The purpose of the study was to optimize the removal of Cr(VI) by means of the Trichoderma viride strain isolated from chromium mud samples a well as the Aspergillus niger and Penicillium citrinum strains from other environments. The growth of organism and removal of chromium(VI) was carried out in water solution of various chromium(VI) contents. The research was carried out at optimal pH for each fungus i.e. Aspergillus niger 4.0, Penicillium citrinum 5.0 and Trichoderma viride 4.5. During 14 days of incubation, samples of 5 ml each were collected every day in order to determine chromium(VI) content in the solution and the efficiency of bioaccumulation of this element was then specified. Furthermore, chromium contents in filtrate and mycelium were checked to verify this type of biological activity of microorganisms. The fungi culture investigated in this study could grow at 10-125 mg/l chromium concentration which indicated that it was characterized by high tolerance to various concentrations of chromium. At 125 mg/l chromium, these organisms could accumulate successfully about 90% of chromium. High tolerance of this culture can make it a potential candidate to be a heavy metal scavenger of chromium.
Three chromium resistant bacterial strains, Pseudomonas fluorescens PF28, Enterobacter amnigenus EA31 and Enterococcus gallinarum S34 isolated from tannery waste contaminated soil were used in this study. All strains could resist a high concentration of K2Cr2O7 that is up to 300 mg/L. The effect of these strains on clover plants (Trifolium campestre) in the presence of two chromium salts CrCl3 and K2Cr2O7 was studied in soil microcosm. Application of chromium salts adversely affected seed germination, root and shoot length. Bacterial inoculation improved the growth parameters under chromate stress when compared with non inoculated respective controls. There was observed more than 50% reduction of Cr(VI) in inoculated soil microcosms, as compared to the uninoculated soil under the same conditions. The results obtained in this study are significant for the bioremediation of chromate pollution.
Three different types of Fe(II)-modified natural zeolites were tested as supports in continuous-flow columns for the treatment of Cr(VI) contaminated water. The natural zeolites chosen as support were commercially available Zeosand (80% clinoptilolite), ATZ (79% phillipsite/chabazite), and ZS-55RW (90% Chabazite). All the examined modified zeolites turned out active for hexavalent chromium abatement, lowering its concentration below the European regulation level, even at relatively high flow rates (40 mL/h, linear velocity 15 cm/h). Zeosand, having a broader pH range of stability, was found to be the best one in terms of both Fe(II) uptake (0.54 wt%) and Cr removal (90 mg Cr/Kg zeolite).
The paper deals with the issue of potential for improvement of resistance of wood chip fine grinders to abrasive wear by providing them with WCCoCr coating applied with the use of atmospheric plasma spraying (APS). The study focused on establishing parameters of the technological process of spraying a 250–270 μm thick coating onto surface of ductile cast iron castings used to date as grinder linings. The presented data include results of microstructure examination, chemical composition analysis, HV hardness measurements, and scratch tests for both previous and new variant of linings. The obtained scratch test results indicate that the material of the coating is characterized with definitely lower susceptibility to scratching. The scratch made on coating was 75–84 μm wide and 7.2–8.2 μm deep, while the scratch on cast iron was distinctly wider (200–220 μm) and deeper (8.5–12.8 μm). In case of cast iron, the range of variability in scratch width and depth was definitely larger. This can be explained with large difference in hardness of individual components of microstructure of cast iron and significantly larger plastic deformation of cast iron compared to the coating revealed in the course of indenter motion over surfaces of the two materials. It has been found that application of WCCoCr coating offered better resistance of lining surfaces to scratching which can be considered a rationale for undertaking in-service tests.
This paper presents results of experimental research concerning the impact of an innovative method of micro-jet cooling on the padding
weld performed with MIG welding. Micro-jet cooling is a novel method patented in 2011. It enables to steer the parameters of weld
cooling in a precise manner. In addition, various elements which may e.g. enhance hardness or alter tribological properties can be entered
into its top surface, depending on the applied cooling gas. The material under study was steel 20MnCr5, which was subject to the welding
process with micro-jet cooling and without cooling. Nitrogen was used as a cooling gas. The main parameter of weld assessment was wear
intensity. The tests were conducted in a tribological pin-on-disc type position. The following results exhibit growth at approximately 5% in
wear resistance of padding welds with micro-jet cooling.
The work deal with an assembling and comparing of transformation diagrams of two low-alloy steels, specifically 16MnCrS5 and 20MnCrS5. In this work, diagrams of the type of CCT and DCCT of both steels were assembled. Transformation diagrams were assembled on the basis of dilatometric tests realized on the plastometer Gleeble 3800, of metallographic analyses and of hardness measurements. In addition, for comparison, the transformation diagrams were assembled even with use of the QTSteel 3.2 software. Uniform austenitization temperature of 850°C was chosen in case of both steels and even both types of diagrams. In case of both steels, an influence of deformation led to expected acceleration of phase transformations controlled by diffusion and also of bainite transformation. In both cases, the kinetics of martensitic transformation was not significantly affected by deformation.
A thermo-insulating moulding sand with a binder made of aluminosilicate microspheres with organic binder was subjected to testing. The aim of the analysis was to determine selected technological properties of the developed compounds. Compressive strength, friability and gas permeability were determined. The binder content was changed within a range of 5÷20 wt% with a 5% step. The applied matrix is characterized by good thermo-insulating properties and a small size of grains, while synthetic organic binder has favourable functional properties, among which the most noteworthy are the extended life and setting time, good rheological properties as well as high resistance to chemical agents. The intended use of the compound is the casting of 3D CRS (Composite Reinforced Skeletons), which are characterized by a well-developed heat transfer surface area, good absorption of impact energy, low mass and a target thickness of connectors within a range of 1.5÷3 mm. The construction of 3D CRS castings is an original concept developed by the employees of the Department of Foundry Engineering at the Silesian University of Technology.
Cast stainless steel of the Cr-Ni duplex type is used, among others, for the cast parts of pumps and valves handling various chemically
aggressive media. Therefore, the main problem discussed in this article is the problem of abrasion wear resistance in a mixture of SiC and
water and resistance to electrochemical corrosion in a 3% NaCl- H2O solution of selected cast steel grades, i.e. typical duplex cast steel,
high silicon and manganese duplex cast steel, and Cr-Ni austenitic cast steel (type AISI 316L). The study shows that the best abrasion
wear resistance comparable to Ni-Hart cast iron was obtained in the cast duplex steel, where Ni was partially replaced with Mn and N.
This cast steel was also characterized by the highest hardness and matrix microhardness among all the tested cast steel grades. The best
resistance to electrochemical corrosion in 3% NaCl- H2O solution showed the cast duplex steel with high content of Cr, Mo and N. The
addition of Ni plays rather insignificant role in the improvement of corrosion resistance of the materials tested.
The results of research on stereological parameters of carbides in modified hypoeutectic chromium cast iron were shown in the paper. The
effect of distance the casting heat centre of casting to the carbide phase morphology was examined. The samples for metallographic
examination were taken from various locations of the model casting prepared in a special tester. This model casting was designed to
simulate the solidification of heavy castings. Using the proposed methodology the relation of the distance from the model mould and the
size, perimeter, length, width and the shape factor of carbides was examined. During the analysis, the values of stereological parameters of
carbides changed on various sections of the model casting.