Introduction of polymers into the cement composites improves same of the properties of concretes and mortars. Therefore, the polymer-cement composites are successfully used in construction. The model of microstructure formation in cement composites modified with thermoplastic polymer (pre-mix modifiers) has already been developed and successfully implemented. However, the formation of microstructure in the case of epoxy-cement composites (containing post-mix modifier) demonstrates same peculiarities which should be taken into account when modelling the process. The microstructure of epoxy-cement composites and its formation is discussed in the paper. The model is offered, formulated on the basis of the microscopic observations and results of testing.
The preliminary stage of asphalt mixture production involves the drying and dedusting of coarse aggregates. The most common types of coarse aggregates used are limestone and basalt. In the process of drying and dedusting the dryer filter accumulates large quantities of waste in the form of mineral powder.
This paper introduces an investigation into limestone powder waste as a potential microfiller of polymer composites. Physical characteristics such as the granulation the of powder collected from the filter - in terms of the season of its collection and the type of input materials used - were analysed. A scanning electron microscope (SEM) was used for the investigation described within this paper. The obtained results were compared against those of other materials which can be used as polymer composites microfillers.
The influence of ion implantation on the structure and properties of polymers is a very complex issue. Many physical and chemical processes taking place during ion bombardment must be taken into consideration. The complexity of the process may exert both positive and negative influence on the structure of the material. The goal of this paper is to investigate the influence of H+, He+ and Ar+ ion implantation on the properties of polypropylene membranes used in filtration processes and in consequence on fouling phenomena. It has appeared that the ion bombardment caused the chemical modification of membranes which has led to decrease of hydrophobicity. The increase of protein adsorption on membrane surface has also been observed.
The general standards and guidelines recommendations for PCC suggest alternating conditions of curing: starting with wet conditions for effective hydration of Portland cement followed by air-dry conditions for polymer hardening. The often accepted curing regime of PCC covers 5 days of wet curing and then the air-dry curing but it is not the optimum one. The aim of the investigation was to find the best scenario for PCC with two types of polymer modifiers: two-component epoxy resin and water dispersion of polyacrylates. The following exploitation properties were accepted as the criteria of evaluation of PCC curing effectiveness: compressive strength, tensile splitting strength, surface tensile strength (by pull-off method), wear resistance, water penetration under pressure and resistance to carbonation. The optimum time of PCC wet curing is possibly between 7 and 14 days, however, it have to be verified experimentally for specific PCC composition.
It was found that the addition of carbon fibers (CFs) does not affect the crosslinking process in the microwave radiation (800 W, 2.45
GHz) of the BioCo2 binder, which is a water solution of poly(acrylic acid) and dextrin (PAA/D). It has influence on BioCo2 thermal
properties. The CFs addition improves the thermostability of a binder and leads to the reduction of gas products quantity generated in the
temperature range of 300-1100°C (TG-DTG, Py-GC/MS). Moreover, it causes the emission of harmful decomposition products such as
benzene, toluene, xylene and styrene to be registered in a higher temperatures (above 700°C). BioCo2 binder without CFs addition is
characterized by the emission of these substances in the lower temperature range. This indicates the positive effect of carbon fibers
presence on the amount of released harmful products.
The selected technological tests (permeability, friability, bending strength, tensile strength) have shown that the moulding sand with the
0.3 parts by weight carbon fibers addition displays the worst properties. The addition of 0.1 parts by weight of CFs is sufficient to obtain a
beneficial effect on the analyzed moulding sands properties. The reduction of harmful substances at the higher temperatures can also be
observed.
The paper deals with the preparation and measurement of an experimental polymer graphite cathode that
seems to be a promising and cheap source of electrons utilizing cold field-emission in high- and ultra-high
vacuum. Polymer graphite seems to be a proper material as it contains a large amount of hybridized carbon
with a low degree of surface oxidation and silicon monoxide (SiO). Within the frame of this work, a special
experimental method of tip preparation has been designed and tuned. This method is based on ion milling
inside a dual-beam electron microscope enabling to obtain ultra-sharp tips of a diameter smaller than 100 nm
with a predefined opening angle. The charge transport within experimental samples is evaluated based on
results provided by the noise spectroscopy of the total emission current in the time and frequency domains.
Very thin liquid jets can be obtained using electric field, whereas an electrically-driven bending instability occurs that enormously increases the jet path and effectively leads to its thinning by very large ratios, enabling the production of nanometre size fibres. This mechanism, although it was discovered almost one century ago, is not yet fully understood. In the following study, experimental data are collected, with the dual goal of characterizing the electro-spinning of different liquids and evaluating the pertinence of a theoretical model.
Two constructions of microfluidic structures are described in this paper. A fibre optic microcell for spectrophometric measurements and a microcell for fluorescence experiments were designed and tested. The structures were made of polymer optical fibres which were incorporated into polymeric material i.e. poly(dimethylsiloxane). The structures were tested as detectors in absorbance measurement (solutions of bromothymol blue with diffierent pH were used) and in fluorescence tests (solution of fluoresceine was used).
The sound absorption property of polyurethane (PU) foams loaded with natural tea-leaf fibers and luffa cylindrica (LC) has been studied. The results show a significant improvement in the sound absorption property parallel to an increase in the amount of tea-leaf fibers (TLF). Using luffa-cylindrica as a filler material improves sound absorption properties of soft foam at all frequency ranges. Moreover, an increase in the thickness of the sample resulted in an improvement of the sound absorption property. It is pleasing to see that adding tea-leaf fibers and luffa-cylindrica to the polyurethane foam demonstrate a significant contribution to sound absorption properties of the material and it encourages using environmental friendly products as sound absorption material in further studies.
The effects of silica additive (Poraver) on selected properties of BioCo3 binder in form of an aqueous poly(sodium acrylate) and dextrin (PAANa/D) binder were determined. Based on the results of the thermoanalytical studies (TG-DTG, FTIR, Py-GC/MS), it was found that the silica additive results in the increase of the thermostability of the BioCo3 binder and its contribution does not affect the increase in the level of emissions of organic destruction products. Compounds from group of aromatic hydrocarbons are only generated in the third set temperature range (420-838°C). The addition of silicate into the moulding sand with BioCo3 causes also the formation of a hydrogen bonds network with its share in the microwave radiation field and they are mainly responsible for maintaining the cross-linked structures in the mineral matrix system. As a consequence, the microwave curing process in the presence of Poraver leads to improved strength properties of the moulding sand (���� �� ). The addition of Poraver's silica to moulding sand did not alter the permeability of the moulding sand samples, and consequently reduced their friability. Microstructure investigations (SEM) of microwave-cured samples have confirmed that heterogeneous sand grains are bonded to one another through a binder film (bridges).
Electrochemical amperometric gas sensors represent a well-established and versatile type of devices with unique features: good sensitivity and stability, short response/recovery times, and low power consumption. These sensors operate at room temperature, and therefore have been applied in monitoring air pollutants and detection of toxic and hazardous gases in a number of areas. Some drawbacks of classical electrochemical sensors are overcome by the solid polymer electrolyte (SPE) based on ionic liquids. This work presents evaluation of an SPE-based amperometric sensor from the point of view of current fluctuations. The sensor is based on a novel three-electrode sensor platform with solid polymer electrolytes containing ionic liquid for detection of nitrogen dioxide − a highly toxic gas that is harmful to the environment and presenting a possible threat to human health even at low concentrations. The paper focuses on using noise measurement (electric current fluctuation measurement) for evaluation of electrochemical sensors which were constructed by different fabrication processes: (i) lift-off and drop-casting technology, (ii) screen printing technology on a ceramic substrate and (iii) screen printing on a flexible substrate.
Graphene is a very promising material for potential applications in many fields. Since manufacturing technologies of graphene are still at the developing stage, low-frequency noise measurements as a tool for evaluating their quality is proposed. In this work, noise properties of polymer thick-film resistors with graphene nano-platelets as a functional phase are reported. The measurements were carried out in room temperature. 1/f noise caused by resistance fluctuations has been found to be the main component in the specimens. The parameter values describing noise intensity of the polymer thick-film specimens have been calculated and compared with the values obtained for other thick-film resistors and layers used in microelectronics. The studied polymer thick-film specimens exhibit rather poor noise properties, especially for the layers with a low content of the functional phase.
The paper presents a dynamic analysis of the damaged masonry building repaired with the Flexible Joint Method. Numerical analysis helped to determine the effect of the applied repairing method on natural frequencies as well as values of stresses and accelerations in the analyzed variants of numerical model. They confirmed efficiency of the proposed repair method.
The paper describes an experimental behaviour of the basalt fibre reinforced polymer composite by external strengthening to the concrete beams. The BFRP composite is wrapped at the bottom face of R.C beam as one layer, two layers, three layers and four layers. The different characteristics – are studied in – first crack load, ultimate load, tensile and compressive strain, cracks propagation, crack spacing and number of cracks etc. To – investigate, total of five beams size 100×160×1700 mm were cast. One beam is taken as control and others are strengthened with BFRP composite with layers. From this investigation, the first crack load is increased depending on the increment in layers from 6.79% to 47.98%. Similarly, the ultimate load carrying – capacity is increased from 5.66% to 20%. The crack’s spacing is also reduced with an increase in the number of layers.
We experimentally studied three different D-shape polymer optical fibres with an exposed core for their applications as surface plasmon resonance sensors. The first one was a conventional D-shape fibre with no microstructure while in two others the fibre core was surrounded by two rings of air holes. In one of the microstructured fibres we introduced special absorbing inclusions placed outside the microstructure to attenuate leaky modes. We compared the performance of the surface plasmon resonance sensors based on the three fibres. We showed that the fibre bending enhances the resonance in all investigated fibres. The measured sensitivity of about 610 nm/RIU for the refractive index of glycerol solution around 1.350 is similar in all fabricated sensors. However, the spectral width of the resonance curve is significantly lower for the fibre with inclusions suppressing the leaky modes.
We experimentally studied three different D-shape polymer optical fibres with an exposed core for their applications as surface plasmon resonance sensors. The first one was a conventional D-shape fibre with no microstructure while in two others the fibre core was surrounded by two rings of air holes. In one of the microstructured fibres we introduced special absorbing inclusions placed outside the microstructure to attenuate leaky modes. We compared the performance of the surface plasmon resonance sensors based on the three fibres. We showed that the fibre bending enhances the resonance in all investigated fibres. The measured sensitivity of about 610 nm/RIUfor the refractive index of glycerol solution around 1.350 is similar in all fabricated sensors. However, the spectral width of the resonance curve is significantly lower for the fibre with inclusions suppressing the leaky modes.
Polymer-based capacitive humidity sensors emerged around 40 years ago; nevertheless, they currently constitute large part of sensors’ market within a range of medium (climatic and industrial) humidity 20−80%RH due to their linearity, stability and cost-effectiveness. However, for low humidity values (0−20%RH) that type of sensor exhibits increasingly nonlinear characteristics with decreasing of humidity values. This paper presents the results of some experimental trials of CMOS polymer-based capacitive humidity sensors, as well as of modelling the behaviour of that type of sensor. A logarithmic functional relationship between the relative humidity and the change of sensor output value at low humidity is suggested.
A review is given on a number of colloidal phenomena with special reference to their applicability to nanoparticles. Phenomena addressed include preparation, electric double layers and their characterization, electrokinetics, van der Waals and Lifshits forces, electric and steric particle interaction.