Nauki Techniczne

Archives of Foundry Engineering

Zawartość

Archives of Foundry Engineering | 2012 | No 3 |

Abstrakt

This article investigates possible use of waste gypsum (synthetic), recovered via flue-gas desulfurization from coal-fired electric power plants, in foundries. Energy sector, which in Eastern Europe is mostly composed from coal-fired electric power plants, is one of the largest producers of sulfur dioxide (SO2). In order to protect the environment and reduce the amount of pollution flue-gas desulfurization (FGD) is used to remove SO2 from exhaust flue gases of fossil-fuel power plants. As a result of this process gypsum waste is produced that can be used in practical applications. Strength and permeability tests have been made and also in-depth analysis of energy consumption of production process to investigate ways of preparing the synthetic gypsum for casting moulds application. This paper also assesses the chemical composition, strength and permeability of moulds made with synthetic gypsum, in comparison with moulds made with traditional GoldStar XL gypsum and with ceramic molds. Moreover examination of structure of synthetic gypsum, the investigations on derivatograph and calculations of energy consumption during production process of synthetic gypsum in wet flue-gas desulfurization were made. After analysis of gathered data it’s possible to conclude that synthetic gypsum can be used as a material for casting mould. There is no significant decrease in key properties, and on the other hand there is many additional benefits including low energy consumption, decreased cost, and decreased environmental impact.

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Abstract An attempt has been made to determine the effect of an addition of colloidal suspensions of the nanoparticles of magnesium oxide on the structure of water glass, which is a binder for moulding and core sands. Nanoparticles of magnesium oxide MgO in propanol and ethanol were introduced in the same mass content (5wt.%) and structural changes were determined by measurement of the FT-IR absorption spectra.
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Modern investigation methods and equipment for the quality estimation of the moulding sands matrices with organic binders, in their circulation process, are presented in the paper. These methods, utilising the special equipment combined with the authors investigation methods developed in the Faculty of Foundry Engineering, AGH the University of Science and Technology, allow for the better estimation of the matrix quality. Moulding sands systems with organic binders require an in-depth approach to factors deciding on the matrix technological suitability as well as on their environmental impact. Into modern methods allowing for the better assessment of the matrix quality belongs the grain size analysis of the reclaimed material performed by means of the laser diffraction and also the estimation of the moulding sand gas evolution rate and identification of the emitted gases and their BTEX group gases content, since they are specially hazardous from the point of view of the Occupational Safety and Health.

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This paper presents a new perspective on the issue of reclamation of moulding and core sands. Taking as a premise that the reclamation process must remain on the surface of grains some not separated binding materials rests, it should be chosen the proper moulding sand’s composition that will be least harmful for the reclaim quality. There are two different moulding and core sands taken into examinations. The researches prove that a small correction of their compositions (hardener type) improves the quality of the received reclaims. Carried out in this article studies have shown that such an approach to the problem of reclamation of the moulding and core sands is needed and reasonable.

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The demand for castings of high quality and sound work is nowadays very high. The production of sound castings without foundry errors is the big issue in modern foundries. Foundry simulation software can do a lot to help improve the disposition of castings, gating system and feeder system, and assure good filling and solidification conditions, and also produce sound casting without the need of the old method of "try and error". One can easily change a lot of parameters for filling and solidification, and create the best proposal for production. Connor inlets have two functions. One is that it serves as an ingate, through which molten metal passes and comes into the mould cavity. The second function is that it serves as a feeder and substitutes the metal contracted during solidification and cooling of the castings. It can also save quite a lot of metal in comparison to classic feeders.

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Definition of a composite [1] describes an ideal composite material with perfect structure. In real composite materials, structure is usually imperfect – composites contain various types of defects [2, 3–5], especially as the casted composites are of concern. The reason for this is a specific structure of castings, related to course of the manufacturing process. In case of metal matrix composite castings, especially regarding these manufactured by saturation, there is no classification of these defects [2, 4]. Classification of defects in castings of classic materials (cast iron, cast steel, non-ferrous alloys) is insufficient and requires completion of specific defects of mentioned materials. This problem (noted during manufacturing metal matrix composite castings with saturated reinforcement in Institute of Basic Technical Sciences of Maritime University Szczecin) has become a reason of starting work aimed at creating such classification. As a result, this paper was prepared. It can contribute to improvement of quality of studied materials and, as a consequence, improve the environment protection level.

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In this paper the results of studies of polymeric binders on the example of the new BioCo2 binder, including the problem of its renewability, are presented. The results of structural studies (FT-IR) for the BioCo2 binder before and after crosslinking, and bending strength tests Rg u fresh and renewed cured molding sands with BioCo2 binder are discussed. The cross-linking binder and curring of moulding sand was carried out by physical agents (microwave radiation, temperature). On the basis of obtained results was shown that it is possible to restore the initial properties of the adhesive of BioCo2 binder. The initial properties of moulding sand can be achieved, after the cross-linking binders and after curing in the moulding sands with bioCo2 binder , by supplementing the moulding sand composition by the appropriate amount of water.

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Increasing demands on the utility properties of materials used for castings have led to the production of cast iron with a modified shape of graphite, where the required properties are achieved by a change in graphite shape, its size and layout, and a change in the basic structure of the metal. This paper is focused on the continuous method of producing spheroidal graphite FLOTRET. In the introductory section is summarized the theoretical foundations of the secondary treatment of cast irons, especially the FLOTRET flow method, describes the advantages and disadvantages of the method. The practical part is divided into laboratory and operational tests. Laboratory experiments were conducted on a laboratory-type modifier FLOTRET chamber, which was designed and hydraulically optimized. Experiments were focused on the effects of pressure altitude and amount of modifier on the residual values of magnesium, as conditions for a successful modification. The method was tested in two foundries under operating conditions and in one of them was observed a long-term modification process.

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In earlier works were described trends in the production of tools for die casting (hot work). Almost the entire set of issues dealt with may seem insignificant when incompletely assembled acceptance of the material and the associated risks of processing a material with an inappropriate structure, leading to a very early defect of the die. Therefore, further work will focus particularly on identifying the causes of thermal cracks and preventing a suitable choice of acceptance criteria conditions and heat treatment.

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The results of investigations of the granulation process of foundry dusts generated in the dry mechanical reclamation process of used sands, where furan resins were binders are presented in the paper. Investigations concerned producing of granules of the determined dimensions and strength parameters. Granules were formed from the dusts mixture consisting in 50 mass% of dusts obtained after the reclamation of the furane sands and in 50 mass % of dusts from sands with bentonite. Dusts from the bentonite sands with water were used as a binder allowing the granulation of after reclamation dusts from the furane sands. The following parameters of the ready final product were determined: moisture content (W), shatter test of granules (Wz) performed directly after the granulation process and after 1, 3, 5, 10 days and nights of seasoning, water-resistance of granules after 24 hours of being immersed in water, surface porosity ep and volumetric porosity ev. In addition the shatter test and water-resistance of granulate dried at a temperature of 105oC were determined. Investigations were performed at the bowl angle of inclination 45o, for three rotational speeds of the bowl being: 10, 15, 20 rpm. For the speed of 10 rpm the granulation tests of dusts mixture after the preliminary mixing in the roller mixer and with the addition of water-glass in the amount of 2% in relation to the amount of dust were carried out. The obtained results indicate that the granulator allows to obtain granules from dusts originated from the reclamations of moulding sands with the furane resin with an addition of dusts from the bentonite sands processing plants.

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The aim of the present study was to develop a modifier for water glass. The method of thermal generation of metal oxide nanoparticles was adapted and used in the research. Nanoparticles of ZnO from the thermal decomposition of basic zinc carbonate were used. A method for the modifier introduction was developed, and the effect of modifier content and organic solvent type on the physico-chemical properties of binder (viscosity) and quartz wettability was determined. Binder viscosity was examined from the flow curves plotted with the help of a RHEOTEST 2 rotational rheometer equipped with proper software. Quartz wettability was determined examining timerelated changes in the value of the contact angle in a quartz-binder system, until full stabilisation of the angle value has been achieved. Binder modification was carried out on sodium water glass designated as R"145". The water glass modifiers were suspensions of ZnO nanoparticles in propanol and methanol at a fixed concentration of c = 0.3 M and with the size of nanoparticles comprised in a range of <61 - 981 nm>. Water glass modification with the suspensions of ZnO nanoparticles in methanol and propanol showed the effect of modifier on the water glass viscosity and quartz wettability. This effect depends on the type of alcohol used. The ZnO suspension in propanol (alcohol with a longer hydrocarbon chain) affects more strongly the viscosity of binder and quartz wettability than the methanol suspension.

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The subject of this study is the presentation of relation between the degree of structure fineness and ultrasonic wave damping coefficient for the high-zinc aluminium alloys represented in this study by the sand mould cast alloy Al - 20 wt% Zn (AlZn20). The studied alloy was refined with a modifying (Al,Zn)-Ti3 ternary master alloy, introducing Ti in the amount of 400 pm into metal. Based on the analysis of the initial and modified alloy macrostructure images and ultrasonic testing, it was found that the addition of (Al,Zn)-Ti3 master alloy, alongside a significant fragmentation of grains, does not reduce the coefficient of ultrasonic waves with a frequency of 1 MHz.
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Suitability of the given binding agent for the moulding sands preparation depends on the one hand on the estimation of technological properties of the sand and the mould made of it and the obtained casting quality and on the other hand on the assessment of this sand influence on the natural and working environment. Out of moulding sands used in the foundry industry, sands with organic binders deserve a special attention. These binders are based on synthetic resins, which ensure obtaining the proper technological properties and sound castings, however, they negatively influence the environment. If in the initial state these resins are not very dangerous for people and for the environment, thus under an influence of high temperatures they generate very harmful products, being the result of their thermal decomposition. Depending on the kind of the applied resin (phenol-formaldehyde, urea, furfuryl, urea–furfuryl, alkyd) under an influence of a temperature such compounds as: furfuryl alcohol, formaldehyde, phenol, BTEX group (benzene, toluene, ethylbenzene, xylene), and also polycyclic aromatic hydrocarbons (PAH) can be formed and released. The aim of the study was the development of the method, selection of analytical methods and the determination of optimal conditions of formation compounds from the BTEX group. An emission of these components constitutes one of the basic criteria of the harmfulness assessment of binders applied for moulding and core sands. Investigations were carried out in the specially designed set up for the thermal decomposition of organic substances in a temperature range: 5000 C – 13000 C at the laboratory scale. The object for testing was alkyd resin applied as a binding material for moulding sands. Within investigations the minimal amount of adsorbent necessary for the adsorption of compounds released during the decomposition of the resin sample of a mass app. 15 mg was selected. Also the minimal amount of solvent needed for the desorption of compounds adsorbed in the column with adsorbent was found. The temperature range, in which the maximal amounts of benzene, toluene, ethylobenzene and xylenes are released from the resin, was defined. The qualitative and quantitative analyses of compounds from the BTEX group were performed by means of the gas chromatography combined with the mass spectrometry (GC/MS).

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The research focused on the production of prototype castings, which is mapped out starting from the drawing documentation up to theproduction of the casting itself. The FDM method was applied for the production of the 3D pattern. Its main objective was to find out whatdimensional changes happened during individual production stages, starting from the 3D pattern printing through a silicon mouldproduction, wax patterns casting, making shells, melting out wax from shells and drying, up to the production of the final casting itself. Five measurements of determined dimensions were made during the production, which were processed and evaluated mathematically. A determination of shrinkage and a proposal of measures to maintain the dimensional stability of the final casting so as to meet requirements specified by a customer were the results.
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The paper presents results of preliminary examinations on possibility of determining binder content in traditional moulding sands with the microwave method. The presented measurements were carried-out using a special stand, the so-called slot line. Binder content in thesandmix was determined by measurements of absorption damping Ad and insertion losses IL of electromagnetic wave. One of main advantages of the suggested new method of binder content measurement is short measuring time.
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The paper presents measurement results of standing wave ratio to be used as an efficiency indicator of microwave absorption by used moulding and core sands chosen for the microwave utilization process. The absorption measurements were made using a prototype stand of microwave slot line. Examined were five used moulding and core sands. It was demonstrated that the microwave absorption measurements can make grounds for actual microwave utilization of moulding and core sands.
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The mechanical properties of steel components are controlled by the chemical composition and mechanical treatment to which the steel is submitted. Non-metallic inclusions have a very high influence on the steel quality but secondary metallurgy enables to reduce their content in the steel. Possibilities of secondary metallurgy are relatively extensive but financial situation in Slovak foundries does not enable to make investments in secondary metallurgy in the near future. Accessible means for influencing of steel quality is injection of aninert gas. Main goal of experiments described in the article was verify the influence of blowing of argon into the steel in an electric induction furnace on its cleanness. Duration and flow-rate of argon blowing have a very clearly influence on the final content of non-metallic inclusions. Minimum time of argon blowing necessary for reducing of content of non-metallic inclusions in one tonne electric induction furnace was more than 6 minutes and recommended argon flow rate was 10 litters per minute.
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Foundry dust from blasting and grinding of castings contain a high amount of iron, ergo it is possible its recycling in foundry process. Dust was compacted by briquetting, two kinds of briquettes were prepared (A contained 95% magnetic part of dust from casting blasting +5% bentonite and B contained 95% mixture of dust from casting grinding and magnetic part of dust from casting blasting + 5% bentonite) and used as a part of charge into the electric induction furnace. It was found that addition of briquettes has had an influence of a chemical composition of cast iron above all on content of sulphur, phosphorus and silicon. It was not reflected in decrease in tensile strength and in microstructure. Yield of metal from briquettes was not lower then 70%.
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The article contains the results of tests performed under the target project in Hardtop Foundry Charsznica. The objective of the tests and studies was to develop a technology of making high-quality ductile iron castings, combined with effective means of environmental protection. The studies presented in this article related to castings weighing from 1 to 300 kg made from ductile iron of grades 400-15 and 500-7, using two-layer moulds, where the facing and core sand was the sand with an alkaline organic binder, while backing sand was the sand with an inorganic geopolymer binder. A simplified method of sand reclamation was applied with possible reuse of the reclaim as an addition to the backing sand. The cast iron spheroidising treatment and inoculation were selected taking into account the specific conditions of Hardtop Foundry. A pilot batch of castings was made, testing the gating and feeding systems and using exothermic sleeves on risers. The study confirmed the validity of the adopted concept of making ductile iron castings in layer moulds, while maintaining the content of sand with an organic binder at a level of maximum 15%.
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Reason for and risks of using of cast iron with vermicular graphite for typical construction parts. Ultrasound checking of graphite shape. Factors influencing plausibility of result. Difference between laboratory and operation application. Roughness, parallelism, stabilityand size dimension of walls. Conditions, proposals for simplification and productivity enhancement of castings checking. Recommendation.
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In this article, an outline of the key questions connected with the essential problems of energy-consumption of air-stream moulding machines has been presented. Research results and calculations of requisite parameters appraisable of energy-consumption of air-stream moulding machines have been supplemented also by the data analysis of offer of the moulding machines manufacturers. The attention on constructional and technological factors which are favourable for the diminution of energy-consuming of the moulding process has been paid.
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The development of economy and industry introducing new technologies and materials often means the increased threat of occurrence of factors harmful to humans and environment. Workers employed in foundries as mould pourers are the group of high professional risk. Foundry moulding sands when poured with liquid metal are a source of the emission of harmful, toxic and carcinogenic (benzene, PAHs) compounds. The paper presents the results of studies on the concentration of chemical compounds emitted in the process of casting aluminium alloy and brass using moulding sands with the new inorganic binders. The specific values of the exposure indices were compared with the limit values. This enabled an assessment of the impact of moulding sands on work environment. The obtained results were compared with the values of contaminants emitted when pouring foundry moulds made from furan sands and bentonite sands with an addition of coal dust. Studies were carried out under the project POIG.01.01.02-00-015/09 "Advanced materials and technologies."
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Casting quality depends on many factors including the quality of the input materials, technology, material securing and last but not least, the mould into which the casting is casted. By pouring into a single-shot mould, based mainly on 1st generation binders, is is a very important factor. Basically, a bentonite mixture represents either a three- or four-component system, but each component of the system is a heterogeneous substance. This heterogeneity punctuates mainly a non-stationary heat field, presented throughout the whole process of the casting production. The most important component is a binder and in the case of first generation binders mostly bentonites are used - clays that contain minimum of 80% of montmorillonite
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Foundry resistance furnaces are thermal devices with a relatively large time delay in their response to a change in power parameters. Commonly used in automation classical PID controllers do not meet the requirements of high-quality control. Developed in recent years, fuzzy control theory is increasingly being used in various branches of economy and industry. Fuzzy controllers allow to introduce new developments in control systems of foundry furnaces as well. Correctly selected fuzzy controller can significantly reduce energy consumption in a controlled thermal process of heating equipment. The article presents a comparison of energy consumption by control system of foundry resistance furnace, equipped with either a PID controller or fuzzy controller optimally chosen.
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The results of testing of the selected group of wax mixtures used in the investment casting technology, are presented in the paper. The measurements of the kinetics of the mixtures shrinkage and changes of viscous-plastic properties as a temperature function were performed. The temperature influence on bending strength of wax mixtures was determined.
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The criteria, with which one should be guided at the assessment of the binding properties of bentonites used for moulding sands, are proposed in the paper. Apart from the standard parameter which is the active bentonite content, the unrestrained growth indicator should be taken into account since it seems to be more adequate in the estimation of the sand compression strength. The investigations performed for three kinds of bentonites, applied in the Polish foundry plants, subjected to a high temperature influences indicate, that the pathway of changes of the unrestrained growth indicator is very similar to the pathway of changes of the sand compression strength. Instead, the character of changes of the montmorillonite content in the sand in dependence of the temperature is quite different. The sand exhibits the significant active bentonite content, and the sand compression strength decreases rapidly. The montmorillonite content in bentonite samples was determined by the modern copper complex method of triethylenetetraamine (Cu(II)-TET). Tests were performed for bentonites and for sands with those bentonites subjected to high temperatures influences in a range: 100-700ºC.
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The solution of applications for air pollution control in foundries for iron and non-ferrous metals may not only be understood as the observance of requested emission limit values at the stack outlet. An effective environmental protection already starts with the greatest possible capture of pollutants at the source with at the same time minimisation of the volume flow necessary for this. Independent of this, the downstream installed filtration system has to realise a degree of separation of definitely above 99%. Furthermore, when selecting the filter construction, attention has to be paid to a high availability. An even temporarily production without filter will more and more no longer be accepted by residents and authorities. Incidents at the filter lead to a shutdown of the whole production. Additional measures for heat recovery while preparing concepts for filtration plants help to reduce the energy consumption and serve for a sustained conservation of environment. A consequent consideration of the items above is also condition for the fact that environmental protection in foundries remains affordable. The lecture deals with the subjects above from the point of view of a plant constructor.
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Redakcja

CHIEF EDITORS
Editor
J. Szajnar
Deputy Editor
J. Jezierski

SUBJECT EDITORS
Theoretical Aspects of Casting Processes
K. Eigenfeld – Freiberg, Germany
E. Guzik – Kraków, Poland
T. G. Mathia - Lyon, France
W. Wołczyński – Kraków, Poland
Innovative Foundry Technologies and Materials
T. Elbel – Ostrava, Czech Republic
Z. Ignaszak – Poznań, Poland
O. P. Pandey – Punjab, India
A. Pereira - Vigo, Spain
Foundry Processes Computer Aiding
B. Mochnacki – Częstochowa, Poland
J. Roučka – Brno, Czech Republic
J.S. Suchy – Kraków, Poland
Mechanization, Automation and Robotics in Foundry
J. Bast – Freiberg, Germany
R. Wrona – Kraków, Poland
Transport Systems in Foundry
J. Dańko – Kraków, Poland
Z. Li – Shijiazhuang, China
Castings Quality Management
D. Bolibruchova– Żilina, Slovak Republic
J. D. B. de Mello - Santa Monica, Brazil
M. Perzyk – Warszawa, Poland
Environment Protection
M. Holtzer – Kraków, Poland
H. Polzin – Freiberg, Germany
J. Sobczak – Kraków, Poland
I. Volchok – Zaporizhzhya, Ukraine

EDITORIAL ADVISORY BOARD
J. Braszczyński – Częstochowa, Poland
B. K. Dhindaw – Rupnagar, India
L. A. Dobrzański – Gliwice, Poland
W. A. Hufenbach – Dresden, Germany
P. Jelínek – Ostrava, Czech Republic
L. Jeziorski – Częstochowa, Poland
J. Lacaze – Toulouse, France
V. L. Naydek – Kiev, Ukraine
A. Passerone – Genova, Italy
I. Riposan – Bucharest, Romania
F. Romankiewicz – Zielona Góra, Poland
A. Sládek – Żilina, Slovak Republic

INTERNATIONAL SCIENTIFIC REVIEW COMMITTEE
S. A. Argyropoulos – Toronto, Canada
M. Azadi – Tehran, Iran
Y. Babaskin – Kiev, Ukraine
K. Bako – Miskolc, Hungary
E. Bayraktar – Paris, France
L. Bechný – Zilina, Slovak Republic
V. Bednarova - Ostrava, Czech Republic
F. Bińczyk – Katowice, Poland
A. Bokota – Częstochowa, Poland
G.P. Borisov – Kiev, Ukraine
A. Bydałek – Kraków, Poland
C. H. Cáceres – Brisbane, Australia
J. Čech – Brno, Czech Republic
L. Q. Chen – Shenyang, China
A. Chojecki – Kraków, Poland
M. Cholewa – Gliwice, Poland
I. A. Dibrov – Moscow, Russia
D. Dispinar – Istanbul, Turkey
S. M. Dobosz – Kraków, Poland
V. I. Dubodelov – Kiev, Ukraine
A. Fedoryszyn – Krakow, Poland
J. Głownia – Kraków, Poland
K. Granat – Wrocław, Poland
J. Hampl – Ostrava, Czech Republic
J. Helber – Düsseldorf, Germany
M. Hetmańczyk – Katowice, Poland
M. Horáček – Brno, Czech Republic
M. Kaczorowski – Warszawa, Poland
W. Kapturkiewicz – Kraków, Poland
R. Kawalla – Freiberg, Germany
Z. Konopka – Czestochowa, Poland
D. Kopyciński – Kraków, Poland
W. K. Krajewski – Kraków, Poland
Z. Libo – Beijing, China
P. Lichy – Ostrava, Czech Republic
Y. P. Lim – Setapak, Malaysia
T. Lipiński – Olsztyn, Poland
E. Majchrzak – Gliwice, Poland
A. Mityayev - Zaporizhzhya, Ukraine
M. Murgaš – Trnava, Slovak Republic
I. Nová – Liberec, Czech Republic
W. Orłowicz – Rzeszów, Poland
T. Pacyniak – Łódź, Poland
B. Piekarski – Szczecin, Poland
A. Rimmer – West Bromwich, United Kingdom
S. Samavedam – Hyderabad, India
P. Schumacher – Leoben, Austria
N. Sczygiol – Częstochowa, Poland
P. Skočovský – Żilina, Slovak Republic
M.S. Soiński – Częstochowa, Poland
J. Sokolowski – Ottawa, Kanada
K. V. Sudhakar – Butte, USA
B. G. Thomas - Champaign, USA
M. Trbižan – Ljubljana, Slovenia
J. Vuorinen – Tampere, Finland
E. Ziółkowski – Kraków, Poland
J. Zych – Kraków, Poland

ASSOCIATE EDITORS
D. Bartocha – Gliwice, Poland, - editorial secretary
J. Suchoń – Gliwice, Poland - editorial secretary
J. Szymszal – Katowice, Poland, Statistic Editor
A. Dulska – Gliwice, Poland
M. Kondracki – Gliwice, Poland
C. Borek –Chicago, USA, Language Editor

 

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