The objective of this study is to investigate the change in partition coefficient with a change in the concentration of the solute in a liquid system consisting of two relatively immiscible solvents. To investigate the changes in the partition coefficients, the data of the partition coefficients at infinite dilution and the ternary Liquid-Liquid Equilibrium (LLE) data at finite concentrations of the solute should be consistent. In this study, 29 ternary systems that are found in literature and for which the partition coefficients at infinite dilution and the ternary LLE data cannot be predicted accurately by the universal quasi-chemical (UNIQUAC) model are identified. On the basis of this model, some consistent and inconsistent ternary systems are introduced. Three inconsistent systems, namely hexane-butanol-water, CCl4 (carbon tetrachloride)-PA (propanoic acid)-water, and hexane-PA-water, are chosen for detailed analysis in this study. The UNIQUAC activity coefficient model is used to represent these data over a range of concentrations. The results show large errors, exhibiting the inability of this model to correlate the data. Furthermore, some ternary systems in which cross behavior of solutes between two phases observed are identified.
The paper presents the stability problem of control systems composed of a fractional-order PI controller and a inertial plant of a fractional order with time delay. Simple and efficient computational method for determining stability regions in the controller and plant parameters space is given. Knowledge of these regions permits tuning of the fractional-order PI controller. The method proposed is based on the classical D-partition method.
The application of aqueous two-phase systems (ATPS) is a cost-effective and simple method of protein separation (including enzymes) from complex systems. The first stage of designing the protein purification process in an ATPS involves the identification of the conditions for the formation of a given extraction system. For this purpose, the conditions for the formation of ATPSs in a thermoseparating EO50PO50 polymer/potassium phosphates system have been studied. Factors determining the ATPS formation comprised: separation temperature (4ºC or 20ºC), phosphate solution pH (6, 7.5 or 9) as well as the concentration of NaCl introduced into the systems (0.085 M, 0.475 M and 0.85 M). ATPS without NaCl were prepared as well. The conditions for the formation of the primary EO50PO50/potassium phosphate ATPS were determined with their phase diagrams. It was observed that with an increase of phosphate pH and NaCl concentration in the system, there was a decrease of the EO50PO50 and phosphate concentrations necessary to form a primary ATPS. After the primary two-phase separation, the top phase (rich in the EO50PO50 polymer) was partitioned from the bottom phase (rich in phosphates). Next, by means of polymer phase thermoseparation, a secondary two-phase system was formed. In the secondary EO50PO50/phosphate ATPS, the bottom phase was formed by the concentrated EO50PO50 polymer (30-80% concentration), while the top phase by a solution composed mainly of water, containing phosphate ions and remains of EO50PO50 polymer (3-7%).
This article attempts to show the importance of newspaper advertisements as a factual source which offers valuable insights into past events. The study of advertisements helps the researcher to complement and verify what has been gleaned from the usual documents, and sometimes can even provide a corrective to conclusions reached by other means. In particular, the advertisements in Lwowskie Tygodniowe Wiadomości [Lwów Weekly News], published 1786–1788 show how much information about property from the monasteries of Galicia, dissolved by Emperor Joseph II in 1782–1788, can be found in the local press. It is a source which not only contains important clues about the history and the scale of the dissolution but also a wealth of minor details that it would be hard find anywhere else.
Up to the present day Suhrawardy remains a controversial figure in both parts of Bengal, with Hindus often seeing him as their fierce persecutor and Bangladeshi Muslims hailing him as their country’s forefather and preacher of communal unity. This article analyses his actions during the period of his Prime Ministership (1946–1947) looking for the sources of the above dichotomy. It argues that although Suhrawardy displayed a mild communal bias at times, circumstances made him inconsistent, being as he was trapped between right wing of Muslim League, the Hindu masses unwilling to trust him and (until the end of 1946) Congress ambitions to inherit the whole Raj. The need to act quickly due to Viceroy Mountbatten’s haste, as well as the PM’s lack of social skills were other factors contributing to failure of his last initiative – United Bengal Scheme – despite his genuine efforts towards Hindu-Muslim settlement and agrarian reforms.
With the rise of coal mine underground reservoir engineering in the Shendong Mining Area, the space time dynamic evolution prediction of storage coefficient is becoming one of the critical technical problems for long-term reservoir operation. This coefficient directly determines the storage capacity and the comprehensive benefits of the operation of a coal mine underground reservoir. To this end, the proposed underground reservoir in Daliuta coal mine (No. 22616 working face) is selected in this study for the development and application of an experimental device to measure the storage coefficient. Rock and coal fragments from similar materials are prepared, which are filled and loaded according to the caving rock nature as well as the lumpiness and accumulation mode characteristics pertaining to No. 22616 working face. Subsequently, the measured storage coefficient under circulating water injection conditions revealed a four-dimensional spatial and temporal pattern. It followed the law of storage coefficient under joint interaction of water-rock and stress. The results showed that, prior to the experiment, rock and coal fragments made from similar materials had good water resistance when the paraffin content was set at 8%. The three stress zones were defined based on a theoretical analysis, which were applied on the corresponding loads. During the experiments, significant regional differences were found in the top surface with persisting subsidence of each stress loading zone. Hence, compared with its initial state, the maximum subsidence in the stress stability zone, the stress recovery zone, and the low-stress zone was 7.89, 5.8, and 1.83 mm, respectively. While the storage capacity and the storage coefficient gradually decreased, the former ranged from 0.2429 to 0.2397 m3, and the latter ranged from 0.270 to 0.266. The experimental results are verified by drainage engineering tests in the Shendong Mining Area. In essence, the storage coefficient had remarkable spatial distribution characteristics and a time-varying effect. In space, the storage coefficient increased with height along the vertical direction of the coal mine underground reservoir. However, it decreased with the distance from the boundary of the dam body in the horizontal direction. With time, the storage coefficient decreased dynamically. This study provides a new way of predicting the storage coefficient of a coal mine underground reservoir.