An analysis of energy efficiency for transcritical compression unit with CO2 (R744) as the refrigerant has been carried out using empirical operating characteristics for the two-phase ejector. The first stage of the refrigerant compression is carried out in the ejector. The criterion adopted for the estimation of energy efficiency for the cycle is the coefficient of performance COP. The analysis is performed for the heat pump and refrigeration systems. The results of COP for the systems with the ejector has been compared with the COPL values for the single stage Linde cycle.
The article presents research results of physico-chemical and environmental issues for the dust generated during dedusting of the
installation for the processing and preparation of moulding sand with bentonite. Particular attention was paid to the content of heavy
metals and emission of gases from the BTEX group, which is one of the determinants of the moulding sands harmfulness for the
environment. The analysis of heavy metals in the test samples indicate that there is an increase of the content of all metals in the dust
compared to the initial mixture of bentonite. The most significant (almost double) increase observed for zinc is probably related to the
adsorption of this element on the dust surface by contact with the liquid metal. The study showed, that dust contained more than 20% of
the amount of montmorillonite and had a loss on ignition at a similar level. The addition of 1% of dust to the used moulding sand results in
almost 30% increase in the total volume of gases generated in casting processes and nearly 30% increase of the benzene emission.
The spectroscopic FT-IR and FT-Raman methods allowed to identify the cross-linking process of the aqueous composition of poly(acrylic
acid)/sodium salt of carboxymethyl starch (PAA/CMS-Na) applied as a binder for moulding sands (as a novel group binders BioCo). The
cross-linking was performed by physical agent, applying the UV-radiation. The results of structural studies (IR, Raman) confirm the
overlapping of the process of cross-linking polymer composition PAA/CMS-Na in UV radiation. Taking into account the ingredients and
structure of the polymeric composition can also refer to a curing process in a binder - mineral matrix mixture. In the system of bindermineral
matrix under the influence of ultraviolet radiation is also observed effect of binding. However, the bonding process does not occur
in the entire volume of the investigated system, but only on the surface, which gives some possibilities for application in the use of UV
curing surface of cores, and also to cure sand moulds in 3D printing technology
Temperature change is one of key factors which should be taken into account in logistics during transportation or storage of many types of goods. In this study, a passive UHF RFID-enabled sensor system for elevated temperature (above 58°C) detection has been demonstrated. This system consists of an RFID reader and disposable temperature sensor comprising an UHF antenna, chip and temperature sensitive unit. The UHF antenna was designed and simulated in an IE3D software. The properties of the system were examined depending on the temperature level, type of package which contains the studied objects and the type of antenna substrate.
The increasing demands for miniaturization and better functionality of electronic components and devices have a significant effect on the requirements facing the printed circuit board (PCB) industry. PCB manufactures are driving for producing high density interconnect (HDI) boards at significantly reduced cost and reduced implementation time. The interconnection complexity of the PCB is still growing and today calls for 50/50 μm or 25/25 μm technology are real. Existing technologies are unable to offer acceptable solution. Recently the Laser Direct Imaging (LDI) technology is considered as an answer for these challenges. LDI is a process of imaging electric circuits directly on PCB without the use of a phototool or mask. Our laboratory system for Laser Direct Imaging is designed for tracks and spaces on PCB with minimum width distance of 50/50 μm. In comparison with conventional photolithography method, this technology is much better for 50/50 μm track and spaces. In our research we used photoresist with resolution 50 μm, but in case of using laser photoresists with better resolution (e.g. 25 μm) it will be possible to image tracks in super-fine-line technology (25/25 μm). The comparison between two technology of creating mosaic pattern tracks on PCB proved that laser imaging is promising technology in high density interconnects patterns, which are widely use in multilayered PCB and similar applications.
Problems concerning structures dynamics are being one of most important subjects in recent investigations associated with railways constructions. The need of modelling of such structures and their behaviour prediction leads to necessity of seeking new approaches, mainly due to highly increasing speeds of vehicles and traffic intensity. Comparative studies carried out on experimental data, measurements and theoretical research show that models based on multi-layered approach supported by semi-analytical approximations of solutions can give new insight into undertaken analyses. More detailed consideration of roads components and their physical properties, along with application of effective estimations allowing to avoid numerical instabilities linked with extremal dynamic variations, can be important tools in obtaining new solutions both, theoretical and engineering. This paper briefly presents a number of multilayer railway track models, with special emphasis on nonlinear track properties. Existing analytical and semi-analytical solution methods are presented with main advantages of new approaches. The theoretical double-beam system with two nonlinear layers is solved and computational examples are presented along with possibility of their transition to other multilayer structures analysis.
Oxidative stress (OxS) has been implicated in the pathogenesis of Crohn’s disease (CD). The aim of this study was to examine whether nonenzymatic antioxidants are associated with active CD, by using the FRAP and GSH assay in plasma. Additionally, we measured bilirubin and albumin levels as two individual components of the plasma antioxidant system. A total of 55 patients with established CD, 30 with active CD and 25 with inactive disease, and 25 healthy individuals were prospectively enrolled in this study. We evaluated CD activity index, BMI and blood morphology, platelet count, serum CRP level, and bochemical parameters of OxS: ferric reducing ability of plasma (FRAP), reduced glutathione (GSH) in plasma and bilirubin and albumin levels in serum. Plasma FRAP and GSH concentrations were decreased in both CD groups compared to controls and negatively correlated with CDAI values (FRAP: r = –0.572, p = 0.003; GSH: r = –0.761, p = 0.001), CRP and platelet count. Bilirubin and albumin levels were lower in the serum of active CD patients than inactive CD patients and controls and negatively correlated with the CD activity index (r = –0328, p = 0.036, r = –0.518, p = 0.002) and CRP (r = –0.433, p = 0.002). The decreased FRAP and GSH levels in plasma and bilirubin and albumin levels in serum of patients with active CD compared to inactive CD and controls underlines the importance of OxS in the pathophysiology and activity of CD.
The growth of the global population, urbanization as well as economic and industrial development, affect the continuously increasing demand for mineral aggregates. The current assessed global production of mineral aggregates amounts to 50 billion Mg/year, which statistically approximates 6.5 Mg per an inhabitant of the globe. In terms of consumption volume, water is the only raw material ahead of aggregates. Despite such a great scale, in many countries and regions the extraction and production of aggregates belong to the least regulated sector of human activity. This refers particularly to the countries of A sia, A frica, and North A merica, where both the resources and the extraction of aggregates, particularly of sand and gravels, are either not monitored and registered. It significantly increases the negative impact on the natural environment, due to the destruction of riverbeds and oxbows, coastal erosion, drying up cultivation areas, etc. In the reports, local terminology of aggregates often functions, which makes it difficult to compare them and prepare appropriate balances. In order to regulate the unfavorable situation, one of the main conclusions of the Report (UNEP 2019) is the need of implementing a common requirement to plan and monitor the process of extraction of natural resources. The paper presents the possibility of forecasting the extraction and producing aggregates based on the consumption of cement, i.e. the basic building material. A lthough the analyzed coefficient of mineral aggregate production per unit of cement consumption (production) varies, its advantage is the fact that the production of cement is identified and taken into account in balances of industrial production of the majority of countries, whereas such identification for mineral aggregate production are still lacking.
The electromagnetic field (EMF) is an environmental factor affecting living organisms. The aim of this study was to demonstrate the effect of an extremely low frequency electro- magnetic field (ELF-EMF) on selected chemical components of the honeybee (Apis mellifera L.) using Fourier Transform Infrared (FTIR) spectroscopy. The FTIR method provides information on the chemical structure of compounds through identification and analysis of functional groups. The honeybees were treated with EMF at a frequency of 50 Hz and magnetic induction of 1.6 mT for 2, 6, 12, 24 and 48 hours. Analysis of FTIR spectra showed that EMF exposure longer than 2 hours induced changes in the structure of chemical compounds, especially in the IR region corresponding to DNA, RNA, phospholipids and protein vibrations, compared to control samples (bees not EMF treated). The results confirm the effect of EMF on bees depending on the duration of exposure.
The intercalation into interlayer spaces of montmorillonite (MMT), obtained from natural calcium bentonite, was investigated. Modification of MMT was performed by the poly(acrylic acid-co-maleic acid) sodium salt (co-MA/AA). Efficiency of modification of MMT by sodium salt co-MA/AA was assessed by the infrared spectroscopic methods (FTIR), X-ray diffraction method (XRD) and spectrophotometry UV-Vis. It was found, that MMT can be relatively simply modified with omitting the preliminary organofilisation – by introducing hydrogel chains of maleic acid-acrylic acid copolymer in a form of sodium salt into interlayer galleries. A successful intercalation by sodium salt of the above mentioned copolymer was confirmed by the powder X-ray diffraction (shifting the reflex(001) originated from the montmorillonite phase indicating an increase of interlayer distances) as well as by the infrared spectroscopy (occurring of vibrations characteristic for the introduced organic macromolecules). The performed modification causes an increase of the ion exchange ability which allows to assume that the developed hybrid composite: MMT-/maleic acid-acrylic acid copolymer (MMT-co- MA/AA) can find the application as a binding material in the moulding sands technology. In addition, modified montmorillonites indicate an increased ability for ion exchanges at higher temperatures (TG-DTG, UV-Vis). MMT modified by sodium salt of maleic acid-acrylic acid copolymer indicates a significant shifting of the loss of the ion exchange ability in the direction of the higher temperature range (500–700°C).
This work presents the methodology for analyzing the impact of ground vibrations induced during the drilling of gas/oil exploration wells on the surrounding constructions, as well as on humans and the natural environment. In the primary stage, this methodology is based on measurements of ground vibrations induced by a specific type of drilling system in the so-called reference site. In the next stage, ground vibrations are estimated in similar conditions to another design site, these conditions are assumed for a given drilling system, treated as a vibration source. In both sites, special seismic and geotechnical data are collected to construct numerical models for dynamic analyses. Finally, if it is required, a protection system is proposed with respect to the drilling technology and local conditions. The methodology presented has been tested on the terrain of an active natural gas mine used as the design site, and located in the southeastern part of Poland. The reference site was placed in the terrain of a working drilling system in similar conditions in the central part of Poland. Based on the results of numerical simulations, one may verify the different locations of the drilling rig in the design site with respect to the existing industrial structure. Due to the hazard from destructive ground vibrations, a certain vibroisolation system was proposed at the design site. Based on the results of numerical simulations one could rearrange the components of the drilling system in order to provide maximum security for the surrounding structures.