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Abstract

The paper deals with hypereutectic high chromium cast irons. The subject of examination was the effect of various alloying elements (Ti, W, Mo, V) on the size of primary carbides and on the resultant material hardness. Using a scanning electron microscope with a wave dispersion analyser, the carbon content in carbides was established. To determine the other elements, an energy dispersion analyser was used. It was found that both the primary and the eutectic carbides were of the M7C3 type and very similar in composition. The carbides always contained Cr and Fe, and also W, Mo, V or Ti, in dependence on the alloying elements used. The structure of materials containing only chromium without any alloying additions exhibited coarse acicular primary carbides. The structure of materials alloyed with another element was always finer. Marked refinement was obtained by Ti alloying.
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Authors and Affiliations

A. Záděra
V. Kaňa
V. Krutiš
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Abstract

Topic of this work is to compare metalurgy of cast irons poured into sand moulds and into shell molds at IEG Jihlava company and from it

following differencies in structures of thin- and thick-walled castings. This work is dealing with investigation and experimental

measurement on surfaces and sections suitable thin- and thick-walled investment castings at IEG Jihlava. Cast irons with flake graphite

(grey cast iron) and cast irons with spheroidal graphite (ductile cast iron). Both mechanical and physical properties are determined using

calculations from as measured values of wall thicknesses L and Lu, Vickers hardness and remanent magnetism. Measurement results are

discussed, findings are formulated and methods for castings metallurgical quality improvement are recommended finally

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Authors and Affiliations

B. Skrbek
K. Policar
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Abstract

An analysis has been carried out of the influence of annealing time at the preheating temperature of 650 °C on the change in hardness and alloy structure of lamellar graphite cast iron in the working as well as in the laboratory conditions. This preheat temperature is common during reclaiming welding of castings with complex shapes. The changes in unalloyed cast iron EN-GJL 200 to EN-GJL 300 according to ISO 1690 standard and cast iron with low amount of elements such as Sn, Cu, Cr, and Mo and their combinations were assessed. It was found that the cast iron of higher strength grades has better hardness and structural stability. Cast iron alloyed with chromium or its combinations has the highest stability. In unalloyed cast iron, a partial degradation of pearlite occurs; in alloyed cast iron the structural changes are not conclusive.

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Authors and Affiliations

J. Roučka
ORCID: ORCID
J. Prochazka
V. Kana
V. Krutis
K. Nedelova
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Abstract

The article presents the results of research on the abrasion resistance of cast iron with vermicular graphite in the as-cast state and after austempering (the latter material is referred to as AVGI – Austempered Vermicular Graphite Iron). Austenitization was carried out at the temperature values of either 900°C or 960°C, and austempering at the temperature values of either 290°C and or 390°C. Both the austenitization and the austempering time was equal to 90 minutes. The change of the pearlitic-ferritic matrix to the ausferritic one resulted in an increase in mechanical properties. Abrasion tests were conducted by means of the T-01M pin-on-disc tribometer. The counter-sample (i.e. the disc) was made of the JT6500 friction material. Each sample was subject to abrasion over a sliding distance of 4000 m. The weight losses of both samples and counter-samples were determined by the gravimetric method. It was found that the vermicular cast iron austenitized at 900°C and austempered at 290°C was characterized by the lowest wear among the evaluated cast iron types. The geometric structure of the surface layer after the dry friction test exhibited irregular noticeable grooves, distinct oriented abrasion traces, plastic flow of the material, microcracks, and pits generated by tearing out the abraded material. The largest surface roughness was found for the AVGI cast iron heat-treated according to the variant 3 (Tγ =900 ºC; Tpi = 390°C), while the smallest one occurred in AVGI cast iron subject to either the variant 2 (Tγ =960 ºC; Tpi = 290°C) or the variant 4 (Tγ =900 ºC; Tpi = 290°C) of heat treatment and was equal to either 2.5 μm or 2.66 μm, respectively. It can be seen that the surface roughness decreases with the decrease in the austempering temperature.
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Bibliography

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[2] Hebda, M. (2007). Processes of friction, lubrication and wear of machines. Warsaw – Radom: Ed. Institute of Sustainable Technologies - PIB.
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[29] Polish Standard PN-75/H-04661: Grey cast iron, nodular cast iron and malleable. Metallographic examinations. Determining of microstructure.
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[38] Institute of Sustainable Technologies. User manual. Tribology set T-01M, mandrel-disc type. State Research Institute. Radom 2010.
[39] makland.com.pl. 28.02.2016, time 13.25.

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Authors and Affiliations

A. Jakubus
1
ORCID: ORCID

  1. The Jacob of Paradies University in Gorzów Wielkopolski, ul. Teatralna 25, 66-400 Gorzów Wielkopolski, Poland
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Abstract

The article presents the influence of the percentage share of pig iron and steel scrap on the chemical composition, physicochemical and mechanical properties. Using an induction furnace, 6 melts were carried out with a variable amount of pig iron in the charge from 0 to 50%. For carburizing, a RANCO 9905 carburizer with a carbon content of 99.2% was used. After melting and introducing FeSi75, temperature measurement was carried out and the metal was superheated to 1500°C. The next step was to pour the samples for chemical analysis, DTA (Derivation Thermal Analysis) and strength and hardness from the melting furnace without inoculation. The last step was to carry out the inoculation by introducing 0.3% barium inoculant into the vat and pouring samplers for DTA analysis. The inoculation was carried out solely to determine changes in DTA parameters, mainly Temin, compared to castings without inoculation.
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Authors and Affiliations

R. Dwulat
1 2
ORCID: ORCID
K. Janerka
2
ORCID: ORCID
K. Grzesiak
1
M. Gałuszka
2

  1. Foundry Lisie Kąty, Lisie Kąty 7, 86-302 Grudziądz
  2. Department of Foundry Engineering, Silesian University of Technology, Towarowa 7, 44-100 Gliwice
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Abstract

The paper presents results of tests carried out on ausferrite carbide matrix alloyed ductile cast iron. The ausferrite was obtained via addition of Cu and Mo alloying elements. This eliminated heat treatment from the alloy production cycle. The article presents results of tests of the quality of the obtained material. Emphasis was put on metallographic analysis using light and scanning microscopy. Works also included chemical composition tests and EDS analysis. Strength tests were executed in an accredited laboratory. It is possible to create a raw ausferrite carbide matrix without subjecting an alloy to heat treatment. However, it turned out that quality parameters of cast iron were insufficient. The obtained material hardness was 515 HB, while Rm strength and A5 ductility were very low. The low tensile strength of the analyzed alloy resulted from the presence of degenerate graphite secretion (of flake or vermicular shape) in the cast iron. The tests also demonstrated that the alloy was prone to shrinkage-related porosity, which further weakened the material. Alloys made of alloyed ductile iron of ausferrite matrix micro-structure are very attractive due to elimination of the heat treatment process. However, their production process and chemical composition must be optimized.
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Bibliography

[1] Ahmed, M., Riedel, E., Kovalko, M., Volochko, A., Bähr, R. & Nofal, A. (2022). Ultrafine ductile and austempered ductile irons by solidification in ultrasonic field. International Journal of Metalcasting. 16(3), 1463-1477. DOI: 10.1007/s40962-021-00683-8.
[2] Benam, A.S. (2015). Effect of alloying elements on austempered ductile iron (ADI) properties and its process: review. China Foundry. 12(1), 54-70.
[3] Uyar, A., Sahin, O., Nalcaci, B., & Kilicli. V. (2022). Effect of austempering times on the microstructures and mechanical properties of dual-matrix structure austempered ductile iron (DMS-ADI). International Journal of Metalcasting. 16(1), 407-418. DOI: 10.1007/s40962-021-00617-4.
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[5] Tyrała, E., Górny, M., Kawalec, M., Muszyńska, A. & Lopez, H.F. (2019). Evaluation of volume fraction of austenite in austempering process of austempered ductile iron. Metals. 9(8), 1-10. DOI: 10.3390/met9080893.
[6] Fraś, E., Górny, M., Tyrała, E. & Lopez. H. (2012). Effect of nodule count on austenitising and austempering kinetics of ductile iron castings and mechanical properties of thin walled iron castings. Materials Science and Technology. 28(12), 1391-1396. DOI: 10.1179/1743284712Y.0000000088.
[7] Ibrahim, M.M., Negm, A.M., Mohamed, S.S. & Ibrahim. K.M. (2022). Fatigue properties and simulation of thin wall ADI and IADI castings. International Journal of Metalcasting. 16(4), 1693-1708. DOI: 10.1007/s40962-021-00711-7.
[8] Gumienny, G. & Kacprzyk. B. (2018). Copper in ausferritic compacted graphite iron. Archives of Foundry Engineering. 18(1), 162-166. DOI: 10.24425/118831.
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[10] Akinribide, O.J., Ogundare, O.D., Oluwafemi, O.M., Ebisike, K., Nageri, A.K., Akinwamide, S.O., Gamaoun, F. & Olubambi, P.A. (2022). A review on heat treatment of cast iron: phase evolution and mechanical characterization. Materials. 15(20), 1-38. DOI: 10.3390/ma15207109. [11] Samaddar, S., Das, T., Chowdhury, A.K., & Singh, M. (2018). Manufacturing of engineering components with Austempered ductile iron - A review. Materials Today: Proceedings. 5(11), 2561525624. DOI: 10.1016/j.matpr.2018.11.001.
[12] Stachowiak, A., Wieczorek, A.N., Nuckowski, P., Staszuk, M. & Kowalski, M. (2022). Effect of spheroidal ausferritic cast iron structure on tribocorrosion resistance. Tribology International. 173. DOI: 10.1016/j.triboint.2022.107688.
[13] Myszka, D. & Wieczorek, A. (2015). Effect of phenomena accompanying wear in dry corundum abrasive on the properties and microstructure of austempered ductile iron with different chemical composition. Archives of Metallurgy and Materials. 60(1), 483-490. DOI: 10.1515/amm-2015-0078.
[14] Pimentel, A.S.O., Guesser, W.L., Portella, P.D., Woydt, M. & Burbank. J. (2019). Slip-rolling behavior of ductile and austempered ductile iron containing niobium or chromium. Materials Performance and Characterization. 8(1), 402-418. DOI: 10.1520/MPC20180188.
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[18] Gumienny, G., Kacprzyk, B., Mrzygłód, B. & Regulski. K. (2022). Data-driven model selection for compacted graphite iron microstructure prediction. Coatings. 12(11). DOI: 10.3390/coatings12111676.
[19] Tenaglia, N.E., Pedro, D.I., Boeri, R.E. & Basso. A.D. (2020). Influence of silicon content on mechanical properties of IADI obtained from as cast microstructures. International Journal of Cast Metals Research. 33(2-3), 72-79. DOI: 10.1080/13640461.2020.1756082.
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[24] Stawarz, M. (2018). Crystallization process of silicon molybdenum cast iron. Archives of Foundry Engineering. 18(2), 100-104. DOI: 10.24425/122509.
[25] Vaško, A., Belan, J. & Tillová. E. (2018). Effect of copper and molybdenum on microstructure and fatigue properties of nodular cast irons. Manufacturing Technology. 18(6), 1049-1052. DOI: 10.21062/ujep/222.2018/a/1213-2489/mt/18/6/1048.
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Authors and Affiliations

M. Stawarz
1
ORCID: ORCID
M. Lenert
1
K. Piasecki
1
ORCID: ORCID

  1. Department of Foundry Engineering, Silesian University of Technology, Towarowa 7 St., 44-100 Gliwice, Poland
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Abstract

The article presents the results of research on the physicochemical and mechanical properties, microstructure, and the tendency to form shrinkage of nodular cast iron depending on the type of inoculant used for secondary inoculation. Six different inoculants containing different active elements in their chemical composition were used for the research. Step castings and Y2 wedges were made on the vertical forming line using an automatic pouring machine. The inoculation in the amount of 0.2% was made using a pneumatic dispenser equipped with a vision system controlling the effectiveness of the inoculation. The results of the thermal analysis were determined and compared, and the potential of each of the inoculants was assessed.
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Bibliography

[1] Fraś, E., Podrzucki, C. (1978). Modified cast iron. Kraków: Skrypt AGH, nr. 675. (in Polish).
[2] ITACAX™ – Final iron control. Retrieved November 10, 2021, from http://www.proservicetech.it/itacax-thermal-analysis-final-iron-quality-control/.
[3] Karsey S.I. (2000). Ductile iron I. Manufacturing. Warszawa: QIT, Fer et Titane Inc. (in Polish).
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[6] Lampic, M. (2013). Inoculation of cast irons: practice and developments. International Foundry, Research. 65(2).
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Authors and Affiliations

R. Dwulat
1 2
ORCID: ORCID
K. Janerka
2
ORCID: ORCID
K. Grzesiak
1

  1. Foundry Lisie Kąty, Lisie Kąty 7, 86-302 Grudziądz, Poland
  2. Department of Foundry Engineering, Silesian University of Technology, Towarowa 7, 44-100 Gliwice, Poland
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Abstract

The paper presents the initial results of investigation concerning the abrasion resistance of cast iron with nodular, vermicular, or flake graphite. The nodular and vermicular cast iron specimens were cut out of test coupons of the IIb type with the wall thickness equal to 25 mm, while the specimens made of grey cast iron containing flake graphite were cut out either of special casts with 20 mm thick walls or of the original brake disk. The abrasion tests were carried out by means of the T-01M tribological unit working in the pin-on-disk configuration. The counterface specimens (i.e. the disks) were made of the JT6500 brand name friction material. Each specimen was abraded over a distance of 4000 m. The mass losses, both of the specimens and of the counterface disks, were determined by weighting. It was found that the least wear among the examined materials was exhibited by the nodular cast iron. In turn, the smallest abrasion resistance was found in vermicular cast iron and in cast iron containing flake graphite coming from the brake disk. However, while the three types of specimens (those taken from the nodular cast iron and from grey cast iron coming either from the special casts or from the brake disk) have almost purely pearlitic matrix (P95/Fe05), the vermicular cast iron matrix was composed of pearlite and ferrite occurring in the amounts of about 50% each (P50/Fe50). Additionally, it was found that the highest temperature at the cast iron/counterface disk contact point was reached during the tests held for the nodular cast iron, while the lowest one occurred for the case of specially cast grey iron.

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Authors and Affiliations

A. Jakubus
ORCID: ORCID
M.S. Soiński
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Abstract

Ductile irons of the type of Si-Mo are characterized by increased resistance to long-term influence of high temperatures and cyclic temperature changes. They are mainly used in castings of combustion engine exhaust piping and other castings utilized at temperatures of up to 850°C. The aim of the study is to verify the mechanical properties of non-alloyed cast iron EN CSN GJS 450, SiMo4-0.5 and SiMo5-1 ductile irons at temperatures of 700 to 800°C, and the extent of their superficial oxidation after longterm annealing at a temperature of 900°C. Via chemical microanalysis the composition of oxidation products in the surface layer was evaluated.
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Authors and Affiliations

J. Roučka
E. Abramová
V. Kaňa
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Abstract

This work presents a scheme for the manufacture of spherical grinding bodies used in grinding and crushing machinery as a grinding medium from abrasion-resistant cast iron CHKH16 (according to GOST 7769-82) free of shrinkage defects produced by casting into single sand molds with a vertical joint and by usingcoolers. The grinding efficiency in terms of material destruction and energy consumption has been studied according to a wide range of operating parameters and new scheme for calculating the sprue and supply system has been developed by the authors of the article. Its functionality has been substantiated, particularly the use of a central riser acting as a head and the use of coolers. The conducted numerical simulation has shown the dependence of a solid phase formation over time, which characterizes the direction of the system crystallization and determines the locations of the shrinkage defects concentration. The manufacture of the grinding body with a 100 mm diameter using the considered technology is presented in this paper.

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Authors and Affiliations

D.O. Pustovalov
T. Ablyaz
K.R. Muratov
K.V. Sharov
A.V. Bogomyagkov
A.A. Shumkov
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Abstract

The possibilities of producing ductile cast iron with the addition of 1 ÷ 3% of tungsten are presented. Tungsten from waste chips from mechanical processing was introduced into the liquid cast iron in the form of specially prepared cartridges. Correct dissolution of tungsten in the metal bath was found, and there were no casting defects in the alloy. The form of carbide precipitates in the microstructure of cast iron was determined and the influence of increasing tungsten content on the reduction of the number of graphite precipitates in the structure was determined. Impact tests show that this property degrades with increasing tungsten content as opposed to hardness which increases. It was found that the addition of tungsten from machining waste is a potential source of enrichment of cast iron with this element.
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Bibliography

[1] Volkov, A.N. (1975). Abrasive wear resistance of manganese cast iron with tungsten. Metal Science and Heat Treatment. 17, 412-414.
[2] Duarte, L.I., Lourenço, N., Santos, H., Santos, J. & Sá, C. Tungsten carbide powder inserts in ductile iron. Materials Science Forum. 455-456, 267-270.
[3] Kopyciński, D. (2009). Analysis of the structure of castings made from chromium white cast iron resistant to abrasive wear. Archives of Foundry Engineering. 9(4), 109-112.
[4] Podrzucki, Cz. (1991). Cast Iron. The Structure, Property, Application. T.1 and T.2, Kraków: Ed. ZG STOP. (in Polish).
[5] Fraś, E. (2003). Crystallization of metals. Warsaw: WNT. (in Polish).
[6] Dean, N.F., Mortensen, A. & Flemings, M.C. (1994). Microsegregation in cellular solidification. Metallurgical And Materials Transactions A-Physical Metallurgy And Materials Science. A 25A, 2295-2301. DOI: 10.1007/BF 02652329.
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[8] Studnicki, A. (2008). Effect of boron carbide on primary crystallization of chromium cast iron. Archives of Foundry Engineering. 8(1), 173-176.
[9] Myszka, D. (2021). Cast Iron–Based Alloys. In: Rana, R. (eds) High-Performance Ferrous Alloys. Springer, Cham., 153-210.
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Authors and Affiliations

D. Myszka
1
Justyna Kasińska
ORCID: ORCID
A. Penkul
1

  1. Department of Metal Forming and Foundry, Warsaw University of Technology, Narbutta 85, Warsaw, Poland
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Abstract

The purpose of the work was to determine the morphology of graphite that occurs in vermicular cast iron, both in the as-cast state and after heat treatment including austenitization (held at a temperature of 890 °C or 960 °C for 90 or 150 min) and isothermal quenching (i.e. austempering, at a temperature of 290 °C or 390 °C for 90 or 150 min). In this case, the aim here was to investigate whether the heat treatment performed, in addition to the undisputed influence of the cast iron matrix on the formation of austenite and ferrite, also affects the morphology of the vermicular graphite precipitates and to what extent. The investigations were carried out for the specimens cut from test coupons cast in the shape of an inverted U letter (type IIb according to the applicable standard); they were taken from the 25mm thick walls of their test parts. The morphology of graphite precipitates in cast iron was investigated using a Metaplan 2 metallographic microscope and a Quantimet 570 Color image analyzer. The shape factor F was calculated as the quotient of the area of given graphite precipitation and the square of its perimeter. The degree of vermicularization of graphite was determined as the ratio of the sum of the graphite surface and precipitates with F <0.05 to the total area occupied by all the precipitations of the graphite surface. The examinations performed revealed that all the heat-treated samples made of vermicular graphite exhibited the lower degree of vermicularization of the graphite compared to the corresponding samples in the as-cast state (the structure contains a greater fraction of the nodular or nearly nodular precipitates). Heat treatment also caused a reduction in the average size of graphite precipitates, which was about 225μm2 for the as-cast state, and dropped to approximately 170-200 μm2 after the austenitization and austempering processes.
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Bibliography

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Authors and Affiliations

M.S. Soiński
1
A. Jakubus
1
ORCID: ORCID
B. Borowiecki
1
P. Mierzwa
2

  1. The Jacob of Paradies University in Gorzów Wielkopolski, ul. Teatralna 25, 66-400 Gorzów Wielkopolski, Poland
  2. Czestochowa University of Technology, Poland
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Abstract

The objective of the study reported in this paper was to determine the effect of structure on thermal power of cast-iron heat exchangers which in this case were furnace chambers constituting the main component of household fireplace-based heating systems and known commonly as fireplace inserts. For the purpose of relevant tests, plate-shaped castings were prepared of gray iron with flake graphite in pearlitic matrix (the material used to date typically for fireplace inserts) as well as similar castings of gray cast iron with vermicular graphite in pearlitic, ferritic-pearlitic, and ferritic matrix. For all the cast iron variants of different structures (graphite precipitate shapes and matrix type), calorimetric measurements were carried out consisting in determining the heat power which is quantity representing the rate of heat transfer to the ambient environment. It has been found that the value of the observed heat power was affected by both the shape of graphite precipitates and the type of alloy matrix. Higher thermal power values characterize plate castings of gray iron with vermicular graphite compared to plates cast of the flake graphite gray iron. In case of plates made of gray cast iron with vermicular graphite, the highest values of thermal power were observed for castings made of iron with ferritic matrix.

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Authors and Affiliations

Marek Mróz
ORCID: ORCID
A.W. Orłowicz
ORCID: ORCID
M. Tupaj
ORCID: ORCID
M. Jacek-Burek
M. Radoń
M. Kawiński
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Abstract

This paper presents a new stand for studying the linear shrinkage kinetics of foundry alloys. The stand is equipped with a laser displacement sensor. Thanks to this arrangement, the measurement is of a contactless nature. This solution allows for the elimination of errors which occur in measurements made using intermediary elements (steel rods). The supposition of the expansion (shrinkage) of the sample and the expansion of the heated rod lead to the distortion of the image of the actual dimensional changes of the studied sample. A series of studies of foundry alloys conducted using the new stand allowed a new image of shrinkage kinetics to be obtained, in particular regarding cast iron. The authors introduce in the study methodology a real-time measurement of two linked quantities; shrinkage (the displacement of the free end of the sample) and temperature in the surface layer of the sample casting. This generates not only a classic image of shrinkage (S) understood as S = f (t), but also the view S = f (T). The latter correlation, developed based on results obtained using the contactless method, provide a new, so far poorly known image of the course of shrinkage in foundry alloys, especially cast iron with graphite in the structure. The study made use of hypo- and hypereutectic cast iron in order to generate an image of the differences which occur in the kinetics of shrinkage (as well as in pre-shrinkage expansion - expansion occurs during solidification).

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Authors and Affiliations

J. Zych
ORCID: ORCID
T. Snopkiewicz
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Abstract

The study presented in this paper concerned the possibility to apply a heat treatment process to ductile cast-iron thin-walled castings in order to remove excessive quantities of pearlite and eutectic cementite precipitates and thus meet the customer’s requirements. After determining the rates of heating a casting up to and cooling down from 900°C feasible in the used production heat treatment furnace (vh = 300°C/h and vc = 200°C/h, respectively), dilatometric tests were carried out to evaluate temperatures Tgr, TAc1start, TAc1end, TAr1start, and TAr1end. The newly acquired knowledge was the base on which conditions for a single-step ferritizing heat treatment securing disintegration of pearlite were developed as well as those of a two-step ferritization process guaranteeing complete disintegration of cementite and arriving at the required ferrite and pearlite content. A purely ferritic matrix and hardness of 119 HB was secured by the treatment scheme: 920°C for 2 hours / vc = 60°C/h / 720°C for 4 hours. A matrix containing 20–45% of pearlite and hardness of 180–182 HB was obtained by applying: 920°C for 2 hours or 4 hours / vc = 200°C/h to 650°C / ambient air.

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Authors and Affiliations

Marek Mróz
ORCID: ORCID
A.W. Orłowicz
ORCID: ORCID
M. Tupaj
ORCID: ORCID
B. Kupiec
M. Kawiński
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Abstract

The article presents research on solid particle erosive wear resistance of ductile cast iron after laser surface melting. This surface treatment technology enables improvement of wear resistance of ductile cast iron surface. For the test ductile cast iron EN GJS-350-22 surface was processed by high power diode laser HPDL Rofin Sinar DL020. For the research single pass and multi pass laser melted surface layers were made. The macrostructure and microstructure of multi pass surface layers were analysed. The Vickers microhardness tests were proceeded for single pass and multi pass surface layers. The solid particle erosive test according to standard ASTM G76 – 04 with 30°, 60° and 90° impact angle was made for each multi pass surface layer. As a reference material in erosive test, base material EN GJS-350-22 was used. After the erosive test, worn surfaces observations were carried out on the Scanning Electron Microscope. Laser surface melting process of tested ductile cast iron resulted in maximum 3.7 times hardness increase caused by microstructure change. This caused the increase of erosive resistance in comparison to the base material.

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Authors and Affiliations

A. Kotarska
D. Janicki
J. Górka
ORCID: ORCID
T. Poloczek
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Abstract

The chemical composition of alloys plays an important role at their crystallization and influences the solid phase formation, and thus, microstructure and properties. The present paper studies the release of the heat of crystallization of alloyed wear-resistant cast irons in order to determine the quantitative patterns of the chemical composition influence to the kinetics of crystallization. The differential thermal analysis was applied to get the data of heat release, its rate at cast iron temperature decrease. The normalized dependence of the amount of crystallization heat over time was obtained. The main temperature parameters were analyzed and four stages at irons crystallization were established and characterized with their duration and released heat. The multiple correlation analysis allowed considering a numerous physical and chemical factors and distinguishing their role at crystallization of irons. As a result, the quantitative regularities are determined of influencing the content of alloying elements, impurities and carbides on a heat and time of crystallization at the different stages of solidification, which are of great importance in developing alloyed irons with required quality and properties.
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Authors and Affiliations

Y. Aftandiliants
1
ORCID: ORCID
S. Gnyloskurenko
1 2
ORCID: ORCID
H. Meniailo
3
ORCID: ORCID
V. Khrychikov
3
ORCID: ORCID
V. Lomakin
4
ORCID: ORCID

  1. National University of Life and Environmental Sciences of Ukraine, Ukraine
  2. Physical and Technological Institute of Metals and Alloys, National Academy of Sciences of Ukraine, Ukraine
  3. Ukrainian State University of Science and Technologies, Ukraine
  4. Central Ukrainian National Technical University, Ukraine
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Abstract

The article presents the technology of layered casting with the use of 3D printing to make a frame insert. The insert was made of powdered titanium and then filled with liquid cast iron. The paper presents the results of research, including structure observation and hardness measurements, as well as abrasion resistance tests. The results indicate the possibility of creating a local reinforcement using a frame insert. The resulting casting is characterized by a local increase in hardness and, in addition, an increase in abrasion resistance of the entire surface layer. The quality of the obtained connection depends strongly on the casting parameters.

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Authors and Affiliations

A. Dulska
ORCID: ORCID
J. Szajnar
ORCID: ORCID
M. Król
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Abstract

This paper presents the problems related to smelting gray and ductile cast iron. Special attention is paid to the metallurgical quality of cast iron. It depends on the type of furnace, charge materials and the special combination of charge, overheating and holding temperature, melting time, modification and spheroidization method. The evaluation of metallurgical quality has been performed by using derivativethermal analysis (DTA). During the smelting process and secondary metallurgy, the ITACA system was used allowing to obtain information on alloy characteristic temperatures (Tliquidus, TeMin, TeMax, Tsolidus), VPS value, recalescence value, IGQ coefficient, nucleation gauge, porosity etc. The results of investigations and calculations are displayed in the form of graphs and dependencies. It has been shown that the derivative-thermal analysis (DTA) is an effective complement of chemical analysis and it has been found that both the increase in temperature and metal holding time have a negative impact on the metallurgical quality of liquid metal. The metallurgical quality can be improved by using proper composition of charge materials and modifiers.

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Authors and Affiliations

Ł. Petrus
A. Bulanowski
J. Kołakowski
ORCID: ORCID
M. Brzeżański
ORCID: ORCID
M. Urbanowicz
J. Sobieraj
G. Matuszkiewicz
L. Szwalbe
K. Janerka
ORCID: ORCID
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Abstract

Results of a research on influence of chromium, molybdenum and aluminium on structure and selected mechanical properties of Ni-Mn-Cu cast iron in the as-cast and heat-treated conditions are presented. All raw castings showed austenitic matrix with relatively low hardness, making the material machinable. Additions of chromium and molybdenum resulted in higher inclination to hard spots. However, a small addition of aluminium slightly limited this tendency. Heat treatment consisting in soaking the castings at 500 °C for 4 h resulted in partial transformation of austenite to acicular, carbon-supersaturated ferrite, similar to the bainitic ferrite. A degree of this transformation depended not only on the nickel equivalent value (its lower value resulted in higher transformation degree), but also on concentrations of Cr and Mo (transformation degree increased with increasing total concentration of both elements). The castings with the highest hard spots degree showed the highest hardness, while hardness increase, caused by heat treatment, was the largest in the castings with the highest austenite transformation degree. Addition of Cr and Mo resulted in lower thermodynamic stability of austenite, so it appeared a favourable solution. For this reason, the castings containing the highest total amount of Cr and Mo with an addition of 0.4% Al (to reduce hard spots tendency) showed the highest tensile strength.

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Authors and Affiliations

Daniel Medyński
ORCID: ORCID
A. Janus
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Abstract

The article discusses benefits associated with the use of silicon carbide in the process of melting gray cast iron and ductile cast iron in induction electric furnaces. It presents the analysis of the impact of various charge materials and the addition of a variable amount of SiC and FeSi to the fixed charge when melting cast iron of grades GJS 400-15 and GJS 500-7 on mechanical properties and microstructure. Moreover, the article includes an analysis of the efficiency of carburization and the increase in the content of silicon during the application of SiC. The article also presents the results of the study of primary modification using silicon carbide at the minimum temperature of Temin eutectic and Tsol solidus. Based on analysis of the literature, conducted research, and calculations, it was found that the addition of silicon carbide has a beneficial impact on the properties of melted cast iron. The addition of SiC in the charge increases the content of C and Si without increasing the amount of contaminations. The addition of SiC at reduced pig iron presence in the charge decreases production costs, while the use of SiC as an inoculant increases both Temin and Tsol, which is beneficial from the point of view of cast iron nucleation.
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Authors and Affiliations

K. Janerka
1
ORCID: ORCID
Ł. Kostrzewski
2
ORCID: ORCID
M. Stawarz
1
ORCID: ORCID
J. Jezierski
1
ORCID: ORCID
J. Szajnar
1
ORCID: ORCID

  1. Silesian University of Technology, Department of Foundry Engineering, 7 Towarowa Str., 44-100 Gliwice, Poland
  2. Leszczyńska Fabryka Pomp, 15 Fabryczna Str., 64-100 Leszno, Poland
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Abstract

This paper deals with the issue of using moulding sands with a new two-component binder: furfuryl-resole resin – PCL polycaprolactone for the production of ductile iron heavy castings. The previous laboratory studies showed the possibility of using biodegradable materials as binders or parts of binders’ compositions for foundry moulding and core sands. The research proved that addition of new biodegradable PCL in the amount of 5% to the furfuryl-resole resin does not cause significant changes in moulding sand’s properties. The article presents research related to the production of ductile iron castings with the use of moulds with a modified composition, i.e. sands with furfuryl resole resin with and without PCL. Mechanical properties and microstructure of the casting surface layer at the metal/ mould interface are presented. The obtained test results indicate that the use of a biodegradable additive for making foundry moulds from moulding sand with a two-component binder does not deteriorate the properties of ductile iron castings.
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Authors and Affiliations

M. Hosadyna-Kondracka
1
ORCID: ORCID
K. Major-Gabryś
2
ORCID: ORCID
M. Warmuzek
1
ORCID: ORCID
M. Brůna
3
ORCID: ORCID

  1. Lukasiewicz Research Network – Krakow Institute of Technology, 73 Zakopiańska Str., 30-418 Krakow, Poland
  2. AGH University of Science and Technology, Faculty of Foundry Engineering, Department of Moulding Materials, Mould Technology and Foundry of Non-ferrous Metals, Al. Mickiewicza 30, 30-059 Krakow, Poland
  3. University of Žilina, Department of Technological Engineering, Faculty of Mechanical Engineering, Univerzitná 1, 010 26, Slovak Republic
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Abstract

Chunky graphite has been recognized for a long time as one of the major problems in production of heavy section nodular cast iron. A great number of studies have been conducted to describe the chunky graphite formation, but a clear understanding of its appearance and a safe mastering of the melt preparation to avoid chunky graphite are not yet available. In the present work the cooling curves were recorded in large cone blocks and standard TA cup. According to measured data from the cone block, melt characteristics and heat transfer coefficient between casting and mould were adjusted in the ProCAST® simulation software. For a near-eutectic nodular cast iron test melt with 0.7 wt. % Ni, relationship between the area of the cone block affected by chunky graphite and simulation software results has been observed, i.e., thermal modulus and time to solidus.

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Authors and Affiliations

B. Bauer
I. Mihalic Pokopec
M. Petrič
P. Mrvar
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Abstract

Material suppliers typically recommend different additive amounts and applications for foundry practices. Therefore, even in the production of the same standard materials, different results may be obtained from various production processes on different foundry floors. In this study, the liquid metal prepared with the addition of different proportions of a FeSi-based inoculation, which is most commonly used in foundries in the production of a cast iron material with EN-GJL-250 lamellar graphite cast iron, was cast into sand molds prepared with a model designed to provide different solidification times. In this way, the optimization of the inoculation amounts on the casting structure for different solidification times was investigated. In addition, hardness values were determined depending on solidification time in varying amounts of inoculation additions. SolidCast casting simulation software was used to determine the casting model geometry and solidification time. In the scope of the study, sand casting, modeling, microstructure analysis, image analysis, microstructure analysis, and hardness tests techniques were used. When the results are examined, the required amount of inoculation for the optimal structure is optimized for the application procedure depending on the casting module and the solidification time.
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Authors and Affiliations

M. Çolak
1
ORCID: ORCID
E. Uslu
1
ORCID: ORCID
Ç. Teke
1
ORCID: ORCID
F. Şafak
2
Ö. Erol
2
Y. Erol
2
Y. Çoban
2 3
M. Yavuz

  1. Bayburt University, Turkey
  2. Konya Technical University, Turkey
  3. Yavuzsan A.Ş., Turkey

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