This paper presents the findings of a study of gas emissivity and the volumetric gas flow rate from a patented modified cellulose mix used
in production of disposable sand casting moulds. The modified cellulose mix with such additives as expanded perlite, expanded
vermiculite and microspheres was used as the study material. The results for gas emissivity and the gas flow rate for the modified cellulose
mix were compared with the gas emissivity of the commercial material used in gating systems in disposable sand casting moulds. The
results have shown that the modified cellulose mix is characterized by a lower gas emissivity by as much as 50% and lower gas flow rate
per unit mass during the process of thermal degradation at the temperature of 900°C, compared to the commercial mix. It was also noted
that the amount of microspheres considerably affected the amount of gas produced.
Outdoor remote temperature measurements in the infrared range can be very inaccurate because of the influence of solar radiation reflected from a measured object. In case of strong directional reflection towards a measuring device, the error rate can easily reach hundreds per cent as the reflected signal adds to the thermal emission of an object. As a result, the measured temperature is much higher than the real one. Error rate depends mainly on the emissivity of an object and intensity of solar radiation. The position of the measuring device with reference to an object and the Sun is also important. The method of compensation of such undesirable influence of solar radiation will be presented. It is based on simultaneous measurements in two different spectral bands, shor-twavelength and long-wavelength ones. The temperature of an object is derived from long-wavelength data only, whereas the short-wavelength band, the corrective one, is used to estimate the solar radiation level. Both bands were selected to achieve proportional changes of the output signal due to solar radiation. Knowing the relation between emissivity and solar radiation levels in both spectral bands, it is possible to reduce the measurement error several times.
The difficulties of access and detailed measurements of land surface temperature (LST) and water surface temperature (WST) especially in wetlands made the use of remote sensing data as one of the sources and techniques to estimate many climate elements including surface temperature and surface emissivity (ɛ). This study aims to estimate the surface tempera-ture of the wetland of Lake Oubeira located in northeastern Algeria and their spatiotemporal evolution in both land and wa-ter. Landsat OLI-TIRS images in two dates (April and September 2016) obtained from the USGS have been used in this work, and forms the basis of a series of operations to obtain the final LST: development of the normalized difference vegeta-tion index (NDVI), conversion of the digital number (DN) of the thermal infrared band (TIR) into spectral radiance as well as the calculation of the effective luminosity temperature of the sensor from the spectral radiation and surface emissivity (ɛ). The results show that the LST varies in space and time (from 16 to 31°C in April and from 24 to 41°C in September). This implies that the absorption of the equilibrium temperature at land cover depends on the optical properties of the sur-face, which are essentially determined by its water content, colour and morphology. At the same time, the water surface is the lowest land cover temperature, which also has a spatial variation (from 19 to 25°C in April and from 26 to 34.5°C in September) induced by atmospheric temperature, wind direction and speed and the depth of the lake.
The article has presented the assumptions underlying the organization of emissions trading of greenhouse gases with a particular emphasis on CO2 emission allowances. Through the analysis of the literature, international activities were undertaken aimed at reducing greenhouse gas emissions into the atmosphere, starting from the First World Climate Conference organized in 1979. The origins and guidelines of the Kyoto Protocol were also given considerable attention. In addition to the description of the key assumptions of the Protocol and its main components, the characteristics of international trade in Kyoto units were also included. The mechanisms involved in international trade and the types of units traded in a detailed manner are described. In the next part of the article, emission trading systems operating in the world are characterized. In the second part of the paper special attention was paid to the conditionings of the European market, i.e. European Emissions Trading System – EU ETS. Historical events were presented that gave rise to the creation of the EU ETS. In the next steps, the types of units that are tradable were described. Furthermore, the trade commodity exchanges on which trade is conducted, the key factors determining the price of individual allowances are also indicated. In the last part of the article, relatively recent issues – the IED Directive and the BAT conclusions have been pointed out. Referring to the applicable regulations, the impact of their implementation on the situation of entities obliged to limit greenhouse gas emissions was analyzed. In the final phase, an attempt was made to assess the impact of IED and BAT to electricity prices.
Photofield emission from SiGe nanoislands formed by molecular beam epitaxy (MBE) have been investigated. Two types of nanoislands, namely the domes and pyramids with different heights, have been addressed. It was found that the arrays of SiGe nanoislands exhibited a low onset voltage for field emission. The increase of emission current and the decrease of the curve slope in Fowler-Nordheim coordinates under green light illumination have been revealed. Electron field emission and photoemission from SiGe nanoislands have been explained based on the energy band diagram of Si-Ge heterostructure and some energy barriers have been determined.
The expected demand for hard coal intended for the households will progressively be decreasing. This is directly related to the introduced anti-smog resolutions, as well as the growing level of environmental awareness. However, it should be noted, that the use of the modern home heating boilers will result in an increase in the demand for medium coal sizes. The shortfall of this type of coal is already observed on the market. Therefore, its import is necessary. One of the solutions to increase the supply of the medium coal sizes is the production of coal briquettes. Moreover, their use will consequently lead to reduced emissions.
The paper presents a comparison of emissions from the combustion of coal briquettes and hard coal in home heating boilers. The briquettes were characterized by significantly lower emissions than hard coal (by 52% on average). The particulate matter emissions were lower by 70%. This may significantly contribute to improving air quality in Poland and in addition, limit the occurrence of smog. The possibility of further emission reduction by using low-emission fuels as briquette components was presented. The average relative emission reduction compared to hard coal for the analyzed fuels was estimated as follows: 62% for coal char, 57% for coke, 51% for charcoal/biocarbon, 49% for anthracite, 45% for torrefied biomass, and 33% for peat.
Furthermore, the issue of the mercury content in the analyzed fuels was discussed. The lowest mercury content was found in biomass fuels, in particular biomass after thermal treatment (torrefied biomass, biocarbon, and charcoal). Fuels produced from hard coal in the pyrolysis process (coal char and coke) were characterized by very low mercury content as well.
Coal combustion processes are the main source of mercury emission to the environment in Poland. Mercury is emitted by both power and heating plants using hard and brown coals as well as in households. With an annual mercury emission in Poland at the level of 10 Mg, the households emit 0.6 Mg. In the paper, studies on the mercury release in the coal and biomass combustion process in household boilers were conducted. The mercury release factors were determined for that purpose. For the analyzed samples the mercury release factors ranged from 98.3 to 99.1% for hard coal and from 99.5% to 99.9% for biomass, respectively. Due to the high values of the determined factors, the amount of mercury released into the environment mainly depends on the mercury content in the combusted fuel. In light of the obtained results, the mercury content in the examined hard coals was 6 times higher than in the biomass (dry basis). Taking the calorific value of fuels into account, the difference in mercury content between coal and biomass decreased, but its content in coal was still 4 times higher. The mercury content determined in that way ranged from 0.7 to 1.7 μg/MJ for hard coal and from 0.1 to 0.5 μg/MJ for biomass, respectively. The main opportunity to decrease the mercury emissions from households is offered by the use of fuels with a mercury content that is as low as possible, as well as by a reduction of fuel consumption. The latter could be obtained by the use of modern boilers as well as by the thermo-modernization of buildings. It is also possible to partially reduce mercury emissions by using dust removal devices.