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Abstract

The mathematical model of the globular eutectic solidification in 2D was designed. Proposed model is based on the Cellular Automaton Finite Differences (CA-FD) calculation method. Model has been used for studies of the primary austenite and of globular eutectic grains growth during the ductile iron solidification in the thin wall casting. Model takes into account, among other things, non-uniform temperature distribution in the casting wall cross-section, kinetics of the austenite and graphite grains nucleation, and non-equilibrium nature of the interphase boundary migration. Calculation of eutectic saturation influence (Sc = 0.9 - 1.1) on microstructure (austenite and graphite fraction, density of austenite and graphite grains) and temperature curves in 2 mm wall ductile iron casting has been done.
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Authors and Affiliations

A.A. Burbelko
M. Górny
D. Gurgul
W. Kapturkiewicz
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Abstract

The paper presents the results of research related to the possibility of inoculation of the AZ91 magnesium alloy casted into ceramic moulds by gadolinium. Effects of gadolinium content (0.1–0.6 wt%) on microstructure of the AZ91 alloy under as-cast state were investigated. The influence of the inoculator on the formation of the microstructure investigated by means of the thermal and derivative analysis by analysing the thermal effects arising during the alloy crystallization resulting from the phases formed. The degree of fragmentation of the microstructure of the tested alloys was assessed by means of the light microscopy studies and an image analysis with statistical analysis was performed. Conducted analyses have aimed at examining on the effect of inoculation of the gadolinium on the differences between the grain diameters and average size of each type of grain by way of measuring their perimeters of all phases, preliminary αMg and eutectics αMg+γ(Mg17Al12) in the prepared examined material.
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Bibliography

[1] Wang, Y.N. & Huang, J.C. (2007). The role of twinning and untwining in yielding behavior in hot-extruded Mg-Al-Zn. Alloy Acta Materialia. 55(3), 897-905. DOI: 10.1016/ j.actamat.2006.09.010.
[2] Yu, Zhang et. al (2017). Effects of samarium addition on as-cast microstructure, grain fragmentation and mechanical properties of Mg-6Zn-0.4Zr magnesium alloy. Journal of Rare Earths. 167(1), 31-33. DOI: 10.1016/S1002-0721(17)60939-6.
[3] Cao, F.Y, Song, G.L. & Atrens, A. (2016). Corrosion and passivation of magnesium alloys. Corrosion Science, 111(10), 835-845. DOI: 10.1016/j.corsci.2016.05.041.
[4] Mao, X., Yi, Y., Huang, S. & He, H. (2019). Bulging limit of AZ31B magnesium alloy tubes in hydroforming with internal and external pressure. The International Journal of Advanced Manufacturing Technology. 101, 2509-2517. DOI: https://doi.org/10.1007/s00170-018-3076-5.
[5] Władysiak, R. & Kozuń, A. (2015). Structure of AlSi20 alloy in heat treated die casting. Archives of Foundry Engineering.15(1), 113-118. DOI: 10.1515/afe-2015-0021.
[6] Rapiejko, C., Pisarek, B. & Pacyniak, T. (2017). Effect of intensive cooling of alloy AZ91 with a chromium addition on the microstructure and mechanical properties of the casting. Archives of Metallurgy and Materials. 62(4), 2199-2204. DOI: 10.1515/amm-2017-0324.
[7] Zhao, H.L., Guan, S.K. & Zheng, F.Y. (2007). Effects of Sr and B addition on microstructure and mechanical properties of AZ91 magnesium alloy. Journal of Materials Research. 22, 2423-2428. DOI: 10.1557/jmr.2007.0331.
[8] Bonnah, R.C., Fu, Y. & Hao, H. (2019). Microstructure and mechanical properties ofAZ91 magnesium alloy with minor additions of Sm, Si and Ca elements. China Foundry. 16(5), 319-325. DOI: 10.1007/s41230-019-9067-9.
[9] Jafari, H. & Amiryavari, P. (2016). The effects of zirconium and beryllium on microstructure evolution, mechanical properties and corrosion behaviour of as-cast AZ63 alloy. Materials Science & Engineering A. 654, 161-168 DOI: 10.1016/j.msea.2015.12.034.
[10] Boby, A., Ravikumar, K.K., Pillai, U.T.S. & Pai, B.C. (2013). Effect of antimony and yttrium addition on the high temperature properties of AZ91 magnesium alloy. Procedia Engineering 55. 355(5), 98-102. DOI: 10.1016/j.proeng. 2013.03.226.
[11] Huang, W., Yang, X., Mukai, T. & Sakai, T. (2019). Effect of yttrium addition on the hot deformation behaviors and microstructure development of magnesium alloy. Journal of Alloys and Compounds. 786, 118-125. DOI: 10.1016/ j.jallcom.2019.01.269.
[12] Pourbahari, B., Mirzadeh, H., Emamy, M. & Roumina, R. (2018). Enhanced ductility of afine-grained Mg-Gd-Al-Zn magnesium alloy by hot extrusion. Advanced Engineering Materials. 20, 1701171. DOI: 10.1002/adem.201701171.
[13] Tardif, S., Tremblay, R. & Dubé, D. (2010). Influence of cerium on the microstructure and mechanical properties of ZA104 and ZA104 + 0.3Ca magnesium alloys. Material Science and Engineering A. 527, 7519-7529. DOI: 10.1016/j.msea.2010.08.082.
[14] Wang, X.J. et al. (2018). What is going on in magnesium alloys? Journal of Materials Science & Technology. 34(2), 245-247. DOI: 10.1016/j.jmst.2017.07.019.
[15] Nan, J. et. al (2016) Effect of neodymium, gadolinium addition on microstructure and mechanical properties of AZ80 magnesium alloy. Journal of Rare Earths. 34(6), 632-637. DOI: 10.1016/S1002-0721(16)60072-8.
[16] Miao, Y., Yaohui, L., Jiaan, L. & Yulai, S. (2014). Corrosion and mechanical properties of AM50 magnesium alloy after being modified by 1 wt.% rare earth element gadolinium. Journal of Rare Earth. 723, 558-563. DOI: 10.1016/S1002-0721(14)60108-3.
[17] Mingbo, Y., Caiyuan, Q., Fusheng, P. & Tao, Z. (2011). Comparison of effects of cerium, yttrium and gadolinium additions on as-cast microstructure and mechanical properties of Mg-3Sn-1Mn magnesium alloy. Journal of Rare Earths. 29(6), 550-557. DOI: 10.1016/S1002-0721(10)60496-6.
[18] Sumida, M., Jung, S. & Okane, T. (2009). Microstructure, solute partitioning and material properties of gadolinium-doped magnesium alloy AZ91D. Journal of Alloys and Compounds. 475. 903-910. DOI: 10.1016/j.jallcom. 2008.08.067/
[19] Pietrowski, S. & Rapiejko, C. (2011). Temperature and microstructure characteristics of silumin casting AlSi9 made with investment casting method. Archives of Foundry Engineering. 11(3), 177-186.
[20] PN-EN 1753:2001. Magnesium and magnesium alloys. Magnesium alloy ingots and castings.
[21] Rapiejko, C., Pisarek, B, Czekaj, E. & Pacyniak, T. (2014). Analysis of AM60 and AZ91 Alloy Crystallisation in ceramic moulds by thermal derivative analisys (TDA). Archive of Metallurgy and Materials. 59(4) DOI: 10.2478/amm-2014-0246.
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Authors and Affiliations

C. Rapiejko
1
ORCID: ORCID
D. Mikusek
1
P. Just
1
T. Pacyniak
1
ORCID: ORCID

  1. Lodz University of Technology, Department of Materials Engineering and Production Systems, ul. Stefanowskiego 1, 90-924 Łódź, Poland
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Abstract

The effect of Ca element on the microstructure evolution of the AZ91 magnesium alloy was investigated in this research. The magne-sium-aluminium alloy AZ91 was inoculated with the Emgesal® Flux 5 to refine its microstructure and also improve its microstructure. Six different concentrations of the Emgesal® Flux 5 content were tested, ranging from 0.1 to 0.6% wt., and compared to the baseline of the AZ91 alloy without inoculation. Melted metal was poured into a preheated metallic mould. Samples to test were achieved after turning treatment. Formed microstructure was assessed using an optical microscope. The microstructure was refined for every tested samples. Me-chanical properties such as tensile strength, elongation, Brinell hardness, Vickers microhardness, abrasion resistance and adhesive resistance were tested on the inoculated samples and compared to the non-inoculated AZ91. Introducing an Emgesal®Flux 5 inoculant caused a change in the tensile strength, elongation, Brinell hard-ness, Vickers microhardness, abrasive wear resistance as well as adhesive wear resistance in each examined concentration.
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Authors and Affiliations

C. Rapiejko
1
ORCID: ORCID
D. Mikusek
1
K. Kubiak
2
ORCID: ORCID
T. Pacyniak
1
ORCID: ORCID

  1. Department of Materials Engineering and Production Systems, Lodz University of Technology, Stefanowskiego 1-15, 90-924 Łódź, Poland
  2. Faculty of Engineering and Physical Sciences, School of Mechanical Engineering, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, United Kingdom
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Abstract

The influence of rapid solidification from the liquid state on the structure of Al71Ni24Fe5 alloy was studied. The samples were prepared by induction melting (ingots) and high pressure die casting into a copper mold (plates). The structure was examined by X-ray diffraction (XRD), light microscopy and high resolution transmission electron microscopy (HRTEM). The mechanism of crystallization was described on the basis of differential scanning calorimetry (DSC) heating and cooling curves, XRD patterns, isothermal section of Al-Ni-Fe alloys at 850°C and binary phase diagram of Al-Ni alloys. The fragmentation of the structure was observed for rapidly solidified alloy in a form of plates. Additionally, the presence of decagonal quasicrystalline phase D-Al70.83Fe9.83Ni19.34 was confirmed by phase analysis of XRD patterns, Fast Fourier Transform (FFT) and Inverse Fast Fourier Transform (IFFT) of transmission electron microscopy images. The metastable character of D-Al70.83Fe9.83Ni19.34 phase was observed because of the lack of thermal effects on the DSC curves. The article indicates the differences with other research works and bring up to date the knowledge about Al71Ni24Fe5 alloys produced by two different cooling rates.
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Bibliography

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[5] Sukhova, O.V., Polonskyy, V.A. & Ustinovа, K.V. (2017). Structure formation and corrosion behaviour of quasicrystalline Al-Ni-Fe alloys. Physics and Chemistry of Solidstate. 18(2), 222-227. DOI: 10.15330/pcss.18.2.222-227.
[6] Kridli, G.T., Friedman, P.A. & Boileau, J.M. (2010). Manufacturing processes for light alloys. In P.K. Mallick (Eds.), Materials, Design and Manufacturing for Lightweight Vehicles (pp. 235-274). Woodhead Publishing.
[7] Bonollo, F., Gramegna, N. & Timelli, G. (2015). High-pressure die-casting: Contradictions and challenges. JOM: The Journal of the Minerals, Metals & Materials Society. 67, 901-908. DOI: 10.1007/s11837-015-1333-8.
[8] Naglič, I., Samardžija, Z., Delijić, K., Kobe, S., Dubois, J.M., Leskovar, B. & Markoli, B. (2017). Metastable quasicrystals in Al–Mn alloys containing copper, magnesium and silicon. Journal of Material Science. 52, 13657-13668. DOI: 10.1007/s10853-017-1477-8.
[9] He, Z., Ma, H., Li, H., Li, X. & Ma, X. (2016). New type of Al-based decagonal quasicrystal in Al60Cr20Fe10Si10 alloy. Scientific Reports. 6, 22337. DOI: 10.1038/srep22337.
[10] Kühn, U., Eckert, J., Mattern, N. & Schultz, L. As-cast quasicrystalline phase in a Zr-based multicomponent bulk alloy. Applied Physics Letter. 77, 3176-3178. DOI: 10.1063/1.1326036.
[11] Avar, B., Gogebakan, M., Yilmaz, F. (2008). Characterization of the icosahedral quasicrystalline phase in rapidly solidified Al-Cu-Fe alloys. Zeitschrift Für Kristallographie- Crystalline Materials. 223, 731-734. DOI: 10.1524/zkri.2008.1077.
[12] Surowiec, M.R. (2017). Quasicrystals. Warsaw: Polish Scientific Publishers PWN. (in Polish) [13] Ishimasa, T. (2016). Mysteries of icosahedral quasicrystals: How are the atoms arranged? IUCrJ. 3, 230-231. DOI: 10.1107/S2052252516009842.
[14] Pedrazzini, S., Galano, M., Audebert, F., Siegkas, P., Gerlach, R., Tagarielli, V.L. & Smith, G.D.W. (2019). High strain rate behaviour of nano-quasicrystalline Al93Fe3Cr2Ti2 alloy and composites. Materials Science and Engineering: A. 764, 138201. DOI: 10.1016/j.msea.2019.138201.
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Authors and Affiliations

K. Młynarek
1
T. Czeppe
2
R. Babilas
1

  1. Department of Engineering Materials and Biomaterials, Silesian University of Technology, Konarskiego 18a, 44-100 Gliwice, Poland
  2. Institute of Metallurgy and Materials Science of Polish Academy of Sciences, 25 Reymonta 5 St., 30-059 Kraków, Poland
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Abstract

The mathematical model and numerical simulations of the solidification of a cylindrical shaped casting, which take into account the process of filling the mould cavity by liquid metal and feeding the casting through the riser during its solidification, are presented in the paper. Mutual dependence of thermal and flow phenomena were taken into account because have an essential influence on solidification process. The effect of the riser shape on the effectiveness of feeding of the solidifying casting was determined. In order to obtain the casting without shrinkage defects, an appropriate selection of riser shape was made, which is important for foundry practice. Numerical calculations of the solidification process of system consisting of the casting and the conical or cylindrical riser were carried out. The velocity fields have been obtained from the solution of momentum equations and continuity equation, while temperature fields from solving the equation of heat conductivity containing the convection term. Changes in thermo-physical parameters as a function of temperature were considered. The finite element method (FEM) was used to solve the problem.

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Authors and Affiliations

L. Sowa
ORCID: ORCID
T. Skrzypczak
ORCID: ORCID
P. Kwiatoń
ORCID: ORCID
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Abstract

The mathematical model and numerical simulations of the solidification of a cylindrical casting, which take into account the process of the mould cavity filling by liquid metal and the feeding of the casting through the conical riser during its solidification, are proposed in the paper. The interdependence of thermal and flow phenomena were taken into account because they have an essential influence on solidification process. The effect of the pouring temperature and pouring velocity of the metal on the solidification kinetics of the casting was determined. In order to obtain the casting without shrinkage defects, an appropriate selection of these parameters was tried, which is important for foundry practice. The velocity fields have been obtained from the solution of Navier-Stokes equations and continuity equation, while temperature fields from solving the equation of heat conductivity containing the convection term. In the solidification modelling the changes in thermo-physical parameters as a function of temperature were considered. The finite element method (FEM) was used to solve the problem.

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Authors and Affiliations

L. Sowa
ORCID: ORCID
T. Skrzypczak
ORCID: ORCID
P. Kwiatoń
ORCID: ORCID
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Abstract

With the aid of eutectic modification treatment, the precipitation of coarse lamellar eutectic silicon can be suspended during the solidification of aluminum-silicon alloys, thereby the formation of fine-grained, fibrous eutectic Si can be promoted by the addition of small amounts of modifying elements, such as Sr, to the liquid alloy. The effectiveness of this technique is, however, highly dependent on many technological factors, and the degree of modification can be lowered during the various stages of melt preparation due to the oxidation of the Sr-content of the melt. During our research, we investigated the effect of rotary degassing melt treatments coupled with the addition of three different fluxes on the degree of modification of an Al-Si-Mg-Cu casting alloy. It was also studied, that whether additional Sr alloying made before and during the melt treatments can compensate the Sr fading with time. The degree of eutectic modification was characterized by thermal analysis (TA) and the microscopic investigation of TA specimens. It was found, that by using one of the three fluxes, and by adding Sr master alloy rods before the melt treatments, better modification levels could be achieved. It was also found that the measurement of Sr-concentration by optical emission spectroscopy alone cannot be used for controlling the level of eutectic modification.

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Authors and Affiliations

F. Vincze
M. Tokár
G. Fegyverneki
G. Gyarmati
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Abstract

In this paper is discussed the effect of the inoculant mischmetal addition on the microstructure of the magnesium alloy AZ91. The concentration of the inoculant was increased in the samples within the range from 0.1% up to 0.6%. The thermal process was performed with the use of Derivative and Thermal Analysis (DTA). A particular attention was paid to finding the optimal amount of the inoculant, which causes fragmentation of the microstructure. The concentration of each element was verified with use of a spark spectrometer. In addition, the microstructures of every samples were examined with the use of an optical microscope and also was performed an image analysis with a statistical analysis using the NIS–Elements program. The point of those analyses was to examine the differences in the grain diameters of phase αMg and eutectic αMg+γ(Mg17Al12) in the prepared samples as well as the average size of each type of grain by way of measuring their perimeters. This paper is the second part of the introduction into a bigger research on grain refinement of magnesium alloys, especially AZ91. Another purpose of this research is to achieve better microstructure fragmentation of magnesium alloys without the relevant changes of the chemical composition, which should improve the mechanical properties.

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Authors and Affiliations

D. Mikusek
C. Rapiejko
ORCID: ORCID
D. Walisiak
T. Pacyniak
ORCID: ORCID
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Abstract

The objective of the research was to determine the influence of boron on the crystallization process and microstructure of ductile cast iron.

In the case of ductile cast iron it is a vital issue because even as little as trace presence of boron changes the properties of ductile cast iron

in a significant way. With the use of a new ATD-4 (TDA) tester and CRYSTALDIGRPAH converter it was possible to measure the

crystallization process parameters of the same alloy with four different contents of boron in one mould. Four samples with different boron

contents were extracted, their microhardness was measured and quantitative analysis of microstructure was conducted. Obtained results

allowed to state that with increasing content of boron the amount of graphite precipitates decreases, the amount of pearlite precipitates

increases, the shape of graphite precipitates deteriorates and hardness increases. It is also planned to perform additional testings with boron

contents between previously tested values.

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Authors and Affiliations

A. Studnicki
R. Dojka
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Abstract

Mg-0.5Si-xSn (x=0.95, 2.9, 5.02wt.%) alloys were cast and extruded at 593K (320 ºC) with an extrusion ratio of 25. The microstructure and mechanical properties of as-cast and extruded test alloys were investigated by OM, SEM, XRD and tensile tests. The experimental results indicate that the microstructure of the Mg-0.5Si-xSn alloys consists of primary α-Mg dendrites and an interdendritic eutectic containing α-Mg, Mg2Si and Mg2Sn. There is no coarse primary Mg2Si phase in the test alloys due to low Si content. With the increase in the Sn content, the Mg2Si phase was refined. The shape of Mg2Si phase was changed from branch to short bar, and the size of them were reduced. The ultimate tensile strength and yield strength of Mg-0.52Si-2.9Sn alloy at the temperature of 473K (200 ºC) reach 133MPa and 112MPa respectively. Refined eutectic Mg2Si phase and dispersed Mg2Sn phase with good elevated temperature stability are beneficial to improve the elevated temperature performance of the alloys. However, with the excess addition of Sn, large block-like Mg2Sn appears around the grain boundary leading to lower mechanical properties.

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Authors and Affiliations

F. Kahrıman
M. Zeren
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Abstract

The article is a case study of the steel milling ring casting of about 6 tonnes net weight. The casting has been cast in the steel foundry the authors have been cooperating with. The aim was to analyse the influence of the shape of the chills and the material which was used to make them on the casting crystallization process. To optimally design the chills the set of the computer simulation has been carried out with 3 chills’ shape versions and 3 material’s versions and the results have been compared with the technology being in use (no chills). The proposed chills were of different thermal conductivity from low to high. Their shapes were obviously dependant on the adjacent casting surface geometry but were the result of the attempt to optimise their effect with the minimum weight, too. The chills working efficiency was analysed jointly with the previously designed top feeders system. The following parameters have been chosen to compare their effectiveness and the crystallization process: time to complete solidification and so-called fed volume describing the casting feeding efficiency. The computer simulations have been carried out with use of MagmaSoft v. 5.2 software. Finally, the optimisation has led to 15% better steel yield thanks to 60% top feeders weight reduction and 40% shorter solidification time. The steel ring cast with use of such technology fulfil all quality criteria.

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Authors and Affiliations

M. Jaromin
R. Dojka
J. Jezierski
M. Dojka
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Abstract

Simulation software can be used not only for checking the correctness of a particular design but also for finding rules which could be used

in majority of future designs. In the present work the recommendations for optimal distance between a side feeder and a casting wall were

formulated. The shrinkage problems with application of side feeders may arise from overheating of the moulding sand layer between

casting wall and the feeder in case the neck is too short as well as formation of a hot spot at the junction of the neck and the casting. A

large number of simulations using commercial software were carried out, in which the main independent variables were: the feeder’s neck

length, type and geometry of the feeder, as well as geometry and material of the casting. It was found that the shrinkage defects do not

appear for tubular castings, whereas for flat walled castings the neck length and the feeders’ geometry are important parameters to be set

properly in order to avoid the shrinkage defects. The rules for optimal lengths were found using the Rough Sets Theory approach,

separately for traditional and exothermic feeders.

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Authors and Affiliations

M. Perzyk
J. Kozlowski
M. Mazur
K. Szymczewski
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Abstract

Simulation software dedicated for design of casting processes is usually tested and calibrated by comparisons of shrinkage defects

distribution predicted by the modelling with that observed in real castings produced in a given foundry. However, a large amount of

expertise obtained from different foundries, including especially made experiments, is available from literature, in the form of

recommendations for design of the rigging systems. This kind of information can be also used for assessment of the simulation predictions.

In the present work two parameters used in the design of feeding systems are considered: feeding ranges in horizontal and vertical plates as

well as efficiency (yield) of feeders of various shapes. The simulation tests were conducted using especially designed steel and aluminium

castings with risers and a commercial FDM based software. It was found that the simulations cannot predict appearance of shrinkage

porosity in horizontal and vertical plates of even cross-sections which would mean, that the feeding ranges are practically unlimited. The

yield of all types of feeders obtained from the simulations appeared to be much higher than that reported in the literature. It can be

concluded that the feeding flow modelling included in the tested software does not reflect phenomena responsible for the feeding processes

in real castings properly. Further tests, with different types of software and more fundamental studies on the feeding process modelling

would be desirable.

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Authors and Affiliations

M. Perzyk
A. Kochański
P. Mazurek
K. Karczewski
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Abstract

This work presents the results of the research of the effect of the inoculant Emgesal Flux 5 on the microstructure of the magnesium alloy AZ91. The concentration of the inoculant was increased in samples in the range from 0.1% to 0.6%. The thermal processes were examined with the use of Derivative and Thermal Analysis (DTA). During the examination, the DTA samplers were preheated up to 180 °C. A particular attention was paid to finding the optimum amount of inoculant, which would cause fragmentation of the microstructure. The concentration of each element was verified by means of a spark spectrometer. In addition, the microstructures of the samples were examined with the use of an optical microscope, and an image analysis with a statistical analysis using the NIS–Elements program were carried out. Those analyses aimed at examining the differences between the grain diameters of phase αMg and eutectic αMg+γ(Mg17Al12) in the prepared samples as well as the average size of each type of grain by way of measuring their perimeters. This paper is an introduction to a further research of grain refinement in magnesium alloys, especially AZ91. Another purpose of this research is to achieve better microstructure fragmentation of magnesium alloys without the related changes of the chemical composition, which should improve the mechanical properties.

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Authors and Affiliations

C. Rapiejko
D. Mikusek
A. Andrzejczak
T. Pacyniak
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Abstract

Directional solidification of ledeburite was realised out using a Bridgman’s device. The growth rate for movement sample v=83.3 μm/s

was used. In one sample the solidification front was freezing. The value of temperature gradient in liquid at the solidification front was

determined. Interfacial distance λ on the samples was measured with NIS-Elements application for image analysis.

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Authors and Affiliations

M. Trepczyńska-Łent
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Abstract

In this paper, the mathematical model and numerical simulations of the molten steel flow by the submerged entry nozzle and the filling process of the continuous casting mould cavity are presented. In the mathematical model, the temperature fields were obtained by solving the energy equation, while the velocity fields were calculated by solving the momentum equations and the continuity equation. These equations contain the turbulent viscosity which is found by solving two additional transport equations for the turbulent kinetic energy and its rate of dissipation. In the numerical simulations, coupling of the thermal and fluid flow phenomena by changes in the thermophysical parameters of alloy depending on the temperature has been taken into consideration. This problem (2D) was solved by using the finite element method. Numerical simulations of filling the continuous casting mould cavity were performed for two variants of liquid metal pouring. The effect of the cases of pouring the continuous casting mould on the velocity fields and the solid phase growth kinetics in the process of filling the continuous casting mould was evaluated as these magnitudes have an influence on the high quality of the continuous cast steel slab.

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Authors and Affiliations

L. Sowa
T. Skrzypczak
P. Kwiatoń
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Abstract

The work presents results of the investigations of effect of intensive cooling of alloy AC-AlSi7Mg with alloy additions on microstructure and mechanical properties of the obtained casts. The experimental casts were made in ceramic molds preliminarily heated to 180°C, into which AC-AlSi7Mg with alloy additions was poured. Within implementation of the research, a comparison was made of the microstructure and mechanical properties of the casts obtained in ceramic molds cooled at ambient temperature and the ones intensively cooled in a cooling liquid. Kinetics and dynamics thermal effects recorded by the TDA method were compared. Metallographic tests were performed with the use of optical microscope and strength properties of the obtained casts were examined: UTS, Elongation and HB hardness.

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Authors and Affiliations

B. Pisarek
C. Rapiejko
T. Pacyniak
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Abstract

The paper presents an analysis of a selected grade of high silicon cast iron intended for work in corrosive and abrasive conditions. The text describes its microstructure taking into account the process of crystallization, TDA analysis, EDS, XRD and the chemical composition analysis. In order to determine the phase composition, X-ray diffraction tests were carried out. The tests were executed on a Panalytical X'Pert PRO X-ray diffractometer with filtration of radiation from a lamp with copper anode and PIXcel 3D detector on the deflected beam axis. Completed tests allowed to describe the microstructure with detailed consideration of intermetallic phases present in the alloy. Results of the analysis of the examined alloy clearly show that we deal with intermetallic phases of Fe3Si, Fe5Si3 types, as well as silicon ferrite and crystals of silicon. In the examined alloy, we observed the phenomenon of segregation of carbon, which, as a result of this process, enriches the surface of silicon crystals, not creating a compound with it. Moreover, the paper demonstrates capability for crystallization of spheroidal graphite in the examined alloy despite lack of elements that contribute to balling in the charge materials.

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Authors and Affiliations

M. Stawarz
ORCID: ORCID
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Abstract

The article focuses on the analysis of the effect of Zr on the properties of the aluminium alloy AlSi9Cu1Mg. The effect of Zr was evaluated depending on the change in mechanical properties and heat resistance during a gradual addition of Zr with an increase of 0.05 wt. % Zr. Half of the cast experimental samples from each variant were heat treated by precipitation hardening T6 (hereinafter HT). The measured values in both states indicate an improvement of the mechanical properties, especially in the experimental variants with a content of Zr ≥ 0.20 wt. %. In the evaluation of Rm, the most significant improvement occurred in the experimental variant with an addition of Zr 0.25 wt. % after HT and E in the experimental variant with addition of Zr 0.20 wt. % after HT. Thus, a difference was found from the results of the authors defining the positive effect of Zr, in particular at 0.15 wt. %. When evaluating the microstructure of the AlSi9Cu1Mg alloy after Zr alloying, Zr phases are already eliminated with the addition of Zr 0.10 wt. %. Especially at higher levels of Zr ≥ 0.20 wt. %, long needle phases with slightly cleaved morphology are visible in the metal matrix. It can be stated that a negative manifestation of Zr alloying is expressed by an increase in gassing of experimental alloys, especially in variants with a content of Zr ≥ 0.15 wt. %. Experimental samples were cast into ceramic moulds. The development of an experimental alloy AlSi9Cu1Mg alloyed with Zr would allow the production of a more sophisticated material applicable to thin-walled Al castings capable of operating at higher temperature loads.

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Authors and Affiliations

M. Matejka
ORCID: ORCID
M. Kuriš
D. Bolibruchova
R. Pastirčák
ORCID: ORCID
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Abstract

The article concerns the experimental verification of the numerical model simulating the solidification and cooling processes proceeding in the domain of cast iron casting. The approximate course of the function describing the evolution of latent heat and the value of substitute specific heat resulting from its course were obtained using the thermal and derivative analysis (TDA) method The TDA was also used to measure the cooling curves at the distinguished points of the casting. The results obtained in this way were compared with the calculated cooling curves at the same points. At the stage of numerical computations, the explicit scheme of the finite difference method was applied. The agreement between the measured and calculated cooling curves is fully satisfactory.
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Bibliography

[1] Mendakiewicz, J. (2011). Identification of the solidification parameters of casting alloys on the example of grey cast iron. Monografia. Gliwice: Wyd. Pol. Śl. (in Polish).
[2] Jiji, L.M. (2009). Heat conduction. Third Edition. Springer.
[3] Mochnacki, B. & Majchrzak, E. (2007). Identification of macro and micro parameters in solidification model. Bulletin of the Polish Academy of Sciences. Technical Sciences. 55(1), 107-113.
[4] Kapturkiewicz, W. (2003). Modelling of cast iron solidification. Cracow: Akapit.
[5] Majchrzak, E., Mendakiewicz, J. & Piasecka-Belkhayat, A. (2005). Algorithm of mould thermal parameters identification in the system casting–mould–environment. Journal of Materials Processing Technology. 162-163, 1544-1549.
[6] Mochnacki, B., Suchy, J.S. (1995). Numerical methods in computations of foundry processes. Cracow: PFTA.
[7] Ciesielski, M. & Mochnacki, B. (2019). Comparison of approaches to the numerical modelling of pure metals solidification using the control volume method. International Journal of Cast Metals Research. 32(4), 213-220. https://doi.org/10.1080/13640461.2019.1607650
[8] Majchrzak, E., Mochnacki, B., Suchy, J.S (2008). Identification of substitute thermal capacity of solidifying alloy. Journal of Theoretical and Applied Mechanics. 46(2), 257-268.

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Authors and Affiliations

J. Mendakiewicz
1
ORCID: ORCID

  1. Department of Computational Mechanics and Engineering, Silesian University of Technology, Konarskiego18A, 44-100 Gliwice, Poland
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Abstract

This paper presents results of a study of the effect of inoculation of yttrium on the microstructure of AZ91 alloy. The concentration of the inoculant was increased in samples in the range from 0.1% up to 0.6%. The influence of Y on the thermal effects resulting from the phase transformations occurring during the crystallisation at different inoculant concentrations were examined with the use of Derivative and Thermal Analysis (DTA). The microstructures of the samples were examined with the use of an optical microscope; and an image analysis with a statistical analysis were also carried out. Those analyses aimed at examining oh the effect of inoculation of the Y on the differences between the grain diameters of phase αMg and eutectic αMg + γ(Mg17Al12) in the prepared examined material as well as the average size of each type of grain by way of measuring their perimeters.

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Authors and Affiliations

D. Mikusek
C. Rapiejko
ORCID: ORCID
A. Andrzejczak
T. Pacyniak
ORCID: ORCID
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Abstract

Due to the importance of uranium and uranium alloys to national defence and nuclear industrial applications, it is necessary to understand dendrite formation in their solidification structures and to control their microstructures. In this study, a modified cellular automaton model was developed to predict 2-D and 3-D equiaxed dendrite growth in U-Nb alloys. The model takes into account solute diffusion, preferential growth orientation, interface curvature, etc., and the solid fraction increment is calculated using the local level rule method. Using this model, 2-D large-scale and 3-D equiaxed dendrite growth with various crystallographic orientations in the U-5.5Nb alloy were simulated, and the Nb micro-segregation behaviour during solidification was analysed. The simulated results showed reasonable agreement with the as-cast microstructure observed experimentally.
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Authors and Affiliations

Bin Su
1
ORCID: ORCID
Jing-Yuan Liu
1
ORCID: ORCID
Xiao-Peng Zhang
1
ORCID: ORCID
Xue-Wei Yan
2
ORCID: ORCID

  1. China Academy of Engineering Physics, Institute of Materials, Jiangyou, China
  2. Zhengzhou University of Aeronautics, School of Aero Engine, Zhengzhou, China
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Abstract

The article presents an integrated analytical and measurement system for evaluation of the properties of cast metals and alloys. The presented platform is an extension of the SLAG - PROP application with new modules, which allow to use information on metallurgical processes in an even more effective way, as well as to evaluate the finished product. In addition, the construction of a measuring station for the analysis of thermal processes taking place in a metal bath allows for precise observation of phenomena together with their appropriate interpretation. The article presents not only the cooling curves of certain copper alloys. The analysis also covered mechanical properties related to hardness, finished products depending on the mold in which the products were cast. In the literature one can find information about the mechanical properties of products in the improved state, usually after plastic or thermal treatment, omitting their properties obtained as a result of a naturally made casting. The article also presents the method of placing information in the database using a convenient graphical tool.

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Authors and Affiliations

S. Biernat
A.W. Bydałek
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Abstract

Silicon – molybdenum cast iron commonly called SiMo due to its unique properties has becoming more and more interesting engineering material. The history and development of this alloy is relatively long but, due to the significant difficulties during the manufacturing process resulting in the lower final quality than expected, it has not been applied to often in practice. The biggest challenge is its brittleness as a result of the carbides precipitations. During last few years, thanks to the many important researches made and the general foundry technology development, the interest in SiMo iron has been rapidly growing, especially for the castings for heavy duty applications like corrosion, high temperature and wear abrasion resistant parts. In the article the heat treatment attempts to improve the microstructure of SiMo castings has been presented. The goal was to destroy or at least to refine and uniformly distribute the carbides precipitations to improve mechanical properties of the exhaust manifold castings for the cars. The experiments were carried out for the alloy contains approx. 4% Si, 1% Mo and 3.2%C. The range of the research included: hardness measuring, standard mechanical properties and microstructure for as-cast state and after that the subsequent heat treatment process with another properties check. The result of the heat treatment was the elimination of pearlite from the metal matrix. Moreover, the changes of the carbide molybdenum – rich phase morphology were observed. The dispersion of the carbides precipitations in the carbides area was observed. The experiments proved the possibility to control the microstructure and the mechanical properties of the SiMo castings by means of heat treatment but only to some extent.

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Authors and Affiliations

B. Cygan
M. Stawarz
J. Jezierski

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