Search results

Filters

  • Journals
  • Authors
  • Keywords
  • Date
  • Type

Search results

Number of results: 66
items per page: 25 50 75
Sort by:
Download PDF Download RIS Download Bibtex

Abstract

High pressure die casting (HDPC) allows to produce aluminum parts for car industry of complicated shapes in long series. Dies used in this process must be robust enough to withstand long term injection cycling with liquid aluminum alloys, as otherwise their defects are imprinted on the product making them unacceptable. It is expected that nitriding followed by coating deposition (duplex treatment) should protect them in best way and increase intervals between the cleaning/repairing operations. The present experiment covered investigations of the microstructure of the as nitride and deposited with CrAlN coating as well as its shape after foundry tests. The observations were performed with the scanning and transmission electron microscopy (SEM/TEM) method. They showed that the bottom part of this bi-layer is formed by roughly equi-axed Cr2N crystallites, while the upper one with the fine columnar (CrAl)N crystallites. This bi-layers were matched with a set of 7x nano-layers of CrN/(CrAl)N, while at the coating bottom a CrN buffer layer was placed. The foundry run for up to 19 500 cycles denuded most of coated area exposed to fast liquid flow (40 m/s) but left most of bottom part of the coating in the areas exposed to slower flow (7 m/s). The acquired data indicated that the main weakness of this coating was in its porosity present both at the columnar grain boundaries (upper layer) as well as at the bottom of droplets imbedded in it (both layers). They nucleate cracks propagating perpendicularly and the latter at an angle or even parallel to the substrate. The most crack resistant part of the coating turned-out the bottom layer built of roughly equiaxed fine Cr2N crystallites. Even application of this relatively simple duplex protection in the form of CrAlN coating deposited on the nitride substrate helped to extend the die run in the foundry by more than three times.
Go to article

Authors and Affiliations

A. Wilczek
1
J. Morgiel
2
ORCID: ORCID
A. Sypień
2
ORCID: ORCID
M. Pomorska
2
ORCID: ORCID
Ł. Rogal
2
ORCID: ORCID

  1. Limatherm S.A., Tarnowska Str. 1, 34-600 Limanowa , Poland
  2. Institute of Metallurgy and Materials Science Polish Academy of Science, 25 Reymonta Str., 30-059 Krakow, Poland
Download PDF Download RIS Download Bibtex

Abstract

The purpose of the study was to optimize the removal of Cr(VI) by means of the Trichoderma viride strain isolated from chromium mud samples a well as the Aspergillus niger and Penicillium citrinum strains from other environments. The growth of organism and removal of chromium(VI) was carried out in water solution of various chromium(VI) contents. The research was carried out at optimal pH for each fungus i.e. Aspergillus niger 4.0, Penicillium citrinum 5.0 and Trichoderma viride 4.5. During 14 days of incubation, samples of 5 ml each were collected every day in order to determine chromium(VI) content in the solution and the efficiency of bioaccumulation of this element was then specified. Furthermore, chromium contents in filtrate and mycelium were checked to verify this type of biological activity of microorganisms. The fungi culture investigated in this study could grow at 10-125 mg/l chromium concentration which indicated that it was characterized by high tolerance to various concentrations of chromium. At 125 mg/l chromium, these organisms could accumulate successfully about 90% of chromium. High tolerance of this culture can make it a potential candidate to be a heavy metal scavenger of chromium.

Go to article

Authors and Affiliations

Anna Hołda
Download PDF Download RIS Download Bibtex

Abstract

An influence of a decreased Cr content on the microstructure of the highly alloyed Cr-Ni cast steel, duplex type, melted under laboratory conditions, was characterized in the paper. The microstructure investigations were performed in the initial state and after the heat treatment (solution annealing) at 1060°C as well as the phase transformation kinetics at continuous cooling was measured. The wear resistance of the investigated cast steel was tested and compared with the 24%Cr-5%Ni-2.5%Mo cast steel. The Cr content decrease, in ferritic-austenitic cast steels (duplex), from 24-26%Cr to 18% leads to the changes of the castings microstructure and eliminating of a brittle σ phase. In dependence of the casting cooling rate, apart from ferrite and austenite, also fine martensite precipitates occur in the casting structure. It was shown that the investigated cast steel is characterised by a slightly lower wear resistance than the typical cast steel duplex grades.
Go to article

Authors and Affiliations

B. Kalandyk
Download PDF Download RIS Download Bibtex

Abstract

A Cu-1Cr-0.1Zr alloy has been subjected to ECAP processing via route Bc and aging at 250-800°C. Electron BackScatter diffraction (EBSD), Transmission Electron Microscopy (TEM) and X-Ray Diffraction Line Profile Analysis (XRDLPA) techniques have been used to unveil some peculiarities of the grain and subgrain structure with a special emphasis on the comparison of the grain size estimated by the three techniques. For the alloy ECAP processed and aged up to 16 passes, the grain size (from EBSD, 0.2 < d < 5 μm), subgrain size (from TEM, d ~ 0.75 μm) and “apparent” average crystallite size (from XRDLPA, d < 0.25 μm) are manifestly different. The results were compared to the published data and analyzed based on the fundamental aspects of these techniques.
Go to article

Authors and Affiliations

K. Abib
1
ORCID: ORCID
B. Alili
1
ORCID: ORCID
T. Baudin
2
ORCID: ORCID
A.-L. Helbert
2
ORCID: ORCID
F. Brisset
2
ORCID: ORCID
L. Litynska-Dobrzynska
3
ORCID: ORCID
P. Zieba
3
ORCID: ORCID
D. Bradai
1
ORCID: ORCID

  1. University Of Sciences And Technology Houari Boumediene, Faculty Of Physics, Bp 32 El Alia, Bab Ezzouar, Algiers, Algeria
  2. University Paris-Saclay, Icmmo, 91405, Orsay, France
  3. Institute Of Meta llurgy And Mat erials Science, Polish Academy Of Sciences, 25 Reymonta Str., 30-059 Krakow, Poland
Download PDF Download RIS Download Bibtex

Abstract

Three chromium resistant bacterial strains, Pseudomonas fluorescens PF28, Enterobacter amnigenus EA31 and Enterococcus gallinarum S34 isolated from tannery waste contaminated soil were used in this study. All strains could resist a high concentration of K2Cr2O7 that is up to 300 mg/L. The effect of these strains on clover plants (Trifolium campestre) in the presence of two chromium salts CrCl3 and K2Cr2O7 was studied in soil microcosm. Application of chromium salts adversely affected seed germination, root and shoot length. Bacterial inoculation improved the growth parameters under chromate stress when compared with non inoculated respective controls. There was observed more than 50% reduction of Cr(VI) in inoculated soil microcosms, as compared to the uninoculated soil under the same conditions. The results obtained in this study are significant for the bioremediation of chromate pollution.

Go to article

Authors and Affiliations

Hanane Sayel
Nezha Tahri Joutey
Wifak Bahafid
Naima El Ghachtouli
Download PDF Download RIS Download Bibtex

Abstract

Three different types of Fe(II)-modified natural zeolites were tested as supports in continuous-flow columns for the treatment of Cr(VI) contaminated water. The natural zeolites chosen as support were commercially available Zeosand (80% clinoptilolite), ATZ (79% phillipsite/chabazite), and ZS-55RW (90% Chabazite). All the examined modified zeolites turned out active for hexavalent chromium abatement, lowering its concentration below the European regulation level, even at relatively high flow rates (40 mL/h, linear velocity 15 cm/h). Zeosand, having a broader pH range of stability, was found to be the best one in terms of both Fe(II) uptake (0.54 wt%) and Cr removal (90 mg Cr/Kg zeolite).

Go to article

Authors and Affiliations

Antonio Lofù
Piero Mastrorilli
Maria Michela Dell’Anna
Matilda Mali
Raffaello Sisto
Rodolfo Vignola
Download PDF Download RIS Download Bibtex

Abstract

Thermal analysis allows for determination of temperature specific for the beginning and the end of phase transitions occurring in studied samples. In this paper results obtained from DTA (Differential Thermal Analysis) of alloys of chemical composition referring to nickel-rich part of Ni-Al-Cr system, specifically from section Ni75Al25÷Ni65Cr35 are presented. Those alloys are based on intermetallic phase Ni3Al. Referring to measurements obtained during heating and cooling, characteristic peaks related to occurrence of phase transition of order-disorder type were noted as well as melting and solidification temperature of alloys was determined. Results of thermal analysis DTA of studied range were compared with results obtained for section Ni75Al25÷Ni75Cr25 and Ni75Al25÷Ni87Cr13, additionally results of measurements performed on high-temperature solution calorimeter were collated. Both methods presented good compatibility.
Go to article

Authors and Affiliations

T. Maciąg
Download PDF Download RIS Download Bibtex

Abstract

The paper deals with the issue of potential for improvement of resistance of wood chip fine grinders to abrasive wear by providing them with WCCoCr coating applied with the use of atmospheric plasma spraying (APS). The study focused on establishing parameters of the technological process of spraying a 250–270 μm thick coating onto surface of ductile cast iron castings used to date as grinder linings. The presented data include results of microstructure examination, chemical composition analysis, HV hardness measurements, and scratch tests for both previous and new variant of linings. The obtained scratch test results indicate that the material of the coating is characterized with definitely lower susceptibility to scratching. The scratch made on coating was 75–84 μm wide and 7.2–8.2 μm deep, while the scratch on cast iron was distinctly wider (200–220 μm) and deeper (8.5–12.8 μm). In case of cast iron, the range of variability in scratch width and depth was definitely larger. This can be explained with large difference in hardness of individual components of microstructure of cast iron and significantly larger plastic deformation of cast iron compared to the coating revealed in the course of indenter motion over surfaces of the two materials. It has been found that application of WCCoCr coating offered better resistance of lining surfaces to scratching which can be considered a rationale for undertaking in-service tests.

Go to article

Authors and Affiliations

A.W. Orłowicz
M. Mróz
M. Tupaj
B. Kupiec
M. Jacek
M. Radoń
Download PDF Download RIS Download Bibtex

Abstract

This paper presents results of experimental research concerning the impact of an innovative method of micro-jet cooling on the padding

weld performed with MIG welding. Micro-jet cooling is a novel method patented in 2011. It enables to steer the parameters of weld

cooling in a precise manner. In addition, various elements which may e.g. enhance hardness or alter tribological properties can be entered

into its top surface, depending on the applied cooling gas. The material under study was steel 20MnCr5, which was subject to the welding

process with micro-jet cooling and without cooling. Nitrogen was used as a cooling gas. The main parameter of weld assessment was wear

intensity. The tests were conducted in a tribological pin-on-disc type position. The following results exhibit growth at approximately 5% in

wear resistance of padding welds with micro-jet cooling.

Go to article

Authors and Affiliations

T. Węgrzyn
W. Tarasiuk
J. Piwnik
D. Sieteski
Download PDF Download RIS Download Bibtex

Abstract

The work deal with an assembling and comparing of transformation diagrams of two low-alloy steels, specifically 16MnCrS5 and 20MnCrS5. In this work, diagrams of the type of CCT and DCCT of both steels were assembled. Transformation diagrams were assembled on the basis of dilatometric tests realized on the plastometer Gleeble 3800, of metallographic analyses and of hardness measurements. In addition, for comparison, the transformation diagrams were assembled even with use of the QTSteel 3.2 software. Uniform austenitization temperature of 850°C was chosen in case of both steels and even both types of diagrams. In case of both steels, an influence of deformation led to expected acceleration of phase transformations controlled by diffusion and also of bainite transformation. In both cases, the kinetics of martensitic transformation was not significantly affected by deformation.

Go to article

Authors and Affiliations

R. Kawulok
P. Kawulok
I. Schindler
P. Opěla
S. Rusz
V. Ševčák
Z. Solowski
Download PDF Download RIS Download Bibtex

Abstract

In this study, NiCrBSi-B4C (wt. %5, %10 ve %15 B4C) powder mixtures are coated on the stainless steel surface of AISI304 by tungsten inert gas (TIG) method. We use optic microscope and scanning electron microscope (SEM) for the coating layer analysis, energy dispersive spectrometry (EDS) for element distribution analysis and X-ray diffractogram (XRD) for the analysis of phase components. The measurements of hardness are determined by the microhardness tester. Based on the results obtained by the examination of microstructure and phases, it has been observed that while B and C elemets are more intense in the middle and upper parts of the coating layer, the parts close to the interface have a higher intensity of Ni and Fe. Moreover, there are phases such as Cr7C3, γ – Ni, CrFeB, Ni3B, CrB ve Fe2B are formed in the coating layer. The increasing ratio of B4C results in increasing on the measurement values of microhardness. The maximum hardness value (430,8 HV0.2) is obtained from the coating layer of S4 sample while the minimum value (366,9 HV0.2) is observed from the NiCrBSi coated sample.
Go to article

Bibliography

[1] R. Rachidi, B. El Kihel, F. Delaunois, Mater. Sci. Eng. B-Adv. 241, 13-21 (2019).
[2] H. Zhao, J. Li, Z. Zheng, A. Wang, D. Zeng, Y. Miao, Surf. Coat. Tech. 286, 303-312 (2016).
[3] C.K. Sahoo, M. Masanta, J. Mater Process Tech. 240, 126-137 (2017).
[4] Q. An, L. Huang, S. Jiang, X. Li, Y. Gao, Y. Liu, L. Geng, Vacuum. 145, 312-319 (2017).
[5] J.-S. Meng, G. Jin, X.-P. Shi, Appl. Surf. Sci. 431, 135-142 (2018).
[6] S . Buytoz, M. Ulutan, M.M. Yildirim, Appl. Surf. Sci. 252, 1313- 1323 (2005).
[7] J. Yin, D. Wang, L. Meng, L. Ke, Q. Hu, X. Zeng, Surf. Coat. Tech. 325, 120-126 (2017).
[8] J. Rodriguez, A. Martı́n, R. Fernández, J.E. Fernández, Wear. 255, 950-955 (2003).
[9] N.L. Parthasarathi, M. Duraiselvam, J. Alloy Compd. 505, 824- 831 (2010).
[10] S . Abdi, S. Lebaili, Phys. Procedia. 2, 1005-1014 (2009).
[11] M.J. Tobar, C. Álvarez, J.M. Amado, G. Rodríguez, A. Yáñez, Surf. Coat. Tech. 200, 6313-6317 (2006).
[12] N.Y. Sari, M. Yilmaz, Surf. Coat. Tech. 202, 3136-3141 (2008).
[13] E. Fernández, M. Cadenas, R. González, C. Navas, R. Fernández, J. de Damborenea, Wear 259, 870-875 (2005).
[14] S . Buytoz, GU J. Sci., Part C. 8, 51-63 (2020).
[15] X.-N. Wang, X.-M. Chen, Q. Sun, H.-S. Di, Mater. Lett. 206, 143-145 (2017).
[16] K.A. Habib, D.L. Cano, José Antonio Heredia, J.S. Mira, Surf. Coat. Tech. 358, 824-832 (2019).
[17] L.-Y. Chen, T. Xu, H. Wang, P. Sang, L.-C. Zhang, Surf Coat Tech. 358, 467-480(2019).
[18] Q.W. Meng, T.L. Geng, B.Y. Zhang, Surf. Coat. Tech. 200, 4923- 4928 (2006).
[19] Y.-X. Zhou, J. Zhang, Z.-G. Xing, H.-D.Wang, Z.-L. Lv, Surf. Coat. Tech. 361, 270-279 (2019).
[20] M. Kilic, A. Imak, I Kirik, JMEPEG. 30, 1411-1419 (2021).
[21] K. Kılıçay, S. Buytoz, M. Ulutan, Surf. Coat. Tech. 397, 125974 (2020).
[22] M.-J.Chao, X. Niu, B. Yuan, E.-J. Liang, D.-S. Wang, Surf. Coat. Tech. 201, 1102-1108 (2006).
[23] Y. Z., T. Yu, L. Chen, Y. Chen, C. Guan, J. Sun, Ceram. Int. 46, 25136-25148 (2020).
[24] L. Guo-lu, L. Ya-long, D. Tian-shun, F. Bin-Guo, Wang Hai-dou, Zheng Xiao-dong, Zhou Xiu-kai, Vacuum. 156, 440-448 (2018).
[25] S. Buytoz, M. Ulutan, M.M. Yıldırım, Eng. & Arch. Fac .Osmangazi University XVIII, 93-107 ( 2005).
[26] M. Kilic, European Journal of Technique (EJT) 10, 106-118 (2020).
[27] Guo-lu Li, Ya-long Li, Tian-shun Dong, Hai-dou Wang, Xiao-dong Zheng, Xiu-kai Zhou, Hindawi Advances in Materials Science and Engineering 2018, Article ID 8979678, 1-10 (2018).
[28] M. Storozhenko, O. Umanskyi, V. Krasovskyy, M. Antonov, O. Terentjev, J. Alloy Compd. 778, 15-22 (2019).
[29] A. Zabihi, R. Soltani, Surf. Coat. Tech. 349, 707-718 (2018).
Go to article

Authors and Affiliations

Musa Kiliҫ
1
ORCID: ORCID

  1. Batman University, Faculty of Technology, Department of Manufacturing Engineering, Batman, Turkey
Download PDF Download RIS Download Bibtex

Abstract

The paper projects the potential of agricultural waste Saraca indica leaf powder (SILP) in biosorbing chromium from aqueous system. The influence of pH, contact time, metal concentration, biomass dosage and particle size on the selectivity of the removal process was investigated. The maximum sorption efficiency of SILP for Cr(lll): 85.23% and Cr(VI): 89.67%was found to be pH dependent giving optimum sorption at pH 6.5 and 2.5 respectively. The adsorption process fitted well to both Freundlich and Langmuir isotherms. Morphological changes observed in Scanning Electron Micrographs ofmetal treated biomass confirm the existence of biosorption phenomenon. Fourier Transform Infra-red Spectrometry confirms that amino acid-Cr interactions contribute a significant role in the biosorption of chromium using target leafpowder. The successful applications of easily abundant agricultural waste SILP, as a biosorbent have potential for a low technological pretreatment step, prior to economically not viable high-tech chemical treatments for the removal of Cr from water bodies.
Go to article

Authors and Affiliations

Pritee Goyal
Parul Sharma
Shalini Srivastava
M.M. Srivastava
Download PDF Download RIS Download Bibtex

Abstract

The 22Cr25NiWCoCu austenitic stainless steel was developed by AB Sandvik Material Technology in Sweden. Due to its high creep strength and good corrosion resistance, this material is well suited for use in superheaters in advanced coal-fired power boilers as well as in other types of steam boilers using various types of fuel. The examined material was subject to long-term ageing for the time of annealing up to 20 000 h at 700 and 750°C. Precipitation processes and microstructure stability as-received and after ageing were investigated. Examination of the microstructure was conducted using scanning electron microscopy. The identification of secondary phases was carried out by X-ray phase composition.
Using the results of the investigations of precipitation processes in the microstructure, both within the grains and at the grain boundaries, their statistical analysis was carried out. To illustrate this impact, the following parameters were used: surface area and equivalent diameter of precipitates. Based on the surface area measurements, the percentage of the phase in the reviewed photo’s total area was calculated.
Go to article

Authors and Affiliations

M. Sroka
1
ORCID: ORCID
A. Zieliński
2
ORCID: ORCID
T. Puszczało
1 3
ORCID: ORCID
K. Sówka
1 3
ORCID: ORCID
B. Hadzima
4

  1. Silesian University of Technology, Department of Engineering Materials and Biomaterials, S. Konarskiego 18A, 44-100 Gliwice, Poland
  2. Łukasiewicz Research Network – Institute for Ferrous Metallurgy, K. Miarki 12-14, 44-100 Gliwice, Poland
  3. ZRE, ul. Gen. Jankego 13, 40-615 Katowice, Poland
  4. University of Žilina, Univerzitná 8215/1, 010 26 Žilina, Slovakia
Download PDF Download RIS Download Bibtex

Abstract

A thermo-insulating moulding sand with a binder made of aluminosilicate microspheres with organic binder was subjected to testing. The aim of the analysis was to determine selected technological properties of the developed compounds. Compressive strength, friability and gas permeability were determined. The binder content was changed within a range of 5÷20 wt% with a 5% step. The applied matrix is characterized by good thermo-insulating properties and a small size of grains, while synthetic organic binder has favourable functional properties, among which the most noteworthy are the extended life and setting time, good rheological properties as well as high resistance to chemical agents. The intended use of the compound is the casting of 3D CRS (Composite Reinforced Skeletons), which are characterized by a well-developed heat transfer surface area, good absorption of impact energy, low mass and a target thickness of connectors within a range of 1.5÷3 mm. The construction of 3D CRS castings is an original concept developed by the employees of the Department of Foundry Engineering at the Silesian University of Technology.

Go to article

Authors and Affiliations

K. Stec
Marian Cholewa
Ł. Kozakiewicz
Download PDF Download RIS Download Bibtex

Abstract

This paper presents the possibility of improving the scratch resistance of the AZ91 magnesium alloy by applying a WCCoCr coating using the Air Plasma Spraying (APS) method. The coating thickness ranged from 140 to 160 m. Microstructural studies of the AZ91 magnesium alloy were performed. The chemical composition of the WCCoCr powder was investigated. The quality of the bond at the substrate–coating interface was assessed and a microanalysis of the chemical composition of the coating was conducted. The scratch resistance of the AZ91 alloy and the WCCoCr coating was determined. The scratch resistance of the WCCoCr powder-based coating is much higher than the AZ91 alloy, as confirmed by scratch geometry measurements. The scratch width in the coating was almost three times smaller compared to the scratch in the substrate. Observations of the substrate–coating interface in the scratch area indicate no discontinuities. The absence of microcracks and delamination at the transition of the scratch from the substrate to the coating indicates good adhesion. On the basis of the study, it was found that there was great potential to use the WCCoCr powder coating to improve the abrasion resistance of castings made from the AZ91 alloy.
Go to article

Bibliography

[1] Wanhill, R.J.H. (2017). Carbon fibre polymer matrix structural composites. Aerospace Materials and Material Technologies. 1, 309-341. https://doi.org/10.1007/978-981-10-2134-3_14.
[2] Dziadoń, A. & Mola, R. (2013). Magnesium – directions of shaping mechanical properties. Obróbka plastyczna Metali. XXIV(4). (in Polish).
[3] Mordike, B.L. & Ebert, T. (2001). Magnesium: Properties – application – potential. Materials Science and Engineering. 302(1), 37-45. DOI: 10.1016/S0921-5093(00)01351-4.
[4] Wang, G.G. & Weiler, J.P. (2023). Recent developments in high pressure die-cast magnesium alloys for automotive and future applications. Journal of Magnesium and Alloys. 11(1), 78 87. DOI: doi.org/10.1016/j.jma.2022.10.001.
[5] Liu, B., Yang, J., Zhang, X., Yang, Q., Zhang, J., Li, X. (2022). Development and application of magnesium alloy parts for automotive OEMs: A review. Journal of Magnesium and Alloys. 11(1), 15-47. DOI: 10.1016/j.jma.2022.12.015.
[6] Janik, B. (2011). Application of magnesium alloys in aviation. Prace Instytutu Lotnictwa. 57(221), 102-108. (in Polish).
[7] Prasad, S.V.S., Prasad, S.B., Verma, K., Mishra, R.K., Kumar, V. & Singh, S. (2021). The role and significance of Magnesium in modern day research – A review. Journal of Magnesium and alloys. 10(1), 1-61. DOI: 10.1016/j.jma.2021.05.012.
[8] Blawert, C., Hort, N. & Kainer, K.U. (2004). Automotive applications of magnesium and its alloys. Transaction of the Indian Institute of Metals. 57(4), 397-408.
[9] Chen, H. & Alpas A.T. (2000). Sliding wear map for the magnesium alloy Mg-9Al-0.9Zn (AZ91). Wear. 246(1-2), 106-116. DOI: 10.1016/S0043-1648(00)00495-6.
[10] Walczak, M., Caban, J. & Pliżga, P. (2015). Tribological characteristic of magnesium alloys used in means of transport. TTS Technika Transportu Szynowego. 22(12), 1614-1617.
[11] Parco, M., Zhao, L., Zwick, J., Bobzin, K. & Lugscheider, E. (2007). Investigation of particle flattening behaviour and bonding mechanisms of APS sprayed coatings on magnesium alloys. Surface and Coating Technology. 201(14), 6290-6296. DOI: 10.1016/j.surfcoat.2006.11.034.
[12] Morelli, S., Rombol`a, G., Bolelli, G., Lopresti, M., Puddu, P, Boccaleri, E., Seralessandri, L., Palin, L., Testa, V., Milanesio, M. & Lusvarghi, L. (2022). Hard ultralight systems by thermal spray deposition of WC-CoCr onto AZ31 magnesium alloy. Surface and Coating Technology. 451, 129056 1-26. DOI.org/10.1016/j.surfcoat.2022.129056.
[13] Gray, J.E. & Luan, B. (2002). Protective coatings on magnesium and its alloys – a critical review. Journal of Allys and Compounds. 336(1-2), 88-113. DOI: 10.1016/S0925 8388(01)01899-0.
Go to article

Authors and Affiliations

Marek Mróz
1
ORCID: ORCID
Sylwia Olszewska
1
ORCID: ORCID
Patryk Rąb
1
ORCID: ORCID

  1. Rzeszow University of Technology, Poland
Download PDF Download RIS Download Bibtex

Abstract

In this study, Ni20Cr coatings were obtained by cold spraying on an aluminum alloy 7075 substrate. The obtained coatings were characterized by a uniform microstructure and low porosity. The sprayed coating has the same phase composition as the powder used. Next, the cold sprayed coatings were heat treated using a TRUMPF TLF 6000 TURBO (4 kW) CO2 laser. The laser surface melting of the coatings resulted in the formation of a columnar structure and an improvement in their mechanical properties. The Ni20Cr cold sprayed coatings after additional laser melting showed lower porosity and an increase in microhardness and Young`s modulus.
Go to article

Bibliography

[1] L. Pawlowski, The science and engineering of thermal spray coatings, J. Willey & Sons Ltd, Chichester, II ed. (2008).
[2] D. Tejero-Martin, M. Rezvani Rad, A. McDonald, T. Hussain, J. Therm. Spray Technol. 28 (4), 598-644 (2019).
[3] G. Di Girolamo, E. Serra, Thermally Sprayed Nanostructured Coatings for Anti-wear and TBC Applications: State-of-the-art and Future Perspectives, Anti-Abrasive Nanocoatings, Ed., Woodhead Publishing Limited, 513-541 (2015). DOI: https://doi.org/10.1016/B978-0-85709-211-3.00020-0
[4] A . Góral, L. Lityńska-Dobrzyńska, W. Żórawski, K. Berent, J. Wojewoda-Budka, Arch. Metall. Mater. 58 (2), 335-339 (2013).
[5] C.M. Kay, J. Karthikeyan, High Pressure Cold Spray, ASM International 2016.
[6] H. Assadi, H. Kreye, F. Gartner, T. Klassen, Acta Materialia 116, 382-407 (2016).
[7] M.R. Rokni, S.R. Nutt, C.A. Widener, G.A. Crawford, V.K. Champagne, Springer. 5, 143-192 (2018).
[8] A . Góral, W. Żórawski, P. Czaja, L. Lityńska-Dobrzyńska, M. Makrenek, S. Kowalski, J. Mater. Res. 110, 49-59 (2019), DOI: 10.3139/146.111698
[9] Q. Wang, N. Birbilis, X. Zahang, Metall. Mater. Trans. A Phys. Metall. Mater. Sci. 43, 1395-1399 (2012),
[10] C.W. Ziemian, M.M. Sharma, B.D. Bouffard, T. Nissly, T. Eden, Mater. Des. 54, 212-221(2014)
[11] L. Ajdelsztajn, B. Jodoin, J.M. Schoenung, Surf. Coat. Tech. 201, 1166-1172 (2006).
[12] M. Scendo, W. Żórawski, A. Góral, Metals 9, 890-910 (2019). DOI: 103390/met9080890
[13] E. Qin, B. Wang, W. Li, Ma, H. Lu, S. Wu, J. Therm. Spray Technol. 28, 1072-1080 (2019).
[14] D. Kong, B. Zhao, J. Alloys Compd. 705, 700-707 (2017).
[15] T . Otmianowski, B. Antoszewski, W. Żórawski, Proceesing of 15th International Thermal Spray Conference, 25-29 May, Nice, France, 1333-1336 (1998).
[16] B . Antoszewski, P. Sęk, Proc. SPIE 8703, 8703-8743 (2012). DOI: https://doi.org/10.1117/12.2015240
[17] P. Sęk, Open Eng. 10, 454-461 (2020).
[18] M. Tlotleng, M. Shukla, E. Akinlabi, S. Pityana, Surface Engineering Techniques and Application: Research Advancements 177- 221 (2014). DOI: https://doi.org/10.4018/978-1-4666-5141-8.ch006
[19] D.K. Christoulis, M. Jeandin, E. Irissou, J.G. Legoux, W. Knapp, Laser-Assisted Cold Spray (LACS) InTech. 59-96 (2012). DOI: https://doi.org/10.5772/36104
[20] S.B. Mishra, K. Chandra, S. Prakash, J. Tribol. 128, 469-475 (2006) DOI: 10.1115/1.2197843
[21] A. Mangla, V. Chawla, G. Singh, Int. J. Eng. Sci. Res. Technol. 6, 674-686 (2017).
[22] N. Abu-Warda, A.J. López, M.D. López, M.V. Utrilla, Surf. Coat. Tech. 381, 125133 (2020).
[23] EN ISO 6507-1: 2018.
[24] https://www.scribd.com/document/423195204/DSMTS-0109-2- Ni20Cr-Powders
Go to article

Authors and Affiliations

D. Soboń
1
ORCID: ORCID

  1. Kielce University of Technology, 7 Tysiąclecia Państwa Polskiego Av., 25-314 Kielce, Poland
Download PDF Download RIS Download Bibtex

Abstract

This paper presents the results of diagnostic examinations conducted on the coils of super-heaters made of 10CrMo9‒10 steel that were operated in industrial conditions at 480°C for 130 thousand hours. The tube was exposed in a coal-fired boiler. The chemical and phase composition of the oxide/deposit layers formed on both sides of the tube walls (outside – flue-gas side and inside – steam side) and their sequence was examined using optical microscopy, scanning electron microscopy with electron backscatter diffraction and energy-dispersive X-ray spectroscopy, and X-ray diffraction. The changes in the mechanical properties caused by corrosion and aging processes were concluded from the hardness measurements. In addition, the nature of cracks in the oxide layers caused by pressing a Vickers indenter was determined. The results of these examinations have shown a high degradation of steel on the flue-gas inflow side and identified the main corrosion products and mechanisms.
Go to article

Bibliography

  1.  S. Frangini, A. Masci, and F. Zaza, “Molten salt synthesis of perovskite conversion coatings: A novel approach for corrosion protection of stainless steels in molten carbonate fuel cells,” Corros. Sci. vol. 53, no. 8, pp. 2539–2548, 2011, doi: 10.1016/j.corsci.2011.04.011.
  2.  M. Gwoździk, “Analysis of crystallite size changes in an oxide layer formed on steel used in the power industry”, Acta Phys. Pol. A. vol. 130, no. 4, pp. 935–938, 2016, doi: 10.12693/APhysPolA.130.935.
  3.  M. Gwoździk and Z. Nitkiewicz, “Texturing of magnetite forming during long-term operation of a pipeline of 10CrMo9‒10 steel,” Solid State Phenomena, vol. 203‒204, pp. 121–124, 2013, doi: 10.4028/www.scientific.net/SSP.203-204.121.
  4.  J. Priss, H. Rojacz, I. Klevtsov, A. Dedov, H. Winkelmann, and E. Badisch, “High temperature corrosion of boiler steels in hydrochloric atmosphere under oil shale ashes,” Corros. Sci. vol. 82, pp. 36–44, 2014, doi: 10.1016/j.corsci.2013.12.016.
  5.  J. Lehmusto, P. Yrjas, and L. Hupa, “Pre-oxidation as a means to increase corrosion resistance of commercial superheater steels,” Oxid Met, vol. 91, pp. 311–326, 2019, doi: 10.1007/s11085-019-09898-x.
  6.  X. Montero and M.C. Galetz, “Effect of different vanadate salt composition on oil ash corrosion of boilers,” Oxid Met, vol. 89, pp. 395–414, 2018, doi: 10.1007/s11085-017-9795-4.
  7.  J. Lehmusto, D. Lindberg, P. Yrjas, and L. Hupa, “The effect of temperature on the formation of oxide scales regarding commercial superheater steels. Oxid Met, vol. 89, pp. 251–278, 2018, doi: 10.1007/s11085-017-9785-6.
  8.  M. Gwoździk and Z. Nitkiewicz, “Studies on the adhesion of oxide layer formed on X10CrMoVNb9‒1 steel,” Arch. Civ. Mech. Eng., vol. 14, pp. 335–341, 2014, doi: 10.1016/j.acme.2013.10.005.
  9.  P. Gawron and S. Danisz, “Dostosowanie zakresu badań diagnostycznych wybranych elementów kotłów pracujących w warunkach współspalania biomasy,” Energetyka, vol. 702, pp. 843–853, 2012 [in Polish].
  10.  F. Klepacki and D. Wywrot, “Trwałość wężownicprzegrzewaczy wtórnych w warunkach niskoemisyjnego spalania,” 12th Informative and Training Symposium: Maintenance of Thermo-Mechanical Power Equipment. Upgrading power equipment to extend its operating period beyond 300 000 hours. Wisła, Poland 2010, pp. 29–35 [in Polish].
  11.  J. Cheng, Y.P. Wu, L.Y. Chen, S. Hong, L. Qiao, and Z. Wei, “Hot corrosion behavior and mechanism of highvelocity arc-sprayed Ni-Cr alloy coatings,” J. Therm. Spray Technol., vol. 28, no. 6, pp. 1263–1274, 2019, doi: 10.1007/s11666-019-00890-0.
  12.  A.K. Pramanick, G. Das, and S.K. Das, “Ghosh Failure investigation of super heater tubes of coalfired power plant,” Case Stud. Eng. Fail. Anal., vol. 9, pp. 17–26, 2017, doi: 10.1016/j.csefa.2017.06.001.
  13.  M. Gwoździk, S. Kulesza, M. Bramowicz, “Application of the fractal geometry methods for analysis of oxide layer”. 26th International Conference on Metallurgy and Materials (METAL 2017), Brno, Czech Republic, 2017, pp. 789- 794.
  14.  P. Monivarman, V.A. Nagarajan, and F.M. Raj, “Mechanical and morphological characterization of discarded fishnet/glass fiber reinforced polyester composite,” Bull. Pol. Acad. Sci. Tech. Sci., vol. 68, no. 6, pp. 1385–1391, 2020, doi: 10.24425/bpasts.2020.134646.
  15.  J. Iwaszko, “Laser surface remelting of powder metallurgy high-speed steel,” Bull. Pol. Acad. Sci. Tech. Sci., vol. 68, no. 6, pp. 1425–1432, 2020, doi: 10.24425/bpasts.2020.135385.
  16.  C. Bhargava, J. Aggarwal, and P.K. Sharma, “Residual life estimation of fabricated humidity sensors using different artificial intelligence techniques,” Bull. Pol. Acad. Sci. Tech. Sci., vol. 67, no. 1, pp. 147–154, 2019, doi: 10.24425/bpas.2019.127344.
  17.  M. Gwoździk, M. Motylenko, and D. Rafaja, “Microstructure changes responsible for the degradation of the 10CrMo9‒10 and 13CrMo4‒5 steels during long-term operation,” Mater. Res. Express, vol. 7, no. 1, p. 016515, 2020, doi: 10.1088/2053-1591/ab5fc8.
  18.  C. Hao, F.M. Deng, Z.H. Guo, X. Bo, S. Wang, and X. Zhao, “Fractal dimension of decobalt surface on PDC with different acid corrosion reagents at room temperature,” Diam. Relat. Mat., vol. 105, p. 107699, 2020, doi: 10.1016/j.diamond.2020.107699.
  19.  F.M. Mwema, E.T. Akinlabi, and O.P. Oladijo, “Effect of substrate type on the fractal characteristics of AFM images of sputtered aluminium thin films,” Mater. Sci.-Medzg., vol. 26, pp. 49–57, 2020, doi: 10.5755/j01.ms.26.1.22769.
  20.  H. Aminirastabi, H. Xue, V.V. Miti´c, G. Lazovi´c, G. Ji, and D. Peng, “Novel fractal analysis of nanograin growth in BaTiO3 thin film,” Mater Chem Phys, vol. 239, p. 122261, 2020, doi: 10.1016/j.matchemphys.2019.122261.
  21.  W.P. Dong, P.J. Sullivan, and K.J. Stout, “Comprehensive study of parameters for characterizing 3-dimensional surface-topography. 4. Parameters for characterizing spatial and hybrid properties,” Wear, vol. 178, no. 1–2, pp. 45–60, 1994, doi: 10.1016/0043-1648(94)90128- 7.
  22.  T.R. Thomas, B.-G. Rosén, and N. Amini, “Fractal characterisation of the anisotropy of rough surfaces,” Wear, vol. 232, no. 1, pp. 41–50, 1999, doi: 10.1016/S0043-1648(99)00128-3.
  23.  R.X. Fischer et al., “A new mineral from the Bellerberg, Eifel, Germany, intermediate between mullite and sillimanite,” Am. Miner., vol. 100, pp. 1493–1501, 2015, doi: 10.2138/am-2015-4966.
  24.  Z. Liang, M. Yu, and Q. Zhao, “Investigation of fireside corrosion of austenitic heat-resistant steel 10Cr18Ni9Cu3NbN in ultra-supercritical power plants,” Eng. Fail. Anal., vol. 100, pp. 180–191, 2019, doi: 10.1016/j.engfailanal.2019.02.048.
  25.  M.F. Ashby and D.R.H. Jones, Engineering Materials 1 An Introduction to Properties, Applications and Design, Elsevier, 2012.
  26.  J. Fernández, F. González, C. Pesquera, A. Neves Junior, M Mendes Viana and J. Dweck, “Qualitative and quantitative characterization of a coal power plant waste by TG/DSC/MS, XRF and XRD,” J. Therm. Anal. Calorim., vol. 125, no. 2, pp. 703–710, 2016, doi: 10.1007/ s10973-016-5270-8.
  27.  P. Viklund, A. Hjörnhede, P. Henderson, A. Stålenheim, and R. Pettersson, “Corrosion of superheater materials in a waste-to-energy plant,” Fuel Process. Technol., vol. 105, pp. 106–112, 2013, doi: 10.1016/j.fuproc.2011.06.017.
  28.  Y. Wang, J. Jin, D. Liu, H. Yang, and X. Kou, “Understanding ash deposition for Zhundong coal combustion in 330 MW utility boiler: focusing on surface temperature effects,” Fuel, vol. 216, pp. 697–706, 2018, doi: 10.1016/j.fuel.2017.08.112.
  29.  Y. Xie, W. Xie, W-P. Pan, A. Riga, and K. Anderson, “A study of ash deposits on the heat exchange tubes using SDT/MS and XRD techniques,” Thermochim. Acta, vol. 324, pp. 123–133, 1998, doi: 10.1016/S0040-6031(98)00529-2.
  30.  P.J. Ennis and W.J. Quadakkers, “Mechanisms of steam oxidation in high strength martensitic steels,” Int. J. Pressure Vessels Pip., vol. 84, pp. 75–81, 2007, doi: 10.1016/j.ijpvp.2006.09.007.
  31.  R. Abang, A. Findeisen, and H.J. Krautz, “Corrosion behaviour of selected Power plant materials under oxyfuel combustion conditions,” Górnictwo i Geoinżynieria, vol. 35, no. 3/1, pp. 23–42, 2011.
  32.  T. Aleksandrov Fabijanic’, D. Ćorić, M. Šnajdar Musa, and M. Sakoman, “Vickers Indentation Fracture Toughness of Near-Nano and Nanostructured WC-Co Cemented Carbides,” Metals, vol. 7, 143, 2017, doi: 10.3390/met7040143.
  33.  M. Gwoździk and Z. Nitkiewicz, “Scratch resistance characteristic of oxide layer formed on P91 steel,” Inżynieria Materiałowa, vol. 182, no. 4, pp. 435–438, 2011.
Go to article

Authors and Affiliations

Monika Gwoździk
1
Christiane Ullrich
2
Christian Schimpf
2
David Rafaja
2
Sławomir Kulesza
3
Mirosław Bramowicz
3

  1. Czestochowa University of Technology, ul. Dabrowskiego 69, 42-201 Czestochowa, Poland
  2. TU Bergakademie Freiberg, Akademiestraße 6, 09599 Freiberg, Germany
  3. University of Warmia and Mazury in Olsztyn, ul. Michała Oczapowskiego 2, 10-719 Olsztyn, Poland
Download PDF Download RIS Download Bibtex

Abstract

The methods of severe plastic deformation (SPD) of metals and metal alloys are very attractive due to the possibility of refinement of the grains to nanometric sizes, which facilitates obtaining high mechanical properties. This study investigated the influence of SPD in the process of hydrostatic extrusion (HE) on the anisotropy of the mechanical properties of the CuCrZr copper alloy. The method of HE leads to the formation of a characteristic microstructure in deformed materials, which can determine their potential applications. On the longitudinal sections of the extruded bars, a strong morphological texture is observed, manifested by elongated grains in the direction of extrusion. In the transverse direction, these grains are visible as equiaxed. The anisotropy of properties was mainly determined based on the analysis of the static mini-sample static tensile test and the dynamic impact test. The obtained results were correlated with microstructural observations. In the study, three different degrees of deformation were applied at the level necessary to refine the grain size to the ultrafine-grained level. Regardless of the applied degree of deformation, the effect of the formation of a strong morphological texture was demonstrated, as a result of which there is a clear difference between the mechanical properties depending on the test direction, both by the static and dynamic method. The obtained results allow for the identification of the characteristic structure formed during the HE process and the more effective use of the CuCrZr copper alloy in applications.
Go to article

Authors and Affiliations

Sylwia Przybysz
1
Mariusz Kulczyk
1
ORCID: ORCID
Jacek Skiba
1
Monika Skorupska
1

  1. Institute of High Pressure Physics of the Polish Academy of Sciences, Warszawa, Poland
Download PDF Download RIS Download Bibtex

Abstract

Gaseous nitriding of binary Ni-Cr solid-solution alloys was studied at 1125ºC over the range 1 to 6000 bar of N2-pressure. At the specified temperature the nitriding response of the Ni-Cr alloys depends on the Cr-content in the initial alloy and activity (fugacity) of nitrogen at the gas/metal interface. Transition from cubic δ-CrN to hexagonal β-Cr2N precipitation occurs within the reaction zone after nitrogenization at 1125ºC under nitrogen pressure 100-6000 bar when chromium content in the initial alloy is 28 at. % or higher. It was found that a ternary phase, π (Cr12.8Ni7.2N4.0) is formed inside the Ni32Cr alloy upon cooling in nitrogen after nitriding at 1125ºC and 1 bar of N2. Experimental evidence is presented that π-phase is involved in peritectoid relations with β-Cr2N and γ-(Ni-Cr) solid solution. It was also demonstrated that nitriding behaviour of the Ni-Cr alloy can be rationalized using pertinent phase diagram information, but, in some cases, effect of mechanical stresses induced upon the internal precipitation can vitiate this prediction.
Go to article

Authors and Affiliations

A. Kodentsov
1
ORCID: ORCID
C. Cserháti
2

  1. Mat-Tech BV, Development & Testing, Son, The Netherlands
  2. University of Debrecen Hungary Faculty of Sciences and Technology, Department of Solid State Physics, Hungary
Download PDF Download RIS Download Bibtex

Abstract

Oncological surgery is the primary treatment for gynecological malignancies and is inseparably linked with anesthesia. The modern approach to interdisciplinary and multidisciplinary perioperative care in gynecologic oncological patients improves the outcome. This paper presents a review of perioperative management of patients with gynecologic oncology related to enhanced recovery after surgery and cytor-eductive surgery with hyperthermic intraperitoneal chemotherapy. We performed a literature search on MEDLINE, EMBASE, Google Scholar, the Cochrane Central Register of Controlled Trials, and Clinical Trials. The database search focused on selected topics related to perioperative gynecological oncology care. The authors also contributed through individual, independent literature searches.
Go to article

Authors and Affiliations

Paweł Krawczyk
1
Rafał Baran
2
Dominika Trojnarska
3
Robert Jach
3
Janusz Andres
1

  1. Department of Anesthesiology and Intensive Care Medicine, Jagiellonian University Medical College, Kraków, Poland
  2. Department of Gynecological Endocrinology and Gynecology, University Hospital, Kraków, Poland
  3. Department of Obstetrics and Gynecology, Jagiellonian University Medical College, Kraków, Poland
Download PDF Download RIS Download Bibtex

Abstract

In this study, precisely controlled large scale gas atomization process was applied to produce spherical and uniform shaped high entropy alloy powder. The gas atomization process was carried out to fabricate CoCrFeNiMn alloy, which was studied for high ductility and mechanical properties at low temperatures. It was confirmed that the mass scale, single phase, equiatomic, and high purity spherical high entropy alloy powder was produced by gas atomization process. The powder was sintered by spark plasma sintering process with various sintering conditions, and mechanical properties were characterized. Through this research, we have developed a mass production process of high quality and spherical high entropy alloy powder, and it is expected to expand applications of this high entropy alloy into fields such as powder injection molding and 3D printing for complex shaped components.
Go to article

Authors and Affiliations

Tae Gyu Park
Sang Hyun Lee
Bin Lee
Hye Mi Cho
Won Jung Choi
Bum Sung Kim
Kwang Seon Shin
Taek-Soo Kim
Download PDF Download RIS Download Bibtex

Abstract

Cast stainless steel of the Cr-Ni duplex type is used, among others, for the cast parts of pumps and valves handling various chemically

aggressive media. Therefore, the main problem discussed in this article is the problem of abrasion wear resistance in a mixture of SiC and

water and resistance to electrochemical corrosion in a 3% NaCl- H2O solution of selected cast steel grades, i.e. typical duplex cast steel,

high silicon and manganese duplex cast steel, and Cr-Ni austenitic cast steel (type AISI 316L). The study shows that the best abrasion

wear resistance comparable to Ni-Hart cast iron was obtained in the cast duplex steel, where Ni was partially replaced with Mn and N.

This cast steel was also characterized by the highest hardness and matrix microhardness among all the tested cast steel grades. The best

resistance to electrochemical corrosion in 3% NaCl- H2O solution showed the cast duplex steel with high content of Cr, Mo and N. The

addition of Ni plays rather insignificant role in the improvement of corrosion resistance of the materials tested.

Go to article

Authors and Affiliations

B. Kalandyk
R. Zapała
M. Starowicz
Download PDF Download RIS Download Bibtex

Abstract

The results of research on stereological parameters of carbides in modified hypoeutectic chromium cast iron were shown in the paper. The

effect of distance the casting heat centre of casting to the carbide phase morphology was examined. The samples for metallographic

examination were taken from various locations of the model casting prepared in a special tester. This model casting was designed to

simulate the solidification of heavy castings. Using the proposed methodology the relation of the distance from the model mould and the

size, perimeter, length, width and the shape factor of carbides was examined. During the analysis, the values of stereological parameters of

carbides changed on various sections of the model casting.

Go to article

Authors and Affiliations

M. Gromczyk
A. Studnicki
M. Kondracki
J. Szajnar

This page uses 'cookies'. Learn more