
1
ORCID: ORCID

  1. Rzeszow University of Technology, Al. Powstańców Warszawy 12, 35-959 Rzeszów, Poland
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Abstract

The objective of the study reported in this paper was to determine the effect of structure on thermal power of cast-iron heat exchangers which in this case were furnace chambers constituting the main component of household fireplace-based heating systems and known commonly as fireplace inserts. For the purpose of relevant tests, plate-shaped castings were prepared of gray iron with flake graphite in pearlitic matrix (the material used to date typically for fireplace inserts) as well as similar castings of gray cast iron with vermicular graphite in pearlitic, ferritic-pearlitic, and ferritic matrix. For all the cast iron variants of different structures (graphite precipitate shapes and matrix type), calorimetric measurements were carried out consisting in determining the heat power which is quantity representing the rate of heat transfer to the ambient environment. It has been found that the value of the observed heat power was affected by both the shape of graphite precipitates and the type of alloy matrix. Higher thermal power values characterize plate castings of gray iron with vermicular graphite compared to plates cast of the flake graphite gray iron. In case of plates made of gray cast iron with vermicular graphite, the highest values of thermal power were observed for castings made of iron with ferritic matrix.

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Authors and Affiliations

Marek Mróz
ORCID: ORCID
A.W. Orłowicz
ORCID: ORCID
M. Tupaj
ORCID: ORCID
M. Jacek-Burek
M. Radoń
M. Kawiński
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Abstract

The study presented in this paper concerned the possibility to apply a heat treatment process to ductile cast-iron thin-walled castings in order to remove excessive quantities of pearlite and eutectic cementite precipitates and thus meet the customer’s requirements. After determining the rates of heating a casting up to and cooling down from 900°C feasible in the used production heat treatment furnace (vh = 300°C/h and vc = 200°C/h, respectively), dilatometric tests were carried out to evaluate temperatures Tgr, TAc1start, TAc1end, TAr1start, and TAr1end. The newly acquired knowledge was the base on which conditions for a single-step ferritizing heat treatment securing disintegration of pearlite were developed as well as those of a two-step ferritization process guaranteeing complete disintegration of cementite and arriving at the required ferrite and pearlite content. A purely ferritic matrix and hardness of 119 HB was secured by the treatment scheme: 920°C for 2 hours / vc = 60°C/h / 720°C for 4 hours. A matrix containing 20–45% of pearlite and hardness of 180–182 HB was obtained by applying: 920°C for 2 hours or 4 hours / vc = 200°C/h to 650°C / ambient air.

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Authors and Affiliations

Marek Mróz
ORCID: ORCID
A.W. Orłowicz
ORCID: ORCID
M. Tupaj
ORCID: ORCID
B. Kupiec
M. Kawiński
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Abstract

The paper presents the results of calorimetric tests of segment elements of fireplace inserts. The aim of the work was to optimize their thermal power by replacing the previously used gray cast iron with flake graphite with gray iron with vermicular graphite and replacing the existing geometry of the heat transfer surface with a more developed one. It turned out that the thermal power of the test segments made of cast iron with vermicular graphite was higher compared to the segments of the same shape made of gray cast iron with flake graphite. It was found that the use of segments made of vermicular cast iron with a ferritic matrix allowed for an increase in the thermal power value by dozen percent, compared to segments of the same shape made of vermicular cast iron with a pearlitic matrix. The test results showed that the thermal power of the test segments depends on the variant of the development of both the heat receiving surface and the heat giving off surface. The highest value of the thermal power was obtained when ribbing in the form of a lattice was used on both of these surfaces, and the lowest when using flat surfaces.
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Bibliography

[1] Directive (2005/32/EC) EUPS Eco-design.
[2] European energy policy (2007). Bruksela 10.02.2007, COM 2007.
[3] Kubica, K. (2010). Conditions for cleaner combustion of solid fuels in domestic thermal energy production installations. Gliwice: Projekt FEWE.
[4] Research report no. 317OA314 (2014). Built-in fireplace insert for solid fuel. Performance tests. Kraków: Instytut Nafty i Gazu. Zespół Laboratoriów Badawczych Sieci, Instalacji i Urządzeń Gazowych. (in Polish).
[5] Podrzucki, Cz., Wojtysik A. (1988). Plastic unalloyed cast iron. Kraków: Part II, AGH Kraków. (in Polish).
[6] Holmgren, D., Dioszegi, A. & Svensson, I.L. (2008). Effect of carbon content and solidification rate on the thermal conductivity of grey cast iron. Tsinghua Science and Technology. 13(2), 170-176.
[7] Greig, G. (1996). Modern ingot mould production. 33 I.F.C., Paper No. 12, New Delhi.
[8] Kinal, G. & Paczkowska M. (2002). The comparison of grey cast irons in the aspects of the possibility of their laser heat treatment. Journal of Research and Applications in Agricultural Engineering. 57(1), 7376.
[9] Dobrzański, L.A. (2000). A lexicon of materials science. Verlag Dashofer, version 1.03.2000 .
[10] Monroe, R.W. & Bates, C.E. (1982). Some thermal and mechanical properties of compacted graphite iron. AFS Trans. 90, 615-619.
[11] Orłowicz, A.W. (2000). Ultrasonic method in foundry industry. Solidification of Metals and Alloys. 2(45). (in Polish).
[12] Mróz, M., Orłowicz, A.W., Tupaj, M., Jacek-Burek, M., Radoń, M., Kawiński, M. (2019). Improvement of operating performance of a cast-iron heat exchanger by application of a copper alloy coating. Archives of Foundry Engineering. 19(3), 84-87.
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Authors and Affiliations

Marek Mróz
ORCID: ORCID
A.W. Orłowicz
1
ORCID: ORCID
M. Tupaj
1
ORCID: ORCID
M. Lenik
1
ORCID: ORCID
M. Kawiński
2
M.. Kawiński
2

  1. Rzeszow University of Technology, Al. Powstańców Warszawy 12, 35-959 Rzeszów, Poland
  2. Cast Iron Foundry KAWMET, ul. Krakowska 11, 37-716 Orły, Poland
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Abstract

The application of ferritic-matrix vermicular graphite cast iron in the production of fireplace fireboxes improves their thermal output, but the consumer market for these products prioritises their price. Given this consideration, this work concerns a comparison of the quality of vermicular graphite cast iron types produced from 0.025%S pig iron (a less expensive material) and 0.010%S pig iron (a more expensive material) in terms of the number and shape of vermicular graphite precipitates varying with the magnesium level in the alloy. It turned out that the vermicular graphite cast iron made with the 0.025%S pig iron demonstrated a slightly lower number of vermicular graphite precipitates. For both vermicular graphite cast iron melts, 0.028%Mg and 0.020%Mg in the alloys provided a vermicular graphite precipitate share of approx. 50% and 95%, respectively.
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Bibliography

[1] Mróz, M., Orłowicz, A.W., Tupaj, M., Lenik, M., Kawiński, M., Kawiński, M. Influence of microstructure and heat transfer surface on the thermal power of cast iron heat exchangers. Archives of Foundry Engineering. (in progres).
[2] Podrzucki, C., Wojtysiak, A. (1987). Unalloyed plastic cast iron. Kraków: Wyd. AGH. ( in Polish).
[3] Sillen, R. (2003). Proces PQ-CGL InMold – cast iron vermicularization in mold. Biuletyn Metals and Minerals. 3, 30-34. (in Polish).
[4] Källbom, R., Hamberg, K., Björkegren, L.S. Chunky graphite in ductile cast iron castings. World Foundry Congress, 184/1-184/10, WFC 06.
[5] Goodrich, G.M. (2001). A microview of some factors that impact cast iron (or the little things that mean a lot). AFS Transactions. 01-121, 1173-1189.
[6] Pietrowski, S., Pisarek, B., Władysiak, R. (2000). Investigation of the crystallization of cast iron with vermicular graphite and description of its analytical and numerical model. Research project KBN Nr 7T08B 006 13, Łódź, (in Polish).
[7] Żyrek, A. (2014). Manufacture of vermicular cast iron by the Inmould method with the use of magnesium mortars and evaluation of its resistance to thermal fatigue. PhD thesis AGH Kraków. (in Polish).
[8] Nodżak, G. (2002). Analysis of the possibilities produced in the foundry of WSK "PZL Rzeszów" S.A. castings of a high-power diesel engine head from vermicular cast iron. Master thesis, AGH Kraków. (in Polish).
[9] Orłowicz A.W. (2000). The use of ultrasound in foundry. Monograph. Krzepnięcie Metali i Stopów. 2(45). (in Polish).
[10] Ashby, M.F. (1998). Selection of materials in engineering design. Warszawa: Wyd. Naukowo-Techniczne. (in Polish).

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Authors and Affiliations

Marek Mróz
ORCID: ORCID
A.W. Orłowicz
1
ORCID: ORCID
M. Tupaj
1
ORCID: ORCID
M. Lenik
1
ORCID: ORCID
M. Kawiński
2
M.. Kawiński
2

  1. Rzeszow University of Technology, Al. Powstańców Warszawy 12, 35-959 Rzeszów, Poland
  2. Cast Iron Foundry KAWMET, ul. Krakowska 11, 37-716 Orły, Poland

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