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Kinetics of the Binding Process of Furan Moulding Sands, Under Conditions of Forced Air Flow, Monitored by the Ultrasonic Technique

Natalia Matonis

Archives of Foundry Engineering | 2023 | vol. 23 | No 4 | 93-98 | DOI: 10.24425/afe.2023.146683

Keywords Self-hardening moulding sands Air flow Permeability Degree of hardening Ultrasound

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Abstract

The paper presents the results of research on the kinetics of the binding process of self-hardening moulding sands with an organic binder under conditions of forced air flow at various pressure values. Three moulding sands made using urea-furfuryl resin Furanol FR75A technology were studied. The moulding sands were prepared on a base of quartz sand with an average grain size of dL = 0.25, 0.29 and and 0.37 mm , with permeability values of 306 , 391 and and 476 m ²/10 ⁸Pa ∙ s (for ρ0 = 1.60 , 1.60 and and 1.61 g/cm ³, respectively). The research was conducted for a resin content of 1% with a constant proportion of hardener to resin, which was equal to 50%. Samples of the tested moulding sands were blown with air at pressures of 0.1, 0.2, 0.4, 0.6, 0.8, and 1.0 bar. The kinetics of the hardening process was monitored using ultrasound technology, according to a previously developed methodology [1]. The research was carried out on an ultrasound testing station equipped with a temperature chamber and an airflow reducer. The tests were conducted at a temperature of 20°C, and of the air flow pressure on the changes in ultrasonic wave velocity in the hardening mouldins sand as a function of time, the kinetics of the hardening process, and the degree of moulding sand hardening were determined. Additionally, the influence of the moulding sand permeability on the course of the hardening process at a constant air flow pressure was determined.

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Bibliography

[1] Zych, J. (2007). Synthesis of the applications of ultrasonic technology in the analysis of the kinetics of selected processes occurring in molding materials. AGH Uczelniane Wydawnictwa Naukowo-Dydaktyczne. Seria: Rozprawy i Monografie nr 163, Kraków. (in Polish).
[2] Holtzer, M., Kmita, A. & Roczniak, A. (2014). New furfuryl resins more environmentally friendly. Archives of Foundry Engineering. 14(spec.4), 51-54. (in Polish).
[3] Lewandowski, J.L. (1997). Materials for casting molds. Kraków: Wydawnictwo Akapit. (in Polish).
[4] Lewandowski, J.L (1971). Molding materials. Warszawa: Wydawnictwo Naukowe PWN. (in Polish).
[5] Dobosz, St.M. (2006). Water in molding and core sands. Kraków: Wydawnictwo Akapit. (in Polish).
[6] Drożyński, D. (1999). Post-surface phenomena in the process of binding masses in the classic cold-box technology. Unpublished doctoral dissertation, AGH Univesity of Science and Technology, Kraków. (in Polish).
[7] Lewandowski, J.L. (1991). Molding and core sands. Warszawa: Wydawnictwo Naukowe PWN. (in Polish).
[8] Jamrozowicz, Ł., Kolczyk, J. & Kaźnicva, N. (2016). Study of the hardening kinetics of self-hardening masses at low temperature. Prace Instytutu Odlewnictwa. LVI, 4/2016, 379-390. (in Polish).
[9] Matonis, N. & Zych, J. (2022). Plasticity changes of moulding sands with chemical binders caused by increasing the hardenin degree. Archives od Foundry Engineering. 22(2), 71-76. DOI: 10.24425/afe.2022.140227.
[10] Zych, J. (1999). Patent Nr PL 192202 B1. Kraków

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Authors and Affiliations

Natalia Matonis

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ORCID:

AGH University of Science and Technology, Faculty of Foundry Engineering, Poland

The Effect of Reclaim Primary Quality on Moulding Sand Parameters and Quality of Ductile Iron Casting Surface Layer

J. Kamińska M. Angrecki S. Puzio M. Stachowicz

Archives of Foundry Engineering | 2022 | vol. 22 | No 2 | 83-88 | DOI: 10.24425/afe.2022.140229

Keywords Foundry industry Furfuryl resin Reclaim Self-hardening moulding sand Surface quality

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Abstract

The aim of the research was to determine the effect of the primary quality of reclaim from dry mechanical reclamation on the strength properties and service life of moulding sands based on this reclaim. Another aim was to establish the effect of the quality of reclaim, sulphur content - in particular, on the surface quality and thickness of the deformed surface layer in ductile iron castings. The research has revealed differences in the strength parameters and service life (mouldability) of sands based on the tested reclaims, depending on the type of the furfuryl resin used, including resins whose synthesis was done as part of the Żywfur project. Examinations of the structure of the surface layer of test castings poured in moulds made of loose self-hardening sands containing the addition of reclaim have confirmed the occurrence of degenerated spheroidal graphite in this part of the casting. It should be noted here that when massive castings with a long solidification time are made, the graphite degeneration effect can be more visible and the layer with the changed structure can increase in thickness. The research has clearly shown that it is necessary to control the parameters of the reclaim, including sulphur content which is transferred from the hardener and accumulates on the grains. This phenomenon has a negative impact not only on the sand strength and technological properties but also on the surface layer of castings.

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Bibliography

[1] Lewandowski, J.L. (1997). Materials for foundry moulds. Kraków: WN Akapit. ISBN: 83-7108-21-2 (in Polish).
[2] Kamińska, J., Puzio, S., Angrecki, M., Stachowicz, M. & Łoś, A. (2019). Preliminary tests of innovative eco-friendly furfuryl resins and foundry sand mixtures based on these resins. Journal of Ecological Engineering. 20(9), 285-292, DOI: 10.12911/22998993/112510.
[3] Acharya, S.G., Vadher, J.A. & Kanjariya, P.V. (2016). Identification and quantification of gases releasing from furan no bake binder. Archives of Foundry Engineering. 16(3), 5-10. DOI: 10.1515/afe-2016-0039.
[4] Chate, G.R., Patel, GC M., Deshpande, A.S. & Parappagoudar, M.B. (2018). Modeling and optimization of furan moulding sand system using design of experiments and particle swarm optimization. Journal of Process Mechanical Engineering. 232(5), 1-20. DOI: 10.1177/0954408917728636.
[5] Sappinen, T., Orkas, J. & Konqvist, T. (2018). Thermal Reclamation of Foundry Sands Using Repurposed Sand Dryer Equipment. Archives of Foundry Engineering. 18(4), 99-102. DOI: 10.24425/afe.2018.125176.
[6] Kamińska, J., Puzio, S., Angrecki, M. & Łoś, A. (2020). Effect of reclaim addition on the mechanical and technological properties of moulding sands based on pro-ecological furfuryl resin. Archives of Metallurgy and Materials. 65(4), 1425-1429. DOI: 10.24425/amm.2020.133709.
[7] Yan-lei, L., Guo-hua, W., Wen-cai, L., An-tao, C., Liang, Z. & Ying-xin Wang, W. (2017). Effect of reclaimed sand additions on mechanical properties and fracture behavior of furan no-bake resin sand. China Foundry. 14(2), 128-137. DOI: 10.1007/s41230-017-6024-3.
[8] Holtzer, M., Dańko, R., Kmita, A., Drożyński, D., Kubecki, M., Skrzyński, M. & Roczniak, A. (2020). Environmental impact of the reclaimed sand addition to moulding sand with furan and phenol-formaldehyde resin—A comparison, Materials. 13(19), 4395; DOI: https://doi.org/10.3390/ma13194395.
[9] Holtzer, M., Dańko, R. & Kmita, A. (2016). Influence of a reclaimed sand addition to moulding sand with furan resin on its impact on the environment. Water Air and Soil Pollution. 227(16), 1-12. DOI: 10.1007/s11270-015-2707-9.
[10] Hosadyna, M. (2012). The effect of sulphur contained in self-hardening moulding sands on the structure of surface layer in ductile iron castings. Doctoral dissertation, Kraków. (in Polish).
[11] Holtzer, M., Zych, J. & Retel, K. (1996). The effect of mould-liquid cast iron interaction on the surface quality of castings. Przegląd Odlewnictwa. 6(1996), 129-134. (in Polish).
[12] Riposan, I., Chisamera, M., Stan, S., Skaland, T. (2008). Surface graphite degeneration in ductile iron castings for resin molds. Tsinghua Science and Technology. 13(2), 157-163.
[13] Linke, T., Sluis, J.R. (1993). The influence of coatings on the graphite structure in the rim-zone of ductile iron castings. 60th World Foundry Congress, The Netherlands
[14] Hosadyna, M., Dobosz, St.M. & Jelinek, P. (2009). The diffusion of sulphur from moulding sand to cast and methods of its elimination. Archives of Foundry Engineering. 9(4), 73-76.
[15] Sheladiya, M.V., Acharya, S.G., Mehta, K., Acharya, G.D. (2019). Evaluate sulphur diffusion at mould-metal interface in no-bake mould system. Archives of Foundry Engineering. 19(1), 63-70. DOI: 10.24425/afe.2018.125193.
[16] Anca, D., Stan, I., Chisamera, M., Riposan, I. & Stan, S. (2021). Experimental study regarding the possibility of blocking the diffusion of sulfur at casting-mold interface in ductile iron castings. Coatings. 11(673), 1-10. DOI: https://doi.org/10.3390/coatings11060673.
[17] Dańko, J., Dańko, R. & Łucarz, M. (2007). Processes and devices for the matrix regeneration of spent molding sands. Kraków: WN Akapit. ISBN: 978-83-89541-88-8 (in Polish).
[18] Holtzer, M., Bobrowski, A., Drożyński, D., Isendorf, B., Mazur, (2012). Influence of the reclaim on the properties of moulding sands with furfuryl resin applied for moulds for manganese steel castings. Archives of Foundry Engineering. 12(1), 57-62.
[19] Dańko, R., Górny, M., Holtzer, M., Żymankowska-Kumon, S. (2014). Effect of the quality of furan moulding sand on the skin layer of ductile iron castings. ISIJ International. 54(6), 1288-1293. DOI: https://doi.org/10.2355/isijinternational.54.1288.
[20] Pałyga, Ł., Stachowicz, M., Granat, K. (2015). Evaluation of 2D and 3D surface roughness of die castings from alloy AlSi9Cu3. Archives of Foundry Engineering. 15(1), 75-80.

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Authors and Affiliations

J. Kamińska

e-mail:

ORCID:

M. Angrecki

e-mail:

ORCID:

S. Puzio

e-mail:

ORCID:

M. Stachowicz

e-mail:

ORCID:

Łukasiewicz Research Network – Krakow Institute of Technology, Poland
Wroclaw University of Technology, Faculty of Mechanical Engineering, Poland

Prediction of Properties of Microwave- Hardened Sandmixes Containing Water- Glass with Use of Neural Networks

M. Stachowicz Ł. Pałyga K. Granat

Archives of Foundry Engineering | 2015 | No 2 | DOI: 10.1515/afe-2015-0047

Keywords Foundry engineering artificial neural networks Loose self-hardening moulding sand Water-glass microwaves

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Abstract

Presented are results of a research on the possibility of using artificial neural networks for forecasting mechanical and technological

parameters of moulding sands containing water-glass, hardened in the innovative microwave heating process. Trial predictions were

confronted with experimental results of examining sandmixes prepared on the base of high-silica sand, containing various grades of

sodium water-glass and additions of a wetting agent. It was found on the grounds of obtained values of tensile strength and permeability

that, with use of artificial neural networks, it is possible complex forecasting mechanical and technological properties of these materials

after microwave heating and the obtained data will be used in further research works on application of modern analytic methods for

designing production technology of high-quality casting cores and moulds.

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Authors and Affiliations

M. Stachowicz

Ł. Pałyga

K. Granat

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Kinetics of the Binding Process of Furan Moulding Sands, Under Conditions of Forced Air Flow, Monitored by the Ultrasonic Technique

Abstract

Bibliography

Authors and Affiliations

The Effect of Reclaim Primary Quality on Moulding Sand Parameters and Quality of Ductile Iron Casting Surface Layer

Abstract

Bibliography

Authors and Affiliations

Prediction of Properties of Microwave- Hardened Sandmixes Containing Water- Glass with Use of Neural Networks

Abstract

Authors and Affiliations